Suppressed Charge Recombination in Inverted Organic Photovoltaics via Enhanced Charge Extraction by Using a Conductive Fullerene Electron Transport Layer

2014 ◽  
Vol 26 (36) ◽  
pp. 6262-6267 ◽  
Author(s):  
Chang-Zhi Li ◽  
Chih-Yu Chang ◽  
Yue Zang ◽  
Huan-Xin Ju ◽  
Chu-Chen Chueh ◽  
...  
Nano Letters ◽  
2018 ◽  
Vol 18 (9) ◽  
pp. 5805-5811 ◽  
Author(s):  
Wenchao Huang ◽  
Bowen Zhu ◽  
Sheng-Yung Chang ◽  
Shuanglin Zhu ◽  
Pei Cheng ◽  
...  

Crystals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 933
Author(s):  
Helong Wang ◽  
Guanchen Liu ◽  
Chongyang Xu ◽  
Fanming Zeng ◽  
Xiaoyin Xie ◽  
...  

Surface passivation, which has been intensively studied recently, is essential for the perovskite solar cells (PSCs), due to the intrinsic defects in perovskite crystal. A series of chemical or physical methods have been published for passivating the defects of perovskites, which effectively suppressed the charge recombination and enhanced the photovoltaic performance. In this study, the n-type semiconductor of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) is dissolved in chlorobenzene (CB) for the surface passivation during the spin-coating process for depositing the two-dimensional (2D) perovskite film. This approach simplifies the fabrication process of 2D PSCs and benefits the film quality. As a result, the defects of perovskite film are effectively passivated by this method. A better perovskite/PCBM heterojunction is generated, exhibiting an increased film coverage and improved film morphology of PCBM. It is found that this technology results in an improved electron transporting performance as well as suppressed charge recombination for electron transport layer. As a result, PSCs based on the one-step formed perovskite/PCBM heterojunctions exhibit the optimized power conversion efficiency of 15.69% which is about 37% higher than that of regular perovskite devices. The device environmental stability is also enhanced due to the quality improved electron transport layer.


Author(s):  
Xiaoyin Xie ◽  
Fanming Zeng ◽  
Helong Wang ◽  
guanchen Liu ◽  
Chongyang Xu ◽  
...  

Surface passivation, which has been intensively studied recently, is essential for the perovskite solar cells (PSCs), due to the intrinsic defects in perovskite crystal. A series of chemical or physical methods have been published for passivating the defects of perovskite, which effectively suppressed the charge recombination and enhanced the photovoltaic performance. In this study, the n-type semiconductor of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) is dissolved in chlorobenzene (CB) for the surface passivation during the spin-coating process for depositing the two-dimensional (2D) perovskite film. This approach simplifies the fabrication process of 2D PSCs and benefits the film quality. As a result, the defects of perovskite film are effectively passivated by this method. A better perovskite/PCBM heterojunction is generated, exhibiting an increased film coverage and improved film morphology of PCBM. It is found that this technology results in an improved electron transporting performance as well as suppressed charge recombination for electron transport layer. As a result, PSCs based on the one-step formed perovskite/PCBM heterojunctions exhibit the optimized power conversion efficiency of 15.69% which is about 37% higher than that of regular perovskite devices. The device environmental stability is also enhanced due to the quality-improved electron transport layer.


2020 ◽  
Vol 132 (47) ◽  
pp. 21166-21173
Author(s):  
Wu‐Qiang Wu ◽  
Jin‐Feng Liao ◽  
Jun‐Xing Zhong ◽  
Yang‐Fan Xu ◽  
Lianzhou Wang ◽  
...  

2020 ◽  
Vol 59 (47) ◽  
pp. 20980-20987
Author(s):  
Wu‐Qiang Wu ◽  
Jin‐Feng Liao ◽  
Jun‐Xing Zhong ◽  
Yang‐Fan Xu ◽  
Lianzhou Wang ◽  
...  

2019 ◽  
Vol 2 (11) ◽  
pp. 8090-8097 ◽  
Author(s):  
Marios Neophytou ◽  
Michele De Bastiani ◽  
Nicola Gasparini ◽  
Erkan Aydin ◽  
Esma Ugur ◽  
...  

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