Writing And Reading With The Longitudinal Component of Light Using Carbazole-Containing Azopolymer Thin Films

It is well known that azobenzene-containing polymers (azopolymers) are sensitive to the polarization orientation of the illuminating radiation, with the resulting photoisomerization inducing material transfer at both the meso-and macroscale. As a result, azopolymers are efficient and versatile photonic materials, for example, they used for the fabrication of linear diffraction gratings, including subwavelength gratings, microlens arrays, and spectral filters. Here we propose to use carbazole-containing azopolymer thin films to directly visualize the longitudinal component of the incident laser beam, a crucial task for the realization of 3D structured light yet remaining experimentally challenging. We demonstrate the approach on both scalar and vectorial states of structured light, including higher-order and hybrid cylindrical vector beams. In addition to detection, our results confirm that carbazole-containing azopolymers are a powerful tool material engineering with the longitudinal component of the electric field, particularly to fabricate microstructures with unusual morphologies that differentiate from the total intensity distribution of the writing laser beam.

Bio-based optical and photonic materials: towards nature-based production methods for photonics

Nature has been a source of inspiration for the fabrication of new optical materials for centuries. During the last decades, the rapid developments in nanofabrication allowed mimicking the photonic properties of living organisms towards more efficient functional devices. But nanophotonics still relies on nanofabrication techniques and materials not compatible with the current environmental challenges. Bio-based optical materials have emerged as a sustainable alternative combining the best of both worlds: precise nanostructuring and unique optical properties with environmentally friendly natural production protocols.

Diffusionless transformation of soft cubic superstructure from amorphous to simple cubic and body-centered cubic phases

In a narrow temperature window in going from the isotropic to highly chiral orders, cholesteric liquid crystals exhibit so-called blue phases, consisting of different morphologies of long, space-filling double twisted cylinders. Those of cubic spatial symmetry have attracted considerable attention in recent years as templates for soft photonic materials. The latter often requires the creation of monodomains of predefined orientation and size, but their engineering is complicated by a lack of comprehensive understanding of how blue phases nucleate and transform into each other at a submicrometer length scale. In this work, we accomplish this by intercepting nucleation processes at intermediate stages with fast cross-linking of a stabilizing polymer matrix. We reveal using transmission electron microscopy, synchrotron small-angle X-ray diffraction, and angle-resolved microspectroscopy that the grid of double-twisted cylinders undergoes highly coordinated, diffusionless transformations. In light of our findings, the implementation of several applications is discussed, such as temperature-switchable QR codes, micro-area lasing, and fabrication of blue phase liquid crystals with large domain sizes.