A Simple Method to Determine Critical Coagulation Concentration from Electrophoretic Mobility

Critical coagulation concentration (CCC) is a key parameter of particle dispersions, since it provides the threshold limit of electrolyte concentrations, above which the dispersions are destabilized due to rapid particle aggregation. A computational method is proposed to predict CCC values using solely electrophoretic mobility data without the need to measure aggregation rates of the particles. The model relies on the DLVO theory; contributions from repulsive double-layer forces and attractive van der Waals forces are included. Comparison between the calculated and previously reported experimental CCC data for the same particles shows that the method performs well in the presence of mono and multivalent electrolytes provided DLVO interparticle forces are dominant. The method is validated for particles of various compositions, shapes, and sizes.

Rectification of bipolar nanopores in multivalent electrolytes: effect of charge inversion and strong ionic correlations

The conductance properties of bipolar nanopores change non-monotonically with surface charge in the presence of multivalent ions due to charge inversion.