Tris(Imidazolyl) Dicopper(I) Complex and its Reactivity to Exert Catalytic Oxidation of Sterically Hindered Phenol Substrates via a [Cu2O]2+ Core

The Cu ion ligated with histidine residues is a common active site motif of various Cu-containing metalloenzymes exerting versatile catalytic oxidation reactions. Due to the scarce of structurally characterized biomimetic...

Antioxidant behavior and tribological performance of a novel multifunctional additive in complex lithium grease

Purpose This paper aims to contrastively investigate the antioxidant behavior and tribological performance of a novel multifunctional additive (PBT) and dialkyldithiophosphate (ZDDP) in complex lithium grease (CLG). Design/methodology/approach PBT was successfully synthesized through esterification reaction. The antioxidant behavior of PBT and ZDDP was investigated by thermal analysis, and meanwhile, their tribological performance was evaluated by Optimol SRV-IV oscillating reciprocating friction and wear tester (SRV-IV test) and MRS-1J four-ball tester (Four-ball test). Furthermore, their anticorrosion ability was determined by copper strip corrosion test. Findings Four-ball tests showed that the extreme pressure property of PBT was a little inferior to that of ZDDP. Besides, all the other results demonstrated that PBT showed more superior antioxidation stability, friction-reduction and antiwear ability, as well as anticorrosion performance than ZDDP. Originality/value This work provides a study of hindered phenol derivative as a multifunctional additive in lubricant grease, which can contribute to the development of substitution of ZDDP.