A New Memristive Neuron Map Model and Its Network’s Dynamics under Electrochemical Coupling

A memristor is a vital circuit element that can mimic biological synapses. This paper proposes the memristive version of a recently proposed map neuron model based on the phase space. The dynamic of the memristive map model is investigated by using bifurcation and Lyapunov exponents’ diagrams. The results prove that the memristive map can present different behaviors such as spiking, periodic bursting, and chaotic bursting. Then, a ring network is constructed by hybrid electrical and chemical synapses, and the memristive neuron models are used to describe the nodes. The collective behavior of the network is studied. It is observed that chemical coupling plays a crucial role in synchronization. Different kinds of synchronization, such as imperfect synchronization, complete synchronization, solitary state, two-cluster synchronization, chimera, and nonstationary chimera, are identified by varying the coupling strengths.

Catalyst-free synthesis of phenanthridines via electrochemical coupling of 2-isocyanobiphenyls and amines

One pot metal-free synthesis of phenanthridines and amides under electrochemical conditions.

Electrochemical coupling halobenzene into biphenyl on a reusable Pd nanoparticle-coated carbon-paper electrode at ambient conditions

Electrochemical homo-coupling halobenzene into biphenyl compounds on the Pd/C surface.

Recent Advances in Metal-Catalyzed, Electrochemical Coupling Reactions of sp2 Halides/Boronic Acids and sp3 Centers

Traditionally, metal-catalyzed cross-coupling reactions rely on stable but expensive metals, such as palladium. However, the recent development of synthetic organic electrochemistry allows for in situ redox manipulations, expanding the use of cheaper, abundant and sustainable metals, such as nickel and copper as efficient cross-coupling catalysts. This short review covers the recent advances in metal-catalyzed electrochemical coupling reactions, with a focus on reactions of sp2 electrophiles and nucleophiles with sp3 coupling partners to form both C–C and C–heteroatom bonds.1 Introduction2 Nickel-Catalyzed C–C sp2–sp3 Coupling Reactions3 Coupling of Aryl Groups with Heteroatomic Nuclei4 Conclusion