Extraction, Characterization and Rheological Behavior of Tamarind Gum Under High Salinity

The objective of this work was to obtain tamarind gum from Tamarindus indica L. seeds, which are waste from the food industry. Tamarind gum was extracted by two methods and the highest yield achieved was 32.6% w/w, containing 69.25% w/w of organic matter, which was composed mostly of the nonionic polysaccharide xyloglucan. The greatest molar mass of the tamarind gum was Mw=7.16 x 105 g/mol with polydispersity index (PI) of 1.7. Evaluation of the rheological behavior of tamarind gum samples were carried out in two brines (total dissolved solids values of 29,711 mg/L and 68,317 mg/L, containing divalent ions) that simulated petroleum reservoir salinity levels, with different temperatures (25, 60 and 80°C). The rheological curves indicated high salt resistance of the gum samples. Under a shear rate of 7.3 s-1 the highest viscosity values found were approximately 86, 41 and 50 cP with at concentration of 5,000 ppm and temperatures of 25, 60 and 80ºC, respectively.

Litho-Based Pore Scale Waterflooding in Carbonate Reservoirs: A Holistic Approach to Predict Displacement Efficiency

Grainstones deposited on carbonate ramps are excellent petroleum reservoir formations and are important for energy needs. Waterflooding is routinely used to augment oil recovery and many carbonate fields have long production histories. Future management of these "mature" assets requires knowledge of how oil production can be sustained and enhanced but requires understanding the pore-scale displacement processes. Despite decades of waterflooding in carbonate oilfields a plausible displacement efficiency prediction is not yet trivial. To evaluate waterflooding economics, it is crucial to know the residual oil saturation (Sor) and where oil is entrapped by capillarity in the reservoir. Microfluidic waterflooding experiments provide a means to visualize pore-scale phenomena within different carbonate minerals (calcite, dolomite, and gypsum) and petrographic textures, to estimate microscopic displacement efficiency. By using analogues of carbonate ramp reservoir-lithologies (in terms of texture, unstructured-irregular pore networks and varied mineralogical compositions) realistic evaluations of displacement efficiency were determined for different mineralogical compositions. The quantitative test results matched closely Arab formation SCAL published data. It was determined that multi-mineralic grainstones undergoing waterflood likely experience contemporaneous imbibition and drainage, giving rise to complex multiphase flow due to the existence of different states of wettability. This wettability contrast induces "capillary jumps" across wettability-boundaries at the interface between different lamina or textures. These "capillary leaps" account for increase in oil recovery as they occur but leave behind bypassed oil. Consequently poly-mineralic arrangements have a lower oil recovery compared to mono-mineralic cases. It was observed that distinct Sor are achieved at different injected pore volumes, despite sharing similar porosity & permeability, thus the relationship between Sor and porosity/permeability is weak. Thus, predicting waterflooding efficiency requires the different carbonate minerals Sor to be incorporated in dynamic simulation.

Smart Optimization of Proactive Control of Petroleum Reservoir

Artificial Intelligence plays an increasingly important role in many industrial applications as it has great potential for solving complex engineering problems. One of such applications is the optimization of petroleum reservoirs production. It is crucial to produce hydrocarbons efficiently as their geological resources are limited. From an economic point of view, optimization of hydrocarbon well control is an important factor as it affects the whole market. The solution proposed in this paper is based on state-of-the-art artificial intelligence methods, optimal control, and decision tree theory. The proposed idea is to apply a novel temporal clustering algorithm utilizing an autoencoder for temporal dimensionality reduction and a temporal clustering layer for cluster assignment, to cluster wells into groups depending on the production situation that occurs in the vicinity of the well, which allows reacting proactively. Then the optimal control of wells belonging to specific groups is determined using an auto-adaptive decision tree whose parameters are optimized using a novel sequential model-based algorithm configuration method. Optimization of petroleum reservoirs production translates directly into several economic benefits: reduction in operation costs, increase in the production effectiveness and increase in overall income without any extra expenditure as only control is changed. This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

Numerical Identification of the Filtration Capacitive Parameters in Two-Phase Petroleum Reservoirs

We study initial and boundary value problem for nonlinear three dimensional two phase nonlinear filtration problem in three dimensional bounded regions. The reservoir is a two phase and three dimensional oil-water system that is been implemented with typical parallelepiped model. The reservoir constructed with different number of grid blocks in x, y and z directions and initialized with initial pressure, water saturation, corresponding fluid and rock properties in every grid block. To find approximate solution of the above mentioned problem we use finite difference method. We form solution’s algorithm of inverse problem for numerical parameter identification of the petroleum reservoir.

Distribution of the Initial Fluid Composition in an Oil-Gas-Condensate Reservoir with Incomplete Gravity Segregation

It is known that initial composition of the hydrocarbon fluid in a petroleum reservoir changes significantly with depth due to the influence of gravity and geothermal gradient. Classical models of these phenomena are based on the assumption of equilibrium (quasiequilibrium) distribution of component concentrations in the gravity field with the presence of stationary thermodiffusional flux. However, there are typical situations in gas condensate reservoirs when the quasi-equilibrium conditions are not met. For example, this is true if immobile residual oil exists in the reservoir or for deep tight formations where gravity segregation is not completed. For such cases, modified models are required. They are proposed in this paper to take into account the non-equilibrium conditions of the initial fluid composition distribution in gas condensate (or oil-gas-condensate) reservoirs.

Last Cretaceous Geology of Taranaki Basin, New Zealand

<p>Taranaki Basin is a large sedimentary basin located along the western side of New Zealand, which contains all of this countries present petroleum production. The basin first formed as the late-Cretaceous Taranaki Rift, and the first widespread sediments are syn-rift deposits associated with this continental rifting. The Taranaki Rift was an obliquely extensional zone which transferred the movement associated with the opening of the New Caledonia Basin southward to the synchronous Tasman Sea oceanic spreading. Along the rift a series of small, en-echelon basins opened, controlled by high-angle normal and strike-slip faults. These small basins presently underlie the much larger Taranaki Basin. Since the initial rift phase, Taranaki Basin has undergone a complex Cenozoic history of subsidence, compression, additional rifting, and minor strike-slip faulting, all usually involving reactivation of the late-Cretaceous rift-controlling faults. One of the late-Cretaceous rift basins is the Pakawau Basin. Rocks deposited in this basin outcrop in Northwest Nelson as the Pakawau Group. Data from the outcrop and from wells drilled in the basin allow the Pakawau Group to be divided into two formations, the Rakopi Formation and the North Cape Formation, each with recognizable members. The Rakopi Formation (new name) is a sequence of terrestrial strata deposited by fans and meandering streams in an enclosed basin. The North Cape Formation is a transgressive sequence of marine, paralic and coastal-plain strata deposited in response to regional flooding of the rift. The coal-measure strata of the Rakopi Formation are organic rich, and are potential petroleum source rocks where buried deeply enough. In contrast, the marine portions of the North Cape Formation contain almost no organic matter and cannot be considered a potential source rock. Sandy facies within both formations have petroleum reservoir potential. The Rakopi and North Cape formations can be correlated with strata intersected by petroleum exploration wells throughout Taranaki Basin, and all syn-rift sediments can be assigned to them. The Taranaki Rift was initiated about 80 Ma, as recorded by the oldest sediments in the Rakopi Formation. The transgression recorded in the North Cape Formation propagated southwards from about 72 to 70 Ma, and the Taranaki Rift remained a large marine embayment until the end of the Cretaceous about 66.5 Ma. Shortly thereafter, a Paleocene regression caused the southern portions of Taranaki Basin to revert to terrestrial (Kapuni Group) sedimentation. The two distinct late Cretaceous sedimentary sequences of the Rakopi and North Cape formations can be identified on seismic reflection data, and the basal trangressive surface that separates them has been mapped throughout the basin. This horizon essentially marks the end of sedimentation in confined, terrestrial subbasins, and the beginning of Taranaki Basin as a single, continental-margin-related basin. Isopach maps show the Rakopi Formation to be up to 3000m thick and confined to fault- controlled basins. The North Cape Formation is up to 1500m thick and was deposited in a large north-south embayment, open to the New Caledonia basin to the northwest. This embayment was predominantly a shallow-marine feature, with shoreline and lower coastal plain facies deposited around its perimeter</p>

Last Cretaceous Geology of Taranaki Basin, New Zealand

<p>Taranaki Basin is a large sedimentary basin located along the western side of New Zealand, which contains all of this countries present petroleum production. The basin first formed as the late-Cretaceous Taranaki Rift, and the first widespread sediments are syn-rift deposits associated with this continental rifting. The Taranaki Rift was an obliquely extensional zone which transferred the movement associated with the opening of the New Caledonia Basin southward to the synchronous Tasman Sea oceanic spreading. Along the rift a series of small, en-echelon basins opened, controlled by high-angle normal and strike-slip faults. These small basins presently underlie the much larger Taranaki Basin. Since the initial rift phase, Taranaki Basin has undergone a complex Cenozoic history of subsidence, compression, additional rifting, and minor strike-slip faulting, all usually involving reactivation of the late-Cretaceous rift-controlling faults. One of the late-Cretaceous rift basins is the Pakawau Basin. Rocks deposited in this basin outcrop in Northwest Nelson as the Pakawau Group. Data from the outcrop and from wells drilled in the basin allow the Pakawau Group to be divided into two formations, the Rakopi Formation and the North Cape Formation, each with recognizable members. The Rakopi Formation (new name) is a sequence of terrestrial strata deposited by fans and meandering streams in an enclosed basin. The North Cape Formation is a transgressive sequence of marine, paralic and coastal-plain strata deposited in response to regional flooding of the rift. The coal-measure strata of the Rakopi Formation are organic rich, and are potential petroleum source rocks where buried deeply enough. In contrast, the marine portions of the North Cape Formation contain almost no organic matter and cannot be considered a potential source rock. Sandy facies within both formations have petroleum reservoir potential. The Rakopi and North Cape formations can be correlated with strata intersected by petroleum exploration wells throughout Taranaki Basin, and all syn-rift sediments can be assigned to them. The Taranaki Rift was initiated about 80 Ma, as recorded by the oldest sediments in the Rakopi Formation. The transgression recorded in the North Cape Formation propagated southwards from about 72 to 70 Ma, and the Taranaki Rift remained a large marine embayment until the end of the Cretaceous about 66.5 Ma. Shortly thereafter, a Paleocene regression caused the southern portions of Taranaki Basin to revert to terrestrial (Kapuni Group) sedimentation. The two distinct late Cretaceous sedimentary sequences of the Rakopi and North Cape formations can be identified on seismic reflection data, and the basal trangressive surface that separates them has been mapped throughout the basin. This horizon essentially marks the end of sedimentation in confined, terrestrial subbasins, and the beginning of Taranaki Basin as a single, continental-margin-related basin. Isopach maps show the Rakopi Formation to be up to 3000m thick and confined to fault- controlled basins. The North Cape Formation is up to 1500m thick and was deposited in a large north-south embayment, open to the New Caledonia basin to the northwest. This embayment was predominantly a shallow-marine feature, with shoreline and lower coastal plain facies deposited around its perimeter</p>

Cretaceous–Quaternary seismic stratigraphy of the Tanga offshore Basin in Tanzania and its petroleum potential

In this study, the available 2D seismic lines have been interpreted to understand the basin development and petroleum potential of the Late Cretaceous–Quaternary stratigraphy of the Tanga offshore Basin in Tanzania. Conventional seismic interpretation has delineated eight sedimentary fill geometries, fault properties, stratal termination patterns and unconformities characterizing the studied stratigraphy. The Late Cretaceous was found to be characterized by tectonic quiescence and uniform subsidence where slope induced gravity flows that resulted during the Miocene block movements was the major mechanism of sediment supply into the basin. The Quaternary was dominated by extensional regime that created deep N-S to NNE-SSW trending graben. The graben accommodated thick Pleistocene and Holocene successions deposited when the rate of tectonic uplift surpasses the rate of sea level rise. Thus, the deposition of lowstand system tracts characterized by debris flow deposits, slope fan turbidites, channel fill turbidites and overbank wedge deposits, known for their excellent petroleum reservoir qualities, especially where charged by Karoo Black Shales. Subsequent tectonic quiescence and transgression lead to the emplacement of deep marine deposits with characteristic seismic reflection patterns that indicate the occurrence of Quaternary shale sealing rocks in the study area. The occurrence of all the necessary petroleum play systems confirms the hydrocarbon generation, accumulations and preservation potential in the Tanga Basin.

Mathematical Modelling and Simulation for One Dimensional - Two-Phase Flow Equation in Petroleum Reservoir: A Matlab Algorithm Approach

The reservoir behaviors described by a set of differential equation those results from combining Darcy’s law and the law of mass conservation for each phase in the system. The one-dimensional two-phase flow equation is implicit in the pressure and saturation and explicit in relative permeability. A mathematical model of a physical system is a set of partial differential equations together with an appropriate set of boundary conditions, which describes the significant physical processes taking place in that system. The processes occurring in petroleum reservoirs are fluid flow and mass transfer. Two immiscible phases (water& oil) flow simultaneously while mass transfer may take place among the phases. Gravity, capillary, and viscous forces play a role in the fluid-flow process. The model equations must account for all these forces and should also take into account an arbitrary reservoir description with respect to heterogeneity and geometry. Finally, one-dimensional two-phase flow equation through porous media is formulated by considering above reservoir parameters and forces. A numerical method based on finite difference scheme is implemented to get the solutions of one-dimensional two-phase flow equation. A MATLAB algorithm is used to solve the equation with mathematical analysis resulting in upper and lower bounds for the ratio of time step to mesh. The MATLAB algorithm is modified as per the model with appropriate initial and boundary conditions. The algorithm is applied to two-phase water flooding problems in laboratory size cores, and resulting saturation and pressure distribution are presented graphically. The saturation and pressure distribution of two-phase flow model is in agreement with the prediction of the Buckley Leveret theory. The numerical solution is used as a base for evaluating the numerical methods with respect to machine time requirement and allowable tie step for fixed mesh spacing.