Co-complexation effects during incineration bottom ash leaching via comparison of measurements and geochemical modeling

2018 ◽  
Vol 189 ◽  
pp. 155-168 ◽  
Author(s):  
Ke Yin ◽  
Wei-Ping Chan ◽  
Xiaomin Dou ◽  
Grzegorz Lisak ◽  
Victor Wei-Chung Chang
2011 ◽  
Vol 189 (1-2) ◽  
pp. 435-443 ◽  
Author(s):  
M. Gori ◽  
B. Bergfeldt ◽  
G. Pfrang-Stotz ◽  
J. Reichelt ◽  
P. Sirini

2021 ◽  
Vol Unlabeled volume ◽  
Author(s):  
Ola Hammoud ◽  
Denise Blanc ◽  
Maria Lupsea-Toader ◽  
Christine De Brauer

Mineral trace elements (MTE) constitute an environmental restriction on the recycling of municipal solid waste incineration-bottom ash (MSWI-BA). The study of the speciation of MTE and the factors that control their release allows to predict their behavior under different environmental conditions and, consequently, suggest different actions to expand the management of MSWI-BA.A geochemical modeling led to a better understanding of the speciation of MTE. In this study, target elements were barium, copper, lead, nickel and zinc and the factors that control their release were identified.The results show that the leaching of metals as a function of pH mainly depends on the mineralogical phases. On the other hand, the organic matter has an influence in the leaching of MTE (for Ni, Cu and Pb notably); organic matter presents adsorbent or complexation properties. Les éléments traces métalliques (ETM) constituent une restriction environnementale pour le recyclage des mâchefers d'incinération des déchets non dangereux (MIDND). L'étude de la spéciation des ETM et des facteurs qui contrôlent leur mobilité permet de prédire le comportement des MIDND dans différentes conditions environnementales et de suggérer ensuite des actions pour élargir leur gestion. Une modélisation géochimique des MIDND a permis de mieux comprendre la spéciation des ETM. Dans cette étude, les éléments ciblés étaient le baryum, le cuivre, le plomb, le nickel et le zinc et les facteurs qui régissent leur mobilité ont été définis. Les résultats montrent que la lixiviation des métaux en fonction du pH dépend principalement des phases minéralogiques ; la matière organique joue également un rôle en tant qu'adsorbant ou complexant dans la lixiviation de certains éléments (Ni, Cu et Pb, notamment). Mots-clés Mâchefers d'incinération des déchets non dangereux (MIDND), éléments traces métalliques, capacité de neutralisation acide, modélisation géochimique, PhreeqCI.


Author(s):  
L. L. Sutter ◽  
G. R. Dewey ◽  
J. F. Sandell

Municipal waste combustion typically involves both energy recovery as well as volume reduction of municipal solid waste prior to landfilling. However, due to environmental concerns, municipal waste combustion (MWC) has not been a widely accepted practice. A primary concern is the leaching behavior of MWC ash when it is stored in a landfill. The ash consists of a finely divided fly ash fraction (10% by volume) and a coarser bottom ash (90% by volume). Typically, MWC fly ash fails tests used to evaluate leaching behavior due to high amounts of soluble lead and cadmium species. The focus of this study was to identify specific lead bearing phases in MWC fly ash. Detailed information regarding lead speciation is necessary to completely understand the leaching behavior of MWC ash.


TAPPI Journal ◽  
2017 ◽  
Vol 16 (7) ◽  
pp. 383-391
Author(s):  
CARLA CÉLIA ROSA MEDEIROS ◽  
FLÁVIA AZEVEDO SILVA ◽  
SAULO GODOY PIGNATON ◽  
ESTANISLAU VICTOR ZUTAUTAS ◽  
KLEVERSON FIGUEIREDO

There are many points in a kraft mill where the alkaline compounds are purged from the process. Several effluents, solid waste, and air emissions contain alkali, which leads to the necessity of chemical makeups to maintain the liquor balance. The main loss of alkali at the Veracel mill is present in the wastewater from the recovery boiler; more precisely, it is from the ash leaching system, which represents 80% of the total losses. To minimize the alkaline losses while keeping the chloride level in the recovery cycle under control, a project was developed at Veracel. Key actions were taken by adjusting the control loops of the ash leaching system, mainly on the slurry density and purge control. These adjustments led to a decrease in alkali losses and to an increase of treated ash, and kept the chloride level of the recovery boiler dust at 2.6%.


Author(s):  
Dyah Marganingrum ◽  
Lenny Marilyn Estiaty

Aim: This paper aims to explain the added value increasing method of reject coal which has not utilized by the company. Methodology and Results: The method to increase added value in this study used the agglomeration process of briquettes form that changing composition by adding biomass. The biomass functions to minimize bottom ash produced from burning briquettes so that the briquettes burn entirely. Stages processes in this study consist of characterization, briquetting, physical test, and chemical test. Based on the analysis, reject coal still has a high calorific value of 5,929 cal/gr. Shapes and sizes that were not following needs of coal market or consumer due to reject coal to be a waste. Briquettes have been successfully produced and meet specification requirements based on applicable regulations in Indonesia. Besides physical properties, the briquette meet density requirements which are greater than or equal to 1 gr/cm3 and shatter index value is less than 0.5%. The gas emission test shows below threshold, which is CO 0-30 ppm, H2S 0-3.6 ppm, and NOx is not detected. After evaluation, it showed that by adding 30% biomass, ignition time could be decreased and remaining unburned briquettes or bottom ash was reduced as much as 68.68%. Conclusion, significance and impact study: The bio-coal briquettes is a strategic solution to environmental problems and alternative energy sources that are environmentally friendly, because CO and H2S emissions are still below the threshold, even for NOx not detected. Making Bio-coal briquettes as a solution to the utilization of reject coal mining waste to be used as an alternative energy source has been successfully carried out.


Sign in / Sign up

Export Citation Format

Share Document