Global nighttime atomic oxygen abundances from GOMOS hydroxyl airglow measurements in the mesopause region

This paper presents a new dataset of nighttime atomic oxygen density [O], derived from OH(8–4) ro-vibrational band emissions, using a non-local thermal equilibrium model, with the aim of offering new insight into the atomic oxygen abundances in the mesopause region. The dataset is derived from the level-1 atmospheric background measurements observed by the Global Ozone Monitoring by Occultation of Stars (GOMOS) instrument aboard Envisat, with the Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) measurements for the atmospheric background. Raw data are reprocessed into monthly zonal mean values in 10∘ latitude bins with a fixed altitude grid of 3 km. The dataset spans from 70∘ S to 70∘ N in latitude and from 80 to 100 km in altitude, covering a time period from May 2002 to December 2011 at local times from 22:00 to 00:00 LT. The atomic oxygen density peaks at about 95 km and the highest values are in the range of 3–8 × 1011 atoms cm−3, depending on latitude and season. There is a rapid decrease of [O] below the peak. The annual oscillation (AO), semiannual oscillation (SAO) and the solar cycle impact are distinguished from the [O] longtime series variations. This new GOMOS [O] dataset conforms to other published datasets and is consistent with the [O] datasets obtained from the Scanning Imaging Absorption Spectrometer for Atmospheric CHartographY (SCIAMACHY) OH airglow measurements within about ±20 %.

Global nighttime atomic oxygen abundances from resampled GOMOS hydroxyl airglow measurements in the mesopause region

This paper presents a new dataset of nighttime atomic oxygen density [O], derived from OH(8–4) ro-vibrational band emissions, using a non-local thermal equilibrium model, with the aim of offering new insight into the atomic oxygen abundances in the mesopause region. The dataset is based on the level-1 atmospheric background measurements observed by the GOMOS instrument on board Envisat. Raw data are reprocessed into monthly zonal mean values in 10° latitude bins with a fixed altitude grid of 3 km. The dataset spans from 70° S to 70° N in latitude and from 80 km to 100 km in altitude, covering a time period from May 2002 to December 2011 at local times of from 10 p.m. to 12 p.m. The atomic oxygen density peaks at about 95 km and the highest values are in the range of 3–8 × 1011 atoms cm−3, depending on latitude and season. There is a rapid decrease of [O] below its peak region. The annual oscillation (AO), semiannual oscillation (SAO), and the solar cycle impact are distinguished from the [O] longtime series variations. This new GOMOS [O] dataset conforms to other published datasets and is consistent with the [O] datasets obtained from the SCIAMACHY OH airglow measurements to within about ±20 %.

Optimizing hydroxyl airglow retrievals from long-slit astronomical spectroscopic observations

Astronomical spectroscopic observations from ground-based telescopes contain background emission lines from the terrestrial atmosphere's airglow. In the near infrared, this background is composed mainly of emission from Meinel bands of hydroxyl (OH), which is produced in highly excited vibrational states by reduction of ozone near 90 km. This emission contains a wealth of information on the chemical and dynamical state of the Earth's atmosphere. However, observation strategies and data reduction processes are usually optimized to minimize the influence of these features on the astronomical spectrum. Here we discuss a measurement technique to optimize the extraction of the OH airglow signal itself from routine J-, H-, and K-band long-slit astronomical spectroscopic observations. As an example, we use data recorded from a point-source observation by the Nordic Optical Telescope's intermediate-resolution spectrograph, which has a spatial resolution of approximately 100 m at the airglow layer. Emission spectra from the OH vibrational manifold from v′ = 9 down to v′ = 3, with signal-to-noise ratios up to 280, have been extracted from 10.8 s integrations. Rotational temperatures representative of the background atmospheric temperature near 90 km, the mesosphere and lower thermosphere region, can be fitted to the OH rotational lines with an accuracy of around 0.7 K. Using this measurement and analysis technique, we derive a rotational temperature distribution with v′ that agrees with atmospheric model conditions and the preponderance of previous work. We discuss the derived rotational temperatures from the different vibrational bands and highlight the potential for both the archived and future observations, which are at unprecedented spatial and temporal resolutions, to contribute toward the resolution of long-standing problems in atmospheric physics.

Effect of water vapour absorption on hydroxyl temperatures measured from Svalbard

We model absorption by atmospheric water vapour of hydroxyl airglow emission using the HIgh-resolution TRANsmission molecular absorption database (HITRAN2012). Transmission coefficients are provided as a function of water vapour column density for the strongest OH Meinel emission lines in the (8–3), (5–1), (9–4), (8–4), and (6–2) vibrational bands. These coefficients are used to determine precise OH(8–3) rotational temperatures from spectra measured by the High Throughput Imaging Echelle Spectrograph (HiTIES), installed at the Kjell Henriksen Observatory (KHO), Svalbard. The method described in this paper also allows us to estimate atmospheric water vapour content using the HiTIES instrument.