Middle Ordovician Upwelling-Related Ironstone of North Wales: Coated Grains, Ocean Chemistry, and Biological Evolution

Middle Ordovician phosphatic ironstone of the Welsh Basin provides new insight into the paleoenvironmental significance of ironstone and Ordovician ocean chemistry. Deposition occurred in a back-arc basin along the southern margin of Avalonia as the Rheic Ocean opened to the south. Ironstone is interpreted to have accumulated as part of an aggradational parasequence on a storm-dominated shelf with coastal upwelling. This parasequence has a laminated pyritic mudstone base that grades upward into variably bioturbated mudstone and coated grain-rich, intraclastic ironstone, which is overlain in turn by cross-stratified grainstone composed entirely of coated Fe grains. A coarser clastic parasequence composed of more proximal lithofacies rests conformably above and suggests the contact between the two parasequences is a maximum flooding surface marking the onset of highstand conditions. Lithofacies associations suggest that sustained coastal upwelling created a wedge of nutrient-rich, ferruginous seawater on the middle shelf that stimulated high surface ocean productivities. Large, coated Fe grains (granule size) composed of discontinuous and concentric carbonate fluorapatite, hematite, and chamosite cortical layers record fluctuations in pore water Eh that are interpreted to have been related to changes in upwelling intensity and intermittent storm reworking of the seafloor. Results support an emerging model for Ordovician ironstone underpinned by the development of ferruginous bottom water that was periodically tapped by coastal upwelling. Expanding, semi-restricted seaways such as the Rheic Ocean were ideal locations for the ponding of this anoxic, hydrothermally enriched seawater, especially during the early Paleozoic when the deep ocean was variably and inconsistently oxygenated. The coincidence of ironstone depositional episodes with graptolite diversification events suggests that, in addition to Fe, the sustained supply of upwelling-related P may have driven the radiation of some planktonic ecosystems during the Great Ordovician Biodiversification Event. Concomitant minor extinctions of benthic trilobites occurred as these ferruginous waters impinged on the shelf.

The stratigraphic record of continental breakup, offshore NW Australia

Continental breakup involves a transition from rapid, fault-controlled syn-rift subsidence to relatively slow, post-breakup subsidence induced lithospheric cooling. Yet the stratigraphic record of many rifted margins contain syn-breakup unconformities, indicating episodes of uplift and erosion interrupt this transition. This uplift has been linked to mantle upwelling, depth-dependent extension, and/or isostatic rebound. Deciphering the breakup processes recorded by these unconformities and their related rock record is difficult because associated erosion commonly removes the strata that help constrain the onset and duration of uplift. We examine three major breakup-related unconformities and intervening rock record in the Lower Cretaceous succession of the Gascoyne and Cuvier margins, offshore NW Australia, using seismic reflection and borehole data. These data show the breakup unconformities are disconformable (non-erosive) in places and angular (erosive) in others. Our recalibration of palynomorph ages from rocks underlying and overlying the unconformities shows: (i) the lowermost unconformity developed between 134.98–133.74 Ma (Intra-Valanginian), probably during the localisation of magma intrusion within continental crust and consequent formation of continent-ocean transition zones (COTZ); (2) the middle unconformity formed between ~134–133 Ma (Top Valanginian), possibly coincident with breakup of continental crust and generation of new magmatic (but not oceanic) crust within the COTZs; and (iii) the uppermost unconformity likely developed between ~132.5–131 Ma (i.e. Intra-Hauterivian), coincident with full breakup of continental lithosphere and the onset of seafloor spreading. During unconformity formation, uplift was focused along the continental rift flanks, likely reflecting landward flow of lower crustal and/or lithospheric mantle from beneath areas of localised extension towards the continent (i.e. depth-dependent extension). Our work supports the growing consensus that the ‘breakup unconformity’ is not always a single stratigraphic surface marking the onset of seafloor spreading; multiple unconformities may form and reflect a complex history of uplift and subsidence during the development of continent-ocean transition.

Comparison of tumor surface marking by experienced neurosurgeon versus neuronavigation guidance

Introduction: Accurate flap marking has always been a challenge for neurosurgeons during tumor surgery. The use of neuronavigation has somewhat overcome this problem by allowing the navigation of intraoperative 3D neuroanatomy of the lesion. In this study, we aim to evaluate the percentage discrepancy of tumor surface marking by experienced neurosurgeon versus neuronavigation guidance. Methods: This is a prospective analytical study. Initial surface marking of the tumor was done by experienced neurosurgeon on the basis of sagittal, coronal and axial Magnetic Resonance Imaging films; and later was re-marked using neuronavigation. Photographs of surface markings were taken then comparison was done by plotting marking on the standard graph paper and percentage discrepancies were calculated for every case. Results: Percentage discrepancy ranged from 15 % to 81 % and the mean discrepancy score was 44%. Conclusion: Even in experienced neurosurgeon's hand, flap marking is not always accurate and neuronavigation definitely seems to be an effective tool.

The Improvement of Moisture Resistance and Organic Compatibility of SrAl2O4: Eu2+, Dy3+ Persistent Phosphors Coated with Silica–Polymer Hybrid Shell

The existing road surface marking with poor visibility at night results in traffic safety hazards in insufficient lighting roads. This study aims to prepare the dedicated aluminate-based persistent phosphors considering the integrated pavement environment, as the first step to achieve the durable luminescent road surface marking. SrAl2O4: Eu2+, Dy3+ persistent phosphors coated with silica–polymer hybrid shell were prepared by chemical precipitation and sol-gel method to improve moisture resistance and organic compatibility. The optimum silane coupling agent type and dosage, the surfactant dosage, the optimum sodium silicate dosage, and the coating reaction time in silica shell and polymer shell coating were studied based on the moisture resistance test. The silica–polymer hybrid shell coating balances the organic compatibility and thermal stability as compared to the silica or polymer shell coating in the oil absorption test and thermogravimetric analysis. Ex-Em Spectra, XRD, and SEM method were used to characterize the persistent phosphors, indicating the preparation does not destroy the persistent phosphors. The outstanding durable properties of SrAl2O4: Eu2+, Dy3+ persistent phosphors coated with silica–polymer hybrid shell as shown in this research is crucial for its potential application in waterborne luminescent coatings of road surface marking.