Crystal transition and thermal behavior of Nylon 12

The polyamide 12 (PA12) with different crystal forms is prepared with three crystallization paths. The crystal structures and corresponding thermal properties are systematically investigated. The results reveal that an α-form and a mixed (α + γ)-form of PA12 can be obtained by casting at 30°C and (40–80°C), respectively. Meanwhile, the γ-form of PA12 can be obtained by both casting at 90°C and slow melt cooling. However, the γ′-form is obtained only by melt quenching. Both the γ and γ′ forms of PA12 exhibit a single melting peak, whereas the α-form exhibits two melting peaks. The higher peak is attributed to the melting of γ-PA12, which originates from the melting–recrystallization of the α-PA12. It is found that the tensile properties of PA12 depend on the crystal forms. Both the γ and γ′-PA12 are strong and tough polymer materials, while α-PA12 is a strong but brittle polymer material.

Improvement of Stiffness and Energy Absorption by Harnessing Hierarchical Interlocking in Brittle Polymer Blocks

The objective of the present work is to investigate the possibility of improving both stiffness and energy absorption in interlocking, architectured, brittle polymer blocks through hierarchical design. The interlocking mechanism allows load transfer between two different material blocks by means of contact at the mating surfaces. The contacting surfaces further act as weak interfaces that allow the polymer blocks to fail gradually under different loading conditions. Such controlled failure enhances the energy absorption of the polymer blocks but with a penalty in stiffness. Incorporating hierarchy in the form of another degree of interlocking at the weak interfaces improves stress transfer between contacting material blocks; thereby, improvement in terms of stiffness and energy absorption can be achieved. In the present work, the effects of hierarchy on the mechanical responses of a single interlocking geometry have been investigated systematically using finite element analysis (FEA) and results are validated with experiments. From finite element (FE) predictions and experiments, presence of two competing failure mechanisms have been observed in the interlock: the pullout of the interlock and brittle fracture of the polymer blocks. It is observed that the hierarchical interface improves the stiffness by restricting sliding between the contacting surfaces. However, such restriction can lead to premature fracture of the polymer blocks that eventually reduces energy absorption of the interlocking mechanism during pullout deformation. It is concluded that the combination of stiffness and energy absorption is optimal when fracture of the polymer blocks is delayed by allowing sufficient sliding at the interfaces.

Improvement of performance of a ductile/brittle polymer system by graphite nanoplatelets: effect of component coupling

The upgrade of a PA/PS system based on the combination of reactive compatibilization of polymer components and their coupling with carbon nanoplatelets.

Interlaminar fracture toughness of flax-epoxy composites

The purpose of this study was to determine the influence of fibre architectures on the interlaminar fracture toughness and tensile toughness of flax fibre epoxy composites. The fracture toughness was investigated for both Mode I (GIC) and Mode II (GIIC) for seven flax-epoxy architectures: one plain weave, two twill 2 × 2 weaves, a quasi-unidirectional and a unidirectional architecture, the UD’s being tested in both [0,90] and [90,0] composite lay-ups. The results of the Mode I and Mode II showed promising results of the flax-epoxy composite performance. The addition of flax fibre increases the GIC and GIIC of the composites over that of the unreinforced brittle polymer by at least two to three times. Further improvements are made with the use of woven textiles. The tensile toughness was found to be a good indicator of the capacity of a material to sustain perforation or non-perforation impact.

Multiplicity of morphologies in poly (l-lactide) bioresorbable vascular scaffolds

Poly(l-lactide) (PLLA) is the structural material of the first clinically approved bioresorbable vascular scaffold (BVS), a promising alternative to permanent metal stents for treatment of coronary heart disease. BVSs are transient implants that support the occluded artery for 6 mo and are completely resorbed in 2 y. Clinical trials of BVSs report restoration of arterial vasomotion and elimination of serious complications such as late stent thrombosis. It is remarkable that a scaffold made from PLLA, known as a brittle polymer, does not fracture when crimped onto a balloon catheter or during deployment in the artery. We used X-ray microdiffraction to discover how PLLA acquired ductile character and found that the crimping process creates localized regions of extreme anisotropy; PLLA chains in the scaffold change orientation from the hoop direction to the radial direction on micrometer-scale distances. This multiplicity of morphologies in the crimped scaffold works in tandem to enable a low-stress response during deployment, which avoids fracture of the PLLA hoops and leaves them with the strength needed to support the artery. Thus, the transformations of the semicrystalline PLLA microstructure during crimping explain the unexpected strength and ductility of the current BVS and point the way to thinner resorbable scaffolds in the future.

Composition Determination of Vehicle Dismantling Waste

In recent years, a large number of toxic and hazardous substances were discharged into environment because of the simple landfill and accumulation of vehivle dismantling waste. Therefore, it is very important to develop the recycling technology of vehivle dismantling waste for the harmless, stability, reduction and resource utilization of vehivle dismantling waste. In this paper, the compositions of vehicle dismantling waste from two different dismantling processes were investigated by manual sorting, infrared spectroscopy and X-ray fluorescence spectrometer, experimental results showed that the vehicle waste from manual dismantling contained more polyurethane, foamed plastic and rubber with low value and the size of waste is lager, the vehicle waste from mechanical dismantling contained more metal and brittle polymer and their size was smaller. The concentration of metal in two kinds of wastes are less than 1%, the total concentration of carbon and hydrogen reach about 70%, so vehicle dismantling waste was suital for recovering ernergy, but the pollution of chlrone from polyvinyl chloride need to be prevented.