A Study on Chemical Ageing of Composite Ribbed GFRP Bars under Load

Here we explored the chemical durability of glass fiber-reinforced polymer (GFRP) bars under load. Three batches of ribbed GFRP bar specimens were fabricated using binder matrices: ED-22+isomethyltetrahydrophthalic anhydride (iso-MTGFA), ED-22+Ethal-450 and NPPN-631+ iso-MTGFA. As the reinforcing filler, we used an EC17 glass roving (for all the specimen batches). The specimens of each batch were aged in a 1 N alkaline NaOH solution at 60 °C for 2000 hrs. The ageing was performed under a 300 MPa load (30% of the failure stress). The tensile strength of the specimens from each batch following ageing was measured. The tensile test results demonstrated that that the strength loss of the specimens following chemical ageing was 58.9% for batch 1 based on ED-22+iso-MTGFA, 6.6% for batch 2 based on ED-22+Ethal-450, and 33.6% for batch 3 based on NPPN-631 + iso-MTGFA. The specimens of batch 2 based on ED-22+Ethal-450 exhibited the greatest resistance to the NaOH alkaline solution (a strength loss of 6.6%).

Ageing Effects in Mounting Media of Microscope Slide Samples from Natural History Collections: A Case Study with Canada Balsam and PermountTM

Microscope slide collections represent extremely valuable depositories of research material in a natural history, forensic, veterinary, and medical context. Unfortunately, most mounting media of these slides deteriorate over time, with the reason for this not yet understood at all. In this study, Raman spectroscopy, ultraviolet–visible (UV–Vis) spectroscopy, and different types of light microscopy were used to investigate the ageing behaviour of naturally aged slides from museum collections and the experimentally aged media of Canada balsam and PermountTM, representing a natural and a synthetic resin, respectively, with both being based on mixtures of various terpenes. Whereas Canada balsam clearly revealed chemical ageing processes, visible as increasing colouration, PermountTM showed physical deterioration recognisable by the increasing number of cracks, which even often impacted a mounted specimen. Noticeable changes to the chemical and physical properties of these mounting media take decades in the case of Canada balsam but just a few years in the case of PermountTM. Our results question whether or not Canada balsam should really be regarded as a mounting medium that lasts for centuries, if its increasing degree of polymerisation can lead to a mount which is no longer restorable.

Characterization of the Evolution of Noble Metal Particles in a Commercial Three-Way Catalyst: Correlation between Real and Simulated Ageing

Ageing of automotive catalysts is associated to a loss of their functionality and ultimately to a waste of precious resources. For this reason, understanding catalyst ageing phenomena is necessary for the design of long lasting efficient catalysts. The present work has the purpose of studying in depth all the phenomena that occur during ageing, in terms of morphological modification and deactivation of the active materials: precious metal particles and oxidic support. The topic was deeply investigated using specific methodologies (FT-IR, CO chemisorption, FE-SEM) in order to understand the behavior of metals and support, in terms of their surface properties, morphology and dispersion in the washcoat material. A series of commercial catalysts, aged in different conditions, have been analyzed, in order to find correlations between real and simulated ageing conditions. The characterization highlights a series of phenomena linked to the deactivation of the catalysts. Pd nanoparticles undergo a rapid agglomeration, exhibiting a quick loss of dispersion and of active sites with an increase of particles size. The evolution of the support allows highlighting also the contribution of chemical ageing effects. These results were also correlated with performance tests executed on synthetic gas bench, underlining a good correspondence between vehicle and laboratory aged samples and the contribution of chemical poisoning to vehicle aged ones. The collected data are crucial for the development of accelerated laboratory ageing protocols, which are instrumental for the development and testing of long lasting abatement systems.

Effects of physical, chemical, and biological ageing on the mineralization of pine wood biochar by a Streptomyces isolate

If biochar is to be used for carbon (C) management, we must understand how ageing affects biochar C mineralization. Here, we incubated aged and unaged eastern white pine wood biochar produced at 350 and 550 °C with a Streptomyces isolate, a putative biochar-decomposing microbe. Ageing was simulated via exposure to (a) alternating freeze-thaw and wet-dry cycles (physical ageing), (b) concentrated hydrogen peroxide (chemical ageing) and (c) nutrients and microorganisms (biological ageing). Elemental composition and surface chemistry (Fourier Transform Infrared spectroscopy) of biochar samples were compared before and after ageing. Ageing significantly increased biochar C mineralization in the case of physically aged 350 °C biochar (p < 0.001). Among 350 °C biochars, biochar C mineralization was positively correlated with an increase in O/C ratio (R2 = 0.78) and O-containing functional groups (R2 = 0.73) post-ageing, suggesting that surface oxidation during ageing enhanced biochar degradation by the isolate. However, in the case of 550 °C biochar, ageing did not result in a significant change in biochar C mineralization (p > 0.05), likely due to lower surface oxidation and high condensed aromatic C content. These results have implications for the use of biochar for long term C storage in soils.

Weaker cooling by aerosols due to dust–pollution interactions

The interactions between aeolian dust and anthropogenic air pollution, notably chemical ageing of mineral dust and coagulation of dust and pollution particles, modify the atmospheric aerosol composition and burden. Since the aerosol particles can act as cloud condensation nuclei, this affects the radiative transfer not only directly via aerosol–radiation interactions, but also indirectly through cloud adjustments. We study both radiative effects using the global ECHAM/MESSy atmospheric chemistry-climate model (EMAC) which combines the Modular Earth Submodel System (MESSy) with the European Centre/Hamburg (ECHAM) climate model. Our simulations show that dust–pollution–cloud interactions reduce the condensed water path and hence the reflection of solar radiation. The associated climate warming outweighs the cooling that the dust–pollution interactions exert through the direct radiative effect. In total, this results in a net warming by dust–pollution interactions which moderates the negative global anthropogenic aerosol forcing at the top of the atmosphere by (0.2 ± 0.1) W m−2.

Weaker cooling by aerosols due to dust-pollution interactions

The interactions between aeolian dust and anthropogenic air pollution, notably chemical ageing of mineral dust and coagulation of dust and pollution particles, modify the atmospheric aerosol composition and burden. Since the aerosol particles can act as cloud condensation nuclei, this not only affects the radiative transfer directly via aerosol-radiation interactions, but also indirectly through cloud adjustments. We study both radiative effects using the global ECHAM/MESSy atmospheric chemistry-climate model (EMAC) which combines the Modular Earth Submodel System (MESSy) with the European Centre/Hamburg (ECHAM) climate model. Our simulations show that dust-pollution interactions reduce the cloud water path and hence the reflection of solar radiation. The associated climate warming outweighs the cooling which the dust-pollution interactions exert through the direct radiative effect. In total, this results in a net warming by dust-pollution interactions which moderates the negative global anthropogenic aerosol forcing at the top of the atmosphere by (0.2 ± 0.1) W m−2.

Weaker cooling by aerosols due to dust-pollution interactions

&lt;p&gt;The interactions between aeolian dust and anthropogenic air pollution, notably chemical ageing of mineral dust and coagulation of dust and pollution particles, modify the atmospheric aerosol burden. Since the aerosol particles can act as cloud condensation nuclei, this not only affects the radiative transfer directly via aerosol radiation interactions, but also indirectly through cloud adjustments. We study both radiative effects using the global ECHAM/MESSy atmospheric chemistry-climate model (EMAC) which combines the Modular Earth Submodel System (MESSy) with the European Centre/Hamburg (ECHAM) climate model. Our simulations show that the dust-pollution interactions reduce the cloud water and hence the reflection of solar radiation. The associated climate warming outweighs the cooling which the dust-pollution interactions exert through the direct radiative effect. In total, this results in a net warming by dust-pollution interactions which we estimate to moderate the negative global anthropogenic aerosol forcing at the top of the atmosphere by more than 0.1 W / m&amp;#178;.&lt;/p&gt;