schrödinger perturbation
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Energies ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 4436 ◽  
Author(s):  
Peter Wouters ◽  
Armand van Deursen

Temperature variation from dynamic cable loading affects the propagation characteristics of transient signals. The distortion of modal signal components as a function of temperature in a three-phase medium-voltage cable is investigated. The temperature influence arises mainly through the complex insulation permittivity, which has a non-linear relationship with temperature. Near the maximum operating temperature of the cross-linked polyethylene insulation, the propagation velocity increases by 0.56% per degree centigrade but is an order of magnitude less sensitive at ambient temperature. The paper presents modeling results based on cable impedance and admittance matrices obtained from electromagnetic field simulation, taking into account the time-varying temperature distribution in the cable cross-section. The results are verified by applying Rayleigh–Schrödinger perturbation analysis. In the time domain, signal patterns shift when the modal propagation velocities change upon cable loading. Moreover, separation of degenerate modes is observed when the cable phase conductors carry an unbalanced current. The perspectives for exploiting the temperature dependency of signal propagation for pinpointing cable defects and for dynamic rating of underground power cables are discussed.


Entropy ◽  
2020 ◽  
Vol 22 (1) ◽  
pp. 80 ◽  
Author(s):  
Miloslav Znojil

Non-Hermitian quantum-Hamiltonian-candidate combination H λ of a non-Hermitian unperturbed operator H = H 0 with an arbitrary “small” non-Hermitian perturbation λ W is given a mathematically consistent unitary-evolution interpretation. The formalism generalizes the conventional constructive Rayleigh–Schrödinger perturbation expansion technique. It is sufficiently general to take into account the well known formal ambiguity of reconstruction of the correct physical Hilbert space of states. The possibility of removal of the ambiguity via a complete, irreducible set of observables is also discussed.


2020 ◽  
Vol 128 (12) ◽  
pp. 1795
Author(s):  
С.В. Краснощеков ◽  
Е.О. Добролюбов ◽  
Сюаньхао Чан

The singular structure of the lower vibrational states of the difluorosilylene molecule (up to four quanta of total excitation) was studied by expanding the energies of each state in the series of high-order Rayleigh-Schrödinger perturbation theory and analyzing their implicit multivalued properties using the fourth degree Padé-Hermite approximants. The quartic potential energy surface in dimensionless normal coordinates was calculated quantum-mechanically at the MP2/cc-pVTZ level. It is shown that one of the values of multivalued approximants reproduces the variational solution with high accuracy, while other values, starting from the fourth polyad, in many cases coincide with the energies of other states of the polyad. The Fermi and Darling-Dennison resonances are analyzed on the basis of the coincidence of the singular complex branch points of the approximants for interacting states inside or near a circle of unit radius on the complex plane. It was found that a pair of states can have several coinciding branch points of solutions, including those inside the unit circle. It is concluded that this approach is an effective method for determining the polyad structure of vibrational states. The calculation parameters are selected, which are necessary for the reproducibility of key results. The calculations were carried out using a software package in the Fortran language using a package of arithmetic calculations with a long mantissa of real numbers (200 digits).


2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Mahmoud Korek ◽  
Nayla El-Kork

By using the Rayleigh-Schrödinger perturbation theory the rovibrational wave function is expanded in terms of the series of functions ϕ0,ϕ1,ϕ2,…ϕn, where ϕ0 is the pure vibrational wave function and ϕι are the rotational harmonics. By replacing the Schrödinger differential equation by the Volterra integral equation the two canonical functions α0 and β0 are well defined for a given potential function. These functions allow the determination of (i) the values of the functions ϕι at any points; (ii) the eigenvalues of the eigenvalue equations of the functions ϕ0,ϕ1,ϕ2,…ϕn which are, respectively, the vibrational energy Ev, the rotational constant Bv, and the large order centrifugal distortion constants Dv,Hv,Lv….. Based on these canonical functions and in the Born-Oppenheimer approximation these constants can be obtained with accurate estimates for the low and high excited electronic state and for any values of the vibrational and rotational quantum numbers v and J even near dissociation. As application, the calculations have been done for the potential energy curves: Morse, Lenard Jones, Reidberg-Klein-Rees (RKR), ab initio, Simon-Parr-Finlin, Kratzer, and Dunhum with a variable step for the empirical potentials. A program is available for these calculations free of charge with the corresponding author.


2018 ◽  
Vol 33 (02) ◽  
pp. 1850009 ◽  
Author(s):  
Miloslav Znojil ◽  
Iveta Semorádová

Singular repulsive barrier [Formula: see text] inside a square-well is interpreted and studied as a linear analog of the state-dependent interaction [Formula: see text] in nonlinear Schrödinger equation. In the linearized case, Rayleigh–Schrödinger perturbation theory is shown to provide a closed-form spectrum at sufficiently small [Formula: see text] or after an amendment of the unperturbed Hamiltonian. At any spike strength [Formula: see text], the model remains solvable numerically, by the matching of wave functions. Analytically, the singularity is shown regularized via the change of variables [Formula: see text] which interchanges the roles of the asymptotic and central boundary conditions.


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