Lattice Dynamics of KAgF3 Perovskite, Unique 1D Antiferromagnet

Theoretical DFT calculations using GGA+U and HSE06 frameworks enabled vibrational mode assignment and partial (atomic) phonon DOS determination in KAgF3 perovskite, a low-dimensional magnetic fluoroargentate(II). Twelve bands in the spectra of KAgF3 were assigned to either IR active or Raman active modes, reaching excellent correlation with experimental values (R2 > 0.997). Low-temperature Raman measurements indicate that the intriguing spin-Peierls-like phase transition at 230 K is an order–disorder transition and it does not strongly impact the vibrational structure of the material.

Cooperative Admission Control with Network Coding in 5G Underlying D2D-Satellite Communication

Cooperative communication supported by device to device (D2D)-LEO earthed satellite increases the performance of the resilient network and offloads base station. Additionally, network coding in a packet-based cooperative framework provides diversity and speedy recovery of lost packets. Cooperative communication advantages are subject to effective joint admission control strengthened by network coding for multiple interfaces. Joint admission control with network coding involves multiple constraints in terms of user selection, mode assignment, power allocation, and interface-based network codewords, which is challenging to solve collectively. Sub-problematization and its heuristic solution lead to a less complex solution. First, the adaptive terrestrial satellite power sentient network (ATSPSN) algorithm is proposed based on low complex convex linearization of mix integer non-linear problem (MINLP), NP-hard. ATSPSN provides optimum power allocation, mode assignment, and user selection based on joint channel conditions. Second, a multiple access network coding algorithm (MANC) is developed underlying the D2D-satellite network, which provides novel multiple interface random linear network codewords. At the end, the bi-directional matching algorithm aiming for joint admission control with network coding, named JAMANC-stream and JAMANC-batch communication, is proposed. JAMANC algorithm leads to a less complex solution and provides improved results in terms of capacity, power efficiency, and packet completion time. The theoretical lower and upper bounds are also derived for comparative study.

Conformational assignment of gas phase peptides and their H-bonded complexes using far-IR/THz: IR-UV ion dip experiment, DFT-MD spectroscopy, and graph theory for mode assignment

Graph theory based vibrational modes as new entities for vibrational THz spectroscopy.