Litho-Based Pore Scale Waterflooding in Carbonate Reservoirs: A Holistic Approach to Predict Displacement Efficiency

Grainstones deposited on carbonate ramps are excellent petroleum reservoir formations and are important for energy needs. Waterflooding is routinely used to augment oil recovery and many carbonate fields have long production histories. Future management of these "mature" assets requires knowledge of how oil production can be sustained and enhanced but requires understanding the pore-scale displacement processes. Despite decades of waterflooding in carbonate oilfields a plausible displacement efficiency prediction is not yet trivial. To evaluate waterflooding economics, it is crucial to know the residual oil saturation (Sor) and where oil is entrapped by capillarity in the reservoir. Microfluidic waterflooding experiments provide a means to visualize pore-scale phenomena within different carbonate minerals (calcite, dolomite, and gypsum) and petrographic textures, to estimate microscopic displacement efficiency. By using analogues of carbonate ramp reservoir-lithologies (in terms of texture, unstructured-irregular pore networks and varied mineralogical compositions) realistic evaluations of displacement efficiency were determined for different mineralogical compositions. The quantitative test results matched closely Arab formation SCAL published data. It was determined that multi-mineralic grainstones undergoing waterflood likely experience contemporaneous imbibition and drainage, giving rise to complex multiphase flow due to the existence of different states of wettability. This wettability contrast induces "capillary jumps" across wettability-boundaries at the interface between different lamina or textures. These "capillary leaps" account for increase in oil recovery as they occur but leave behind bypassed oil. Consequently poly-mineralic arrangements have a lower oil recovery compared to mono-mineralic cases. It was observed that distinct Sor are achieved at different injected pore volumes, despite sharing similar porosity & permeability, thus the relationship between Sor and porosity/permeability is weak. Thus, predicting waterflooding efficiency requires the different carbonate minerals Sor to be incorporated in dynamic simulation.

Hydrodynamic influences on sedimentology and geomorphology of nearshore parts of carbonate ramps: Holocene, NE Yucatán Shelf, Mexico

ABSTRACT Although carbonate ramps are ubiquitous in the geologic record, the impacts of oceanographic processes on their facies patterns are less well constrained than with other carbonate geomorphic forms such as isolated carbonate platforms. To better understand the role of physical and chemical oceanographic forces on geomorphic and sedimentologic variability of ramps, this study examines in-situ field measurements, remote-sensing data, and hydrodynamic modeling of the nearshore inner ramp of the modern northeastern Yucatán Shelf, Mexico. The results reveal how sediment production and accumulation are influenced by the complex interactions of the physical, chemical, and biological processes on the ramp. Upwelled, cool, nutrient-rich waters are transported westward across the ramp and concentrated along the shoreline by cold fronts (Nortes), westerly regional currents, and longshore currents. This influx supports a mix of both heterozoan and photozoan fauna and flora in the nearshore realm. Geomorphically, the nearshore parts of this ramp system in the study area include lagoon, barrier island, and shoreface environments, influenced by the mixed-energy (wave and tidal) setting. Persistent trade winds, episodic tropical depressions, and winter storms generate waves that propagate onto the shoreface. Extensive shore-parallel sand bodies (beach ridges and subaqueous dune fields) of the high-energy, wave-dominated upper shoreface and foreshore are composed of fine to coarse skeletal sand, lack mud, and include highly abraded, broken and bored grains. The large shallow lagoon is mixed-energy: wave-dominated near the inlet, it transitions to tide-dominated in the more protected central and eastern regions. Lagoon sediment consists of Halimeda-rich muddy gravel and sand. Hydrodynamic forces are especially strong where bathymetry focuses water flow, as occurs along a promontory and at the lagoon inlet, and can form subaqueous dunes. Explicit comparison among numerical models of conceptual shorefaces in which variables are altered and isolated systematically demonstrates the influences of the winds, waves, tides, and currents on hydrodynamics across a broad spectrum of settings (e.g., increased tidal range, differing wind and wave conditions). Results quantify how sediment transport patterns are determined by wave height and direction relative to the shoreface, but tidal forces locally control geomorphic and sedimentologic character. Similarly, the physical oceanographic processes acting throughout the year (e.g., daily tides, episodic winter Nortes, and persistent easterly winds and waves) have more impact on geomorphology and sedimentology of comparable nearshore systems than intense, but infrequent, hurricanes. Overall, this study provides perspectives on how upwelling, nutrient levels, and hydrodynamics influence the varied sedimentologic and geomorphic character of the nearshore areas of this high-energy carbonate ramp system. These results also provide for more accurate and realistic conceptual models of the depositional variability for a spectrum of modern and ancient ramp systems.

Manganese carbonate stromatolites of the Ediacaran Doushantuo Formation in Chengkou, northern Yangtze Craton, China

The origin process of manganese ores remains unsolved worldwide. Exploring the origins of stromatolites that contain manganese may be a key to deciphering the sedimentary environments and metallogenic processes of these deposits. However, only a few manganese stromatolites have been discovered and described until now. Microbialites are well developed in the manganese deposits, located near the top of the Ediacaran Doushantuo Formation in Chengkou area of Chongqing, northern Yangtze Craton, but has not been explicitly studied; and whether they are true stromatolites or Epiphyton microbialites remains controversial. Based on field and core observations and thin section microscopy, the characteristics of five types of manganese stromatolites and their growth modes are described in detail in this study. The results show that these stromatolites grew in a biostrome in shoal and lagoon environments and were syngenetic with oncolites and oolites on a carbonate ramp behind the shoal. Manganese stromatolites can be categorized into three forms: (1) stratiform; (2) columnar, which includes branched and columnar types; and (3) stratiform-columnar, which is a transitional type. Based on a criterion that the diameter is less than or greater than 1 mm, columnar stromatolites are further divided into micro-columnar (< 1 mm) and columnar (> 1 mm) columns, which display synchronous growth and are similar to Pseudogymnosolenaceae. Their shapes are mainly controlled by water depths and hydrodynamic strengths. The greater the water depth, the more columnar the columns tend to be. Excessively strong hydrodynamic conditions decrease the growth rate of stromatolites, and they even stopped growth due to wave damage. Furthermore, pillared laminar textures (not Epiphyton), which consist of dendritic, micro-branched and micro-columnar stromatolites, are a common feature of the larger stratiform, stratiform-columnar and columnar stromatolites. The alternations of laminae with different internal textures record subtle fluctuations in water depths and hydrodynamic strengths, which indicate that stromatolite growth is controlled by tidal cycles at the lamina level. Therefore, it is possible that the vertical evolution of the stromatolites could reveal the changing characteristics of both local and regional sedimentary environments, i.e., stromatolite shape changes from columnar to stratiform can represent the onset of shallower environments with weak hydrodynamic conditions. In addition, as important reef builders in shallow carbonate ramps, microstromatolites accelerate the development from ramp to platform. Indicators of microbial control on stromatolite shapes and manganese sedimentation processes include the fabric of stromatolite laminae, organic rhodochrosite with a micritic texture that is usually clotted, spherical, tubular, fibrous or dendritic, which suggests that the laminae resulted from microbially induced in situ precipitation.

Anoxia and salinity changes: a new Permian catastrophe record

Bituminous shales are associated to worldwide geological events, such as mass extinction, anoxia and climatic changes, mainly when preserved in carbonate ramps, and constitute reliable records of this dynamics. However, a minority of data still exist that measure the Permian, especially in the Southern Hemisphere associated to Panthalassic Ocean as compared to numerous studies of Oceanic Anoxic Events in the Cretaceous or associated to Tethys. The Late Permian extinction was the most severe extinction of the past 500 million years, which wiped out over 90 % of marine species. Before the Permian-Triassic boundary (e.g. Early-Middle Permian successions) geochemical and geological anomalous aspects has received more attention due the information about the Late Paleozoic icehouse-greenhous transitions, which is one of the triggers for the catastrophic ectinction. Therefore the Irati Formation, Permian interval of Paraná Basin in southern Brazil, is suitable for the study of these intricate processes due to the presence of Permian bituminous shales and carbonates. Based on core descriptions, spectral gamma ray data and organic geochemistry, a stratigraphic scheme is here proposed to support paleoenvironmental inferences. We identified three depositional sequences formed internally by T-R cycles of highest frequency. The sedimentary facies analysis indicates a carbonate ramp subdivided into outer, middle and inner. Climatic and sea level changes are defined, and also oscillations in the salinity, oxygenation and organic matter source. Bituminous shales record normal salinity, with anoxia levels and even euxinia, associated to the increase in bioproductivity. Carbonate facies register periods of hypersalinity under oxic environment and semi-arid conditions. The accumulation of Mesosaurus skeletal remains results from the action of reworking fluxes, creating an endemic facies in this region. Climatic versus eustatic influence were differentiated, and also the controlling hierarchies. These results are evidence for the environmental dynamics from the Permian, that generated extreme global events, mainly in Gondwana.

A Middle Triassic pachypleurosaur (Diapsida: Eosauropterygia) from a restricted carbonate ramp in the Western Carpathians (Gutenstein Formation, Fatric Unit): paleogeographic implications

An eosauropterygian skeleton found in the Middle Triassic (upper Anisian) Gutenstein Formation of the Fatric Unit (Demänovská dolina Valley, Low Tatra Mountains, Slovakia) represents the earliest known occurrence of marine tetrapods in the Western Carpathians. The specimen represents a partly articulated portion of the postcranial skeleton (nine dorsal vertebrae, coracoid, ribs, gastral ribs, pelvic girdle, femur and one zeugopodial element). It is assigned to the Pachypleurosauria, more precisely to theSerpianosaurus–Neusticosaurusclade based on the following combination of features: (1) small body size; (2) morphology of vertebrae, ribs and femur; (3) tripartite gastral ribs; and (4) microanatomy of the femur as revealed by μCT. Members of this clade were described from the epicontinental Germanic Basin and the Alpine Triassic (now southern Germany, Switzerland, Italy), and possibly from Spain. This finding shows that pachypleurosaur reptiles attained a broader geographical distribution during the Middle Triassic, with their geographical range reaching to the Central Western Carpathians. Pachypleurosaurs are often found in sediments formed in shallow, hypersaline carbonate-platform environments. The specimen found here occurs in a succession with vermicular limestones in a shallow subtidal zone and stromatolitic limestones in a peritidal zone, indicating that pachypleurosaurs inhabited hypersaline, restricted carbonate ramps in the Western Carpathians.