Antioxidant behavior and tribological performance of a novel multifunctional additive in complex lithium grease

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Mianran Chao ◽  
Ming Jin ◽  
Peiwei Gong ◽  
Duyi Shen ◽  
Lili Zhu
Keyword(s):  
Tribological Performance ◽  
Friction Reduction ◽  
Esterification Reaction ◽  
Copper Strip ◽  
Multifunctional Additive ◽  
Lithium Grease ◽  
Content Type ◽  
Complex Lithium ◽  
Hindered Phenol ◽  
Ball Test

Purpose This paper aims to contrastively investigate the antioxidant behavior and tribological performance of a novel multifunctional additive (PBT) and dialkyldithiophosphate (ZDDP) in complex lithium grease (CLG). Design/methodology/approach PBT was successfully synthesized through esterification reaction. The antioxidant behavior of PBT and ZDDP was investigated by thermal analysis, and meanwhile, their tribological performance was evaluated by Optimol SRV-IV oscillating reciprocating friction and wear tester (SRV-IV test) and MRS-1J four-ball tester (Four-ball test). Furthermore, their anticorrosion ability was determined by copper strip corrosion test. Findings Four-ball tests showed that the extreme pressure property of PBT was a little inferior to that of ZDDP. Besides, all the other results demonstrated that PBT showed more superior antioxidation stability, friction-reduction and antiwear ability, as well as anticorrosion performance than ZDDP. Originality/value This work provides a study of hindered phenol derivative as a multifunctional additive in lubricant grease, which can contribute to the development of substitution of ZDDP.

Influence of positive texturing on friction and wear properties of piston ring-cylinder liner tribo pair under lubricated conditions

2019 ◽  
Vol 71 (4) ◽  
pp. 515-524 ◽  
Author(s):  
Venkateswara Babu P. ◽  
Ismail Syed ◽  
Satish Ben Beera
Keyword(s):  
Wear Resistance ◽  
Internal Combustion Engine ◽  
Friction And Wear ◽  
Piston Ring ◽  
Combustion Engine ◽  
Cylinder Liner ◽  
Internal Combustion ◽  
Tribological Performance ◽  
Friction Reduction ◽  
Content Type

Purpose In an internal combustion engine, piston ring-cylinder liner tribo pair is one among the most critical rubbing pairs. Most of the energy produced by an internal combustion engine is dissipated as frictional losses of which major portion is contributed by the piston ring-cylinder liner tribo pair. Hence, proper design of tribological parameters of piston ring-cylinder liner pair is essential and can effectively reduce the friction and wear, thereby improving the tribological performance of the engine. This paper aims to use surface texturing, an effective and feasible method, to improve the tribological performance of piston ring-cylinder liner tribo pair. Design/methodology/approach In this paper, influence of positive texturing (protruding) on friction reduction and wear resistance of piston ring surfaces was studied. The square-shaped positive textures were fabricated on piston ring surface by chemical etching method, and the experiments were conducted with textured piston ring surfaces against un-textured cylinder liner surface on pin-on-disc apparatus by continuous supply of lubricant at the inlet of contact zone. The parameters varied in this study are area density and normal load at a constant sliding speed. A comparison was made between the tribological properties of textured and un-textured piston ring surfaces. Findings From the experimental results, the tribological performance of the textured piston ring-cylinder liner tribo pair was significantly improved over a un-textured tribo pair. A maximum friction reduction of 67.6 per cent and wear resistance of 81.6 per cent were observed with textured ring surfaces as compared to un-textured ring surfaces. Originality/value This experimental study is helpful for better understanding of the potency of positive texturing on friction reduction and wear resistance of piston ring-cylinder liner tribo pair under lubricated sliding conditions.

Tribological effects of laser surface texturing and residual stress

2018 ◽  
Vol 70 (1) ◽  
pp. 126-132 ◽  
Author(s):  
Shuwen Wang ◽  
Feiyan Yan ◽  
Ao Chen
Keyword(s):  
Residual Stress ◽  
Wear Resistance ◽  
Friction And Wear ◽  
Surface Texturing ◽  
Laser Surface ◽  
Friction Reduction ◽  
Laser Surface Texturing ◽  
Wear Testing ◽  
Content Type ◽  
Surface Textures

Purpose The purpose of this paper is to investigate the tribological effects of laser surface texturing (LST) and residual stress on functional surfaces. Design/methodology/approach Three different surface textures (circular dimple, elliptical dimple and groove) with two different textured area ratios (10 and 20 per cent) are designed and fabricated by a Picosecond Nd YAG Laser machine. The friction and wear performance of textured specimens is tested using a UMT-2 friction and wear testing machine in mixed lubrication. Findings Test results show that elliptical dimples exhibit the best performance in wear resistance, circular dimples in friction reduction and grooves in stabilization of friction. The surfaces with larger textured area density exhibit better performance in both friction reduction and wear resistance. The improved performance of LST is the coupled effect of surface texture and residual stress. Originality/value The findings of this study may provide guidance for optimal design of functional surface textures in reciprocating sliding contacts under mixed or hydrodynamic lubrication, which can be used in automotive and other industrial applications.

Tribological behaviors of some novel dimercaptothiadiazole derivatives containing hydroxyl as multifunctional lubricant additives in biodegradable lithium grease

2014 ◽  
Vol 66 (1) ◽  
pp. 51-61 ◽  
Author(s):  
Huan Chen ◽  
Junhui Jiang ◽  
Tianhui Ren ◽  
Lei Zheng ◽  
Yidong Zhao
Keyword(s):  
Lubricant Additives ◽  
Short Chain ◽  
Lithium Grease ◽  
Edge Structure ◽  
Content Type ◽  
Organic Sulfide ◽  
Ferrous Sulfide ◽  
Heterocyclic Derivatives ◽  
Main Component ◽  
Thermal Films

Purpose – In order to meet the requests of exploring environmental-friendly and multifunctional lubricant additives, some novel dimercaptothiadiazole derivatives containing hydroxyl are prepared and used as antiwear (AW) and extreme-pressure (EP) additives in biodegradable lithium grease. The paper aims to discuss these issues. Design/methodology/approach – The tribological performances of the grease samples containing these derivatives are evaluated by using a four-ball tester. X-ray absorption near edge structure (XANES) spectroscopy is used to analyze the chemistry of tribofilms under AW/EP regime, and thermal films are also considered for comparison. Findings – The tribological tests show that these derivatives are all effective in reducing wear, especially at lower additive concentrations, but they are basically failed in reducing friction. They are also helpful in improving the EP characteristic of the base grease. The thermal films generated by these derivatives are composed of adsorbed organic sulfide and ferrous sulfate, though for short-chain derivatives, organic sulfide is the only component at 5.0 wt.%. Ferrous sulfide is the main component of the tribofilms formed by these derivatives at various additive concentrations. But for short-chain derivatives, these tribofilms consist of ferrous sulfide and ferrous disulfide at 5.0 wt.%, and the appearance of disulfide suggests that the interfacial temperature between the upper ball and three lower balls under these conditions is considerably low. The EP films generated by short-chain derivatives are all composed of organic sulfide and ferrous sulfide, while for long-chain derivatives, ferrous sulfide is the main component. Originality/value – These low-toxic and oil-soluble dimercaptothiadiazole derivatives are effective in improving the tribological characteristic of the biodegradable lithium grease, and these heterocyclic derivatives may be good substitutes for some harmful traditional additives.

Tribological Behavior of Carbon Nanotubes as an Additive on Lithium Grease

2014 ◽  
Vol 137 (1) ◽  
Author(s):  
Alaa Mohamed ◽  
T. A. Osman ◽  
A. Khattab ◽  
M. Zaki
Keyword(s):  
Carbon Nanotubes ◽  
Arc Discharge ◽  
Average Diameter ◽  
Friction Reduction ◽  
Lithium Grease ◽  
X Ray ◽  
Transmission Electron ◽  
Boundary Film ◽  
Load Carrying ◽  
Worn Surface

Carbon nanotubes (CNTs) with 10 nm average diameter and 5 μm in length were synthesized by electric arc discharge. The morphology and structure of CNTs were characterized by high resolution transmission electron microscopy (HRTEM) and X-ray powder diffraction. The tribological properties of CNTs as an additive on lithium grease were evaluated with a four ball tester. The results show that the grease with CNTs exhibit good performance in antiwear (AW) and decrease the wear scare diameter (WSD) about 63%, decrease friction reduction about 81.5%, and increase the extreme pressure (EP) properties and load carrying capacity about 52% with only 1% wt. of CNTs added to lithium grease. The action mechanism was estimated through analysis of the worn surface with a scanning electron microscope (SEM) and energy dispersive X-ray (EDX). The results indicate that a boundary film mainly composed of CNTs, Cr, iron oxide, and other organic compounds was formed on the worn surface during the friction process.

Tribological performance of self-lubricated polyamide6/boric oxide composites after water conditioning

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Kawaljit Singh Randhawa ◽  
Ashwin Patel
Keyword(s):  
Friction Coefficient ◽  
Abrasion Resistance ◽  
Tribological Performance ◽  
Boric Oxide ◽  
Resistance Testing ◽  
Tribological Behaviour ◽  
Content Type ◽  
Wear Rates ◽  
Water Conditioning ◽  
Oxide Composites

Purpose This paper aims to investigate the tribological performance, i.e. abrasion resistance, friction coefficient and wear rates, of self-lubricated water conditioned polyamide6/boric oxide composites. Design/methodology/approach Polyamide6 and polyamide6/boric oxide self-lubricated composites were immersed in water for 15 days to analyze the effect of water conditioning on friction, wear and abrasion resistance. Tribological testing on pin-on-disc tribometer and abrasion resistance testing on TABER abrader were performed to see the friction coefficient and wear rates of materials. The scanning electron microscopy (SEM) characterizations were performed to analyze the wear tracks. Findings Tribological testing results revealed the loss in abrasive resistance, but there was an improvement in frictional coefficient and wear rates with steel after water absorption. The SEM images clearly show less depth of wear tracks in water-conditioned materials than dry ones. Water conditioning was found supportive in the formation of smooth lubricating transfer film on steel disc during the tribological testing. Originality/value The tribological behaviour of polymer composites is different in dry and in high humidity or water conditions. Experiments were performed to investigate B2O3 solid lubricant filler effectiveness on tribological behaviour of water-conditioned polyamide composites. Bonding between polyamide6 and water molecules plus the formation of orthoboric acid was found advantageous in decreasing the friction coefficient and wear rates of composites.

Friction reduction in EHL contacts by surface microtexturing – tribological performance, manufacturing and tailored design

2019 ◽  
Vol 71 (8) ◽  
pp. 986-990 ◽  
Author(s):  
Stephan Tremmel ◽  
Max Marian ◽  
Michael Zahner ◽  
Sandro Wartzack ◽  
Marion Merklein
Keyword(s):  
Product Life Cycle ◽  
Structural Parameters ◽  
Surface Texturing ◽  
Friction Reduction ◽  
Forming Process ◽  
Friction Behavior ◽  
Holistic View ◽  
Content Type ◽  
Efficient Manufacturing ◽  
Tailored Design

Purpose This paper aims to derive tailor-made microtextures for elastohydrodynamically lubricated (EHL) contacts under consideration of manufacturing possibilities. Design/methodology/approach Component tests were used for the evaluation of the influence of surface texturing on the friction behavior in the cam/tappet contact. Furthermore, the manufacturing possibilities and limitations of a combined μEDM and micro-coining process and the feasibility of integration into a forming process were studied. Finally, a methodology based on transient EHL simulations and a meta-model of optimal prognosis was exemplarily used for microtexture optimization. Findings It was found that surface texturing in EHL contacts with high amount of sliding is promising. Moreover, the combination of μEDM and micro coining and the integration into established production processes allow the manufacturing of microtextures with desirable structural parameters and sufficient accuracy. Originality/value This paper gives a holistic view on surface microtexturing over several phases of the product life cycle, from the design, over efficient manufacturing to application-related testing.

Preparation and tribological properties of a microemulsion for magnesium alloy warm rolling

2019 ◽  
Vol 71 (1) ◽  
pp. 74-82 ◽  
Author(s):  
Chang Dong ◽  
Jianlin Sun ◽  
Zixuan Cheng ◽  
Yuqing Hou
Keyword(s):  
Magnesium Alloy ◽  
Surface Morphology ◽  
Tribological Properties ◽  
Warm Rolling ◽  
Friction Reduction ◽  
Alloy Strip ◽  
Lubrication Mechanism ◽  
Content Type ◽  
Rolling Oil ◽  
Lubrication Properties

Purpose The purpose of this paper is to synthesize a microemulsion and investigate its tribological properties as lubricant. Magnesium alloy warm rolling experiments were conducted. Surface morphology was observed and wear form was summarized. The composition of surface residues was analyzed, which sheds light on the lubrication mechanism of microemulsion. Design/methodology/approach A microemulsion was prepared with a proper amount of oil, surfactant, cosurfactant, water and other additives for magnesium alloy strip warm rolling. Tribological properties, such as maximum non-seizure load (PB), friction coefficient (μ) and wear scar diameter (D) of the microemulsion were measured and compared with those of emulsion and rolling oil on an MR-10A four-ball tribotester. The extreme pressure anti-wear coefficients (O) were calculated and compared. Warm rolling experiments were carried out on a Ф 170/400 × 300 mm four-high rolling mill at 240°C to compare the finish rolling thickness and surface quality of rolled AZ31B magnesium alloy strip under four lubrication states, namely, no lubrication, rolling oil, microemulsion and emulsion. The surface morphology after warm rolling was observed with confocal laser scanning microscope and scanning electron microscope, respectively. The composition of surface residues was analyzed with energy dispersive spectrometry and X-Ray photoelectron spectroscopy. Findings Surface morphology indicated that pitting wear, adhesive wear and ploughing wear were three main forms of wear in magnesium alloy warm rolling. Microemulsion had excellent lubrication properties with less residual oil remaining. Two types of adsorption layers formed on magnesium alloy strip surface were responsible for lubrication properties. MgSO4 and magnesium stearate in the reaction layer played a key role in anti-wear and friction-reduction in warm rolling. Originality/value The study is original and gives valuable information on lubrication mechanism of microemulsion in warm rolling of magnesium alloy strips.

Polymer mechanics and tribology

2018 ◽  
Vol 70 (4) ◽  
pp. 764-772 ◽  
Author(s):  
Nikolai K. Myshkin ◽  
Alexander Kovalev
Keyword(s):  
Polymer Composites ◽  
Contact Mechanics ◽  
Tribological Behavior ◽  
Tribological Performance ◽  
Memory Storage ◽  
Polymer Mechanics ◽  
Micro Electro Mechanical Systems ◽  
Content Type ◽  
Storage Devices ◽  
Functional Additives

Purpose The purpose of this paper is to review the advances in mechanics and tribology of polymers and polymer-based materials. It is focused on the understanding of the correlation of contact mechanics and the tribological behavior of polymers and polymer composites by taking account of surface forces and adhesion in the contact. Design/methodology/approach Mechanical behavior of polymers is considered a viscoelasticity. Tribological performance is estimated while considering the parts of deformation and adhesion in friction arising in the contact. Surface energy, roughness, load and temperature effects on the tribological behavior of polymers are evaluated. Polymer composites produced by reinforcing and by the addition of functional additives are considered as materials for various applications in tribology. Particular attention is given to polymer-based nanocomposites. Findings A review of studies in tribology has shown that polymer-based materials can be most successfully used as self-lubricating components of sliding bearings. The use of the fillers provides changes in the tribological performance of neat polymers and widens their areas of application in the industry. Thin polymer films were found to be prospective lubricants for memory storage devices, micro-electro-mechanical systems and precision mechanisms. Further progress in polymer tribology should be achieved on solving the problems of contact mechanics, surface physics and tribochemistry by taking account of the scale factor. Originality/value The review is based on the experience of the authors in polymer mechanics and tribology, their research data and on data of many other literature sources published in this area. It can be useful for specialists in polymer research and industrial engineers working in tribology and industrial lubrication.

Investigation of mechanical properties and tribological performance of Al-LSP and Al-Al2O3 composite

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Lokanadham Dharmana ◽  
Venkata Subbaiah Kambagowni
Keyword(s):  
Mechanical Properties ◽  
Optimal Condition ◽  
Casting Process ◽  
Stir Casting ◽  
Tribological Performance ◽  
Connecting Rod ◽  
Content Type ◽  
Specific Strength ◽  
Error Band ◽  
Structural Applications

Purpose This study aims to develop the Al-Si-Mg metal matrix composite, reinforced distinctly with lime stone powder (LSP; 12% by weight) and Al2O3 (12% by weight), and compare their mechanical properties and tribological performance. Design/methodology/approach The composites are fabricated through stir casting process. In view of the previous work, the Al-LSP composite with LSP reinforcement (12 Wt.%) shows enhanced mechanical properties and tribological performance, as compared with other weight percentages. Findings Though the Al-LSP composite is less expensive, it shows similar hardness, tensile strength and specific strength, when compared with Al- Al2O3 composite. However, the Al-LSP composite exhibits significant enhancement of above three properties, when compared with Al-Si-Mg metal. The systematic factorial design of experiments is obtained through Taguchi OA [L9]. The tribological performance is estimated through wear rate (WR-mm3/m) and coefficient of friction (CF) by varying the operating parameters of sliding distance (SD), load (L) and sliding velocity (SV). According to ANOVA results, the optimal condition of WR for all the tested materials is L1SD3SV1. Further, the optimal condition of CF is L1SD1SV3 for Al-LSP and Al-Si-Mg metal, while L2SD3SV2 is for Al-Al2O3 composite. The regression equation predicts the measured experimental values within error band of ± 8 percentage. Originality/value A comparison of two composite materials (Al-LSP and Al-Al2O3) with same weight fractions (12%) shows almost same trend in both the mechanical and tribological testing process. However, the developed Al-LSP composite exhibited better properties than the Al-Al2O3 and Al-base. Therefore, Al-LSP can be suggested for automotive applications (i.e., connecting rod, cylinder liners, camshaft) and structural applications (such as frames, over hanging supports), without compromising in desirable original with properties of constituents in the new material, which is achievable for looking to the end uses.

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