Blue-Gap Poly(p-phenylene vinylene)s with Fluorinated Double Bonds: Interplay Between Supramolecular Organization and Optical Properties in Thin Films

2009 ◽  
Vol 21 (10-11) ◽  
pp. 1115-1120 ◽  
Author(s):  
Maria Losurdo ◽  
Maria M. Giangregorio ◽  
Pio Capezzuto ◽  
Antonio Cardone ◽  
Carmela Martinelli ◽  
...  
Author(s):  
C. Bubeck ◽  
A. Kaltbeitzel ◽  
R. W. Lenz ◽  
D. Neher ◽  
J. D. Stenger-Smith ◽  
...  

1998 ◽  
Vol 227 (1-2) ◽  
pp. 65-74 ◽  
Author(s):  
H.J. Brouwer ◽  
V.V. Krasnikov ◽  
T.A. Pham ◽  
R.E. Gill ◽  
P.F. van Hutten ◽  
...  

Polymer ◽  
2008 ◽  
Vol 49 (19) ◽  
pp. 4133-4140 ◽  
Author(s):  
Maria Losurdo ◽  
Maria M. Giangregorio ◽  
Pio Capezzuto ◽  
Giovanni Bruno ◽  
Francesco Babudri ◽  
...  

2015 ◽  
Vol 1109 ◽  
pp. 534-538
Author(s):  
Najwa Ezira Ahmed Azhar ◽  
A.K.S. Shafura ◽  
Irma Hidayanti Halim Affendi ◽  
Shafinaz Sobihana Shariffudin ◽  
Mohamad Rusop

Poly (2-methoxy-5(2’-ethylhexyloxy)-phenylene vinylene) (MEH-PPV) thin films were deposited by spin-coating technique. The MEH-PPV powders were dissolved in toluene solution. In this study, we report the effect of ageing on electrical and optical properties MEH-PPV thin films. The thickness of MEH-PPV increased as ageing time increased. The electrical properties were obtained using 2-point probe. The resistivity of thin films decreased as ageing time increased and vice versa with conductivity. The optical properties were investigated using UV-Visible-NIR (UV-VIS-NIR) and atom force microscope (AFM). From UV-Vis result shows the lower band gaps of films in toluene solution proved MEH-PPV has longer conjugation segments. The surface roughness of thin films decreased with the increased of ageing time; which is caused by the aggregation of the MEH-PPV. The PL spectra show the quenching of emission might be due to the conjugation of length polymer changes in different ageing times.


2012 ◽  
Vol 12 (3) ◽  
pp. 870-874 ◽  
Author(s):  
E. Laureto ◽  
M.A.T. da Silva ◽  
R.V. Fernandes ◽  
J.L. Duarte ◽  
I.F.L. Dias ◽  
...  

2013 ◽  
Vol 667 ◽  
pp. 402-406 ◽  
Author(s):  
N.Y. Zayana ◽  
Mohamad Rusop

Thin films of poly [2-methoxy-5(2’-ethyl hexyloxy)-phenylene vinylene] (MEH-PPV) prepared from aromatic and non-aromatic solvents were obtained by spin coating techniques. The non-aromatic solvents used are chloroform and tetrahydrofuran (THF), while the aromatic solvents used are toluene and xylene. The UV-Vis and PL spectra of MEH-PPV thin films prepared from toluene and xylene slightly red shift compared to thin films from chloroform and THF. The shifting due to the aggregation formed in thin films. The SEM images of thin films prepared from aromatic solvents shows smooth surface while surface of thin films from non-aromatic is rough. The FTIR spectra of all samples show the same peak assignment of MEH-PPV.


1983 ◽  
Vol 44 (C10) ◽  
pp. C10-363-C10-366 ◽  
Author(s):  
J. Vlieger ◽  
M. M. Wind

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