Origin of Mesozoic Porphyritic Rocks and Regional Magmatic Evolution in the Zijinshan Ore Field of Fujian Province, China: Hf-O Isotope Characteristics of Magmatic Zircons

Mesozoic porphyritic rocks from the Zijinshan area, southwestern Fujian Province, China, are andesitic to rhyolitic in composition. The whole-rock SiO2 contents of these rocks are between 62.5% and 78.1%. Magmatic zircon from the Mesozoic porphyritic rocks was determined via secondary-ionization mass spectrometry (SIMS) for the U-Pb age and Hf and O isotopes. The zircon U-Pb ages could be mainly divided into three age groups: Group 1: ~138.8 Ma; Group 2: 109.2~107.4 Ma; and Group 3: 99.7~98.2 Ma. The εHf(t) and δ18O values of the porphyritic zircons showed that the porphyritic rocks in Group 2 were more affected by mantle-derived magma. Combined with previous research results, the medium-acidic magmatism in the southwestern Fujian Province can be divided into eight periods: Paleoproterozoic, Mesoproterozoic, Middle Neoproterozoic, Silurian to Lower Devonian, Permian to Triassic, Middle Jurassic to early Lower Cretaceous, late Lower Cretaceous, and late Lower Cretaceous to early Upper Cretaceous. The Paleoproterozoic crust was the predominant magmatic source for the subsequent Mesoproterozoic to Jurassic magmatism, but the only melts that were closely related to mineralization were derived from partial melting of the Mesoproterozoic crust and a more depleted upper mantle.

LA-ICP-MS U–Pb ages of detrital zircons from Middle Jurassic sedimentary rocks in southwestern Fujian: Sedimentary provenance and its geological significance

In order to determine the tectonic regime change of the early Mesozoic in the South China Block, this study analyzed sedimentary rocks in the Middle Jurassic of southwestern Fujian by modal analysis of sandstones, elemental geochemical analysis of mudstones, and detrital zircons U–Pb dating. The results show that the detrital zircons in Southwestern Fujian mainly consist of Paleoproterozoic to early Mesozoic zircons in the Middle Jurassic. Within the Dongkeng profile of the Zhangping Formation, DK5 sample (lower part) showed a major age peak at ca. 1,848 Ma and two secondary age peaks at ca. 235 and 180 Ma, while DK15 sample (middle part) showed a major age peak at ca. 1,876 Ma and two secondary age peaks at ca. 233 and 190 Ma; the age compositions of these two samples’ were similar. Modal analysis of sandstones indicated that sediments of Zhangping Formation might source from arc orogen and recycled orogen, and element geochemical analysis showed that source rocks of Zhangping Formation might be sedimentary rocks and granites. The Indosinian zircons were mainly derived from the Wuyi region, and the Yanshanian zircons were mainly derived from the Nanling region. The major age group changes from ca. 230 to 220 Ma of the Late Triassic – Early Jurassic to ca. 190 to 180 Ma of the Middle Jurassic in Southwestern Fujian, and main sources changed from Indosinian magmatic rocks in the Late Triassic – Early Jurassic to early Yanshanian magmatic rocks in the Middle Jurassic.

Quantifying the Distribution Characteristics of Geochemical Elements and Identifying Their Associations in Southwestern Fujian Province, China

The distribution of geochemical elements in the surficial media is the end product of geochemical dispersion under complex geological conditions. This study explored the frequency and spatial distribution characteristics of geochemical elements and their associations. It quantifies the frequency distribution via mean, variance, skewness and kurtosis, followed by measuring the spatial distribution characteristics (i.e., spatial autocorrelation, heterogeneity and self-similarity) via semivariogram, q-statistic and multifractal spectrum, and further identify the elemental associations based on these distribution parameters using hierarchical clustering. A criterion was defined to identify the importance of parameters in the clustering procedure. A case study processing a geochemical dataset of stream sediment samples collected in southwestern Fujian province of China was carried out to illustrate and validate the procedure. The results indicate that studies of the frequency and spatial distribution characteristics of geochemical elements can enhance the knowledge of geochemical dispersions. The associations identified based on the frequency and spatial distribution parameters are different from those obtained by conventional cluster analysis. Spatial distribution characteristics cannot be neglected when investigating the distribution patterns of geochemical elements and their associations. The findings can enhance the knowledge of the geochemical dispersion in the study area and might benefit the following-up mineral exploration.

Detrital zircon U–Pb dating of Late Triassic Wenbinshan Formation in southwestern Fujian, South China, and its geological significance

Based on research of the petrology, geochemistry, and zircon U–Pb dating of detrital rocks in the Late Triassic Wenbinshan Formation in southwestern Fujian, and comparing the detrital zircon ages of Wenbinshan Formation with those of Late Paleozoic – Early Mesozoic main basins in South China, the sedimentary provenance of the Late Triassic in southwestern Fujian and its implications for changes in basin properties are discussed. The research results demonstrate that there is a major age peak at 222 Ma, two subordinate age peaks at 275 Ma and 1851 Ma, and two minor age peaks at 413 Ma and 2447 Ma in the detrital zircon age spectra of the upper samples (YGP–6) of the Wenbinshan Formation, whereas there are two major age peaks at 229 Ma and 1817 Ma and other minor age peaks 265 Ma 309 Ma, 415 Ma, 1968 Ma, and 2435 Ma in the detrital zircon age spectra of the lower samples (YGP–26) of the Wenbinshan Formation. The upper samples contain fewer old detrital zircons than the lower samples, but the upper and lower samples of Wenbinshan Formation are similar in major age composition, which indicates the main provenances of the upper and lower sediments are very similar. The source rocks are mainly sedimentary rocks and their provenances are derived from a source area of recycled orogenic belt and volcanic arc orogenic belt (acidic island arc). The detrital zircon composition of the Wenbinshan Formation is mainly composed of Paleoproterozoic zircon and Late Paleozoic – Early Mesozoic zircon. In the Paleoproterozoic, sedimentary provenances were mainly derived from the Wuyi Massif and partly from northwestern Fujian-southwestern Zhejiang. As for the period of Late Paleozoic – Early Mesozoic, the provenances of the Wenbinshan Formation were derived from magmatic active belts of the Early Indosinian Epoch of northern South China, eastern South China, and the Indosinian Period of northern South China and coastal areas of eastern South China. The similarities and differences between detrital zircon age peaks of the Wenbinshan Formation in southwestern Fujian and that of the main basins in South China during the period of Late Paleozoic – Early Mesozoic indicate that from eastern coastal areas of South China to the north and interior of South China, the age composition of basin sediments has changed from simple to relatively complex, and from young sediments to older sediments. There are similarities and differences in the detrital zircon compositions of the different basins, which can indicate differences in the nature of the basins.