An Impedance Study of the Membrane Polarisation Effect in Simulated Rock Systems

<p>Work is reported on the development of a high precision, low frequency impedance bridge, and the use of impedance measurement in characterising the induced polarisation effect of unmineralised material. Impedance spectra for a variety of laboratory model clay/rock/electrolyte systems are analysed in terms of an equivalent circuit. By measuring the dependence of the parameters of this circuit, on such variables as electrolyte type and concentration, temperature and pore geometry, an electrochemical model for membrane polarisation has been developed. Polarisation is considered to arise from diffusional limitation of cations at the membrane/electrolyte interface of clay aggregations in rock pores, and this is found to be amenable to a Warburg diffusional impedance analysis.</p>

An Impedance Study of the Membrane Polarisation Effect in Simulated Rock Systems

<p>Work is reported on the development of a high precision, low frequency impedance bridge, and the use of impedance measurement in characterising the induced polarisation effect of unmineralised material. Impedance spectra for a variety of laboratory model clay/rock/electrolyte systems are analysed in terms of an equivalent circuit. By measuring the dependence of the parameters of this circuit, on such variables as electrolyte type and concentration, temperature and pore geometry, an electrochemical model for membrane polarisation has been developed. Polarisation is considered to arise from diffusional limitation of cations at the membrane/electrolyte interface of clay aggregations in rock pores, and this is found to be amenable to a Warburg diffusional impedance analysis.</p>

Polarisation changes in guided infrared thermography using silver halide poly-crystalline mid-infrared fibre bundle

Broadband mid-infrared (B-MIR) thermography using fibre optic waveguides can be critical in real-time imaging in harsh environments such as additive manufacturing, personalised medical diagnosis and therapy. We investigate the polarisation effect on thermal measurements through poly-crystalline fibre bundle employing a simple broadband cross-polarisation configuration experimental set-up. Silver halide poly-crystalline fibres AgCl1−xBrx (0 ≤ x≤1) (AgClBr-PolyC) have very wide transmission bandwidth spanning over the spectral range from 1 µm up to 31 µm FWHM. Moreover, they are non-toxic, non-hygroscopic, with relatively good flexibility, which make them very adequate for spectroscopic and thermal measurements in medical and clinical fields. In this study, we used a fibre bundle composed of seven single AgClBr-PolyC fibres, each with a core diameter of about 300 µm, inserted between two broadband MIR polarisers. A silicon carbide filament source was placed at the entrance of the fibre bundle, while a FLIR thermal camera with a close-up lens was employed to measure the spatial temperature distribution over the fibre-bundle end. Indeed, polarisation dependence of temperature measurements has been clearly observed in which the orientation of temperature extrema (minima and maxima) vary from one fibre to another within the bundle. Moreover, these observations have enabled the classification of AgClBr-PolyC fibres following their polarisation sensitivities by which some fibres are relatively highly sensitive to polarisation with polarisation temperature difference (PTD) that can reach 22.1 ± 2.8 °C, whereas some others show very low PTD values down to 3.1 ± 2.8 °C. Many applications can readily be found based on the advantages of both extreme cases.

Quantification of the Local Heat Release Rate During Flame-Vortex Interactions at Different Lewis Numbers and Equivalence Ratios

<p>The present work aims at the detailed understanding of the local processes in premixed combustion of hydrogen, methane and propane flames at unsteady conditions. The methodology consists of the analysis of simulations of two-dimensional flame-vortex interactions as well as statistical data obtained from threedimensional Direct Numerical Simulations (DNS) of the flame front interacting with a set of vortexes. Special attention is given to the relationship between the Lewis number (<em>Le</em>) of the fuel and the flame front stretch in terms of both curvature and strain rate. A large single vortex bends the flame front thus creating both positive and negative curvatures, which in turn enhance the heat release rate in some locations of the flame front and decrease it in others. The resulting effect is called “polarisation effect”. The occurrence and the strength of the polarisation effect of curvature are tightly bound up with the Lewis number of the fuel. The polarisation effect is quantified by the ratio of maximum to minimum heat release rates along the flame front, which defines the Polarisation Effect Number (PEN). The more the Lewis number of a fuel deviates from unity, the stronger the polarisation effect is. Strong polarisation effects lead finally to local flame extinction. This is demonstrated for hydrogen flames with<em> Le</em> = 0.29 (lean) and Le = 2.2 (rich) as well as for artificially designed cases with <em>Le</em> = 0.1 and <em>Le</em> = 10.0. Therefore, flame extinction can occur for both thermodiffusively stable and unstable flames. It is shown that choosing an appropriate mixture of real fuels with different Lewis numbers, the homogeneity of the heat release rate along the flame front could be considerably enhanced. This relatively uniform heat release rate is not sensitive to curvature, which consequently decreases the occurrence of local extinction.</p><p> </p>

1.3-Dithienium-and 1.3-Dithiolenium Salts, VI ,13C NMR Spectroscopic Investigations on 2-Substituted 1,3-Dithian-2-ylium Cations. Unusual γ-Effects

The 13C NMR chemical shifts of 19 2-substituted 1,3-dithian-2-ylium-tetrafluorborates 1a-1s are discussed in comparison to known analogous 1,3-dithianes and 2-lithio-1,3-dithianes. The unusual γ-effects (up to 9 ppm), which can also observed in other six-membered ring systems, are explained by the electric field effect (σ-polarisation effect). The electron density distribution can be estimated qualitatively by comparison with the 1,3-dioxan-2-ylium-and cyclohexylcations.