Effects of Wildfires and Ash Leaching on Stream Chemistry in the Santa Ynez Mountains of Southern California

Wildfires can change ecosystems by altering solutes in streams. We examined major cations in streams draining a chaparral-dominated watershed in the Santa Ynez Mountains (California, USA) following a wildfire that burned 75 km2 from July 8 to October 5, 2017. We identified changes in solute concentrations, and postulated a relation between these changes and ash leached by rainwater following the wildfire. Collectively, K+ leached from ash samples exceeded that of all other major cations combined. After the wildfire, the concentrations of all major cations increased in stream water sampled near the fire perimeter following the first storm of the season: K+ increased 12-fold, Na+ and Ca2+ increased 1.4-fold, and Mg2+ increased 1.6-fold. Our results suggested that the 12-fold increase in K+ in stream water resulted from K+ leached from ash in the fire scar. Both C and N were measured in the ash samples. The low N content of the ash indicated either high volatilization of N relative to C occurred, or burned material contained less N.

Waste Wood Fly Ash Treatment in Switzerland: Effects of Co-Processing with Fly Ash from Municipal Solid Waste on Cr(VI) Reduction and Heavy Metal Recovery

In Switzerland, waste wood fly ash (WWFA) must be treated before deposition on landfills due to its high pollutant load (Cr(VI) and heavy metals). Acid fly ash leaching, the process used for heavy metal recovery from municipal solid waste incineration fly ash (MSWIFA), represents a possible treatment for heavy metal depletion and Cr(VI) reduction in WWFA. The co-processing of WWFA with MSWIFA during acid fly ash leaching was investigated in laboratory- and industrial-scale experiments with different setups. Of interest were the effects on heavy metal recovery efficiency, the successful outcome of Cr(VI) reduction and consumption of neutralizing chemicals (HCl, H2O2). Detailed chemical and mineralogical characterization of two WWFA types and MSWIFA showed that MSWIFA has higher concentrations in potentially harmful elements than WWFA. However, both WWFA types showed high concentrations in Pb and Cr(VI), and therefore need treatment prior to deposition. Depending on the waste wood proportion and quality, WWFA showed chemical and mineralogical differences that affect leaching behavior. In all experimental setups, successful Cr(VI) reduction was achieved. However, WWFA showed higher consumption of HCl and H2O2, the latter resulting in a particularly negative effect on the recovery of Pb and Cu. Thus, co-processing of smaller WWFA portions could be expedient in order to diminish the negative effects of Pb and Cu recovery.

There Reduction of alkali loss in an ash leaching system

There are many points in a kraft mill where the alkaline compounds are purged from the process. Several effluents, solid waste, and air emissions contain alkali, which leads to the necessity of chemical makeups to maintain the liquor balance. The main loss of alkali at the Veracel mill is present in the wastewater from the recovery boiler; more precisely, it is from the ash leaching system, which represents 80% of the total losses. To minimize the alkaline losses while keeping the chloride level in the recovery cycle under control, a project was developed at Veracel. Key actions were taken by adjusting the control loops of the ash leaching system, mainly on the slurry density and purge control. These adjustments led to a decrease in alkali losses and to an increase of treated ash, and kept the chloride level of the recovery boiler dust at 2.6%.