Morphology-Dependent Room-Temperature Ferromagnetism in Undoped ZnO Nanostructures

Since Dietl et al. predicted that Co-doped ZnO may show room-temperature ferromagnetism (RTFM) in 2000, researchers have focused on the investigation of ferromagnetic ZnO doped with various transition metals. However, after decades of exploration, it has been found that undoped ZnO nanostructures can also show RTFM, which in general is dependent on ZnO morphologies. Here, we will give an overall review on undoped ZnO nanomaterials with RTFM. The advanced strategies to achieve multidimensional (quasi-0D, 1D, 2D, and 3D) ferromagnetic ZnO nanostructures and the mechanisms behind RTFM are systematically presented. We have successfully prepared ferromagnetic nanostructures, including thin films, horizontal arrays and vertical arrays. The existing challenges, including open questions about quantum-bound ZnO nanostructures, are then discussed.

Asymmetric Hysteresis Loops in Structured Ferromagnetic Nanoparticles with Hard/Soft Areas

Horizontally shifted and asymmetric hysteresis loops are often associated with exchange-biased samples, consisting of a ferromagnet exchange coupled with an antiferromagnet. In purely ferromagnetic samples, such effects can occur due to undetected minor loops or thermal effects. Simulations of ferromagnetic nanostructures at zero temperature with sufficiently large saturation fields should not lead to such asymmetries. Here we report on micromagnetic simulations at zero temperature, performed on sputtered nanoparticles with different structures. The small deviations of the systems due to random anisotropy orientations in the different grains can not only result in strong deviations of magnetization reversal processes and hysteresis loops, but also lead to distinctly asymmetric, horizontally shifted hysteresis loops in purely ferromagnetic nanoparticles.

Asymmetric Hysteresis Loops and Horizontal Loop Shifts in Purely Ferromagnetic Nanoparticles

Horizontally shifted and asymmetric hysteresis loops are often associated with exchange-biased samples, consisting of a ferromagnet exchange-coupled with an antiferromagnet. In purely ferromagnetic samples, such effects can occur due to undetected minor loops or thermal effects. Simulations of ferromagnetic nanostructures at zero temperature with sufficiently large saturation fields should not lead to such asymmetries. Here we report on micromagnetic simulations at zero temperature, performed on sputtered nanoparticles with different shapes. The small deviations of the systems due to random anisotropy orientations in the different grains can not only result in strong deviations of magnetization reversal processes and hysteresis loops, but also to distinctly asymmetric, horizontally shifted hysteresis loops in purely ferromagnetic nanoparticles.