Approaching Ultrastable High‐Rate Li–S Batteries through Hierarchically Porous Titanium Nitride Synthesized by Multiscale Phase Separation

2018 ◽  
Vol 31 (3) ◽  
pp. 1806547 ◽  
Author(s):  
Won‐Gwang Lim ◽  
Changshin Jo ◽  
Ara Cho ◽  
Jongkook Hwang ◽  
Seongseop Kim ◽  
...  
Keyword(s):  
Phase Separation ◽  
Titanium Nitride ◽  
Porous Titanium ◽  
High Rate ◽  
Hierarchically Porous ◽  
Multiscale Phase Separation

A 3D ordered hierarchically porous non-carbon electrode for highly effective and efficient capacitive deionization

2019 ◽  
Vol 7 (26) ◽  
pp. 15633-15639 ◽  
Author(s):  
Yuchen Wu ◽  
Gaopeng Jiang ◽  
Guihua Liu ◽  
Gregory Lui ◽  
Zachary Paul Cano ◽  
...  
Keyword(s):  
Titanium Nitride ◽  
Adsorption Capacity ◽  
Porous Titanium ◽  
Adsorption Rate ◽  
Carbon Electrode ◽  
Capacitive Deionization ◽  
Hierarchically Porous ◽  
Highly Effective ◽  
Ordered Porous

A nanoengineered 3D hierarchical ordered porous titanium nitride electrode is applied as an effective and efficient non-carbon electrode to deliver outstanding salt adsorption capacity and record-breaking salt adsorption rate in a capacitive deionization cell.

Compositional Effects on the Degradation of PVD-Tisin

1997 ◽  
Vol 473 ◽  
Author(s):  
W. F. McArthur ◽  
F. Deng ◽  
K. Ring ◽  
P. M. Pattison ◽  
K. L. Kavanagh
Keyword(s):  
Phase Separation ◽  
Silicon Nitride ◽  
Electron Diffraction ◽  
Titanium Nitride ◽  
Amorphous Matrix ◽  
Barrier Material ◽  
Rutherford Back Scattering ◽  
Phase Line ◽  
Back Scattering ◽  
Target Ratio

ABSTRACTPVD-TixSiyNz films formed by reactive RF-magnetron co-sputtering of Ti and Si in Ar/N2 are evaluated as a diffusion barrier between Cu and Si. A complete range of compositions are obtained by Ti targets inlaid with Si. Film composition is controlled by the target ratio of titanium to silicon and N2 partial pressure. Electrical results versus thermal history for films of∼6–18% Si as well as the composition and microstructure as determined by Rutherford back scattering (RBS), TEM and electron diffraction are reported. These films are an amorphous matrix with imbedded nanocrystals of titanium nitride as-deposited and undergo phase separation to yield titanium nitride and silicon nitride after a 1000°C anneal. As-deposited compositions which lie above the TiN-Si3N4 phase line yield crystals of TiN. Compositions below the TiN-Si3N4 phase line yield crystals of Ti2N. Bulk resistivity as-deposited (<400μω-cm) is acceptable for use as a contact liner/barrier material and improves with annealing. Si pn-diodes metallized with 20nm Ti40Si15N45 and Cu show no significant increase in reverse leakage current at anneal temperatures below 700°C.

A bio-inspired, hierarchically porous structure with a decoupled fluidic transportation and evaporative pathway toward high-performance evaporation

2021 ◽  
Author(s):  
Jianguo Li ◽  
Chaoji Chen ◽  
Wentao Gan ◽  
Zhihan Li ◽  
Hua Xie ◽  
...  
Keyword(s):  
Porous Structure ◽  
High Performance ◽  
Evaporation Rate ◽  
High Rate ◽  
Hierarchically Porous ◽  
Hierarchically Porous Structure ◽  
High Evaporation Rate

High-rate evaporation is achieved by a delignified reed, featuring hierarchically, 3D porous structure with microchannels surrounding macrochannels, which decouples the transport and evaporation of fluids, contributing to a high evaporation rate.

Design and synthesis of interconnected hierarchically porous anatase titanium dioxide nanofibers as high-rate and long-cycle-life anodes for lithium-ion batteries

Nanoscale ◽  
2018 ◽  
Vol 10 (28) ◽  
pp. 13539-13547 ◽  
Author(s):  
Min Su Jo ◽  
Gi Dae Park ◽  
Yun Chan Kang ◽  
Jung Sang Cho
Keyword(s):  
Titanium Dioxide ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Lithium Ion ◽  
Cycle Life ◽  
High Rate ◽  
Hierarchically Porous ◽  
Long Cycle Life ◽  
Design And Synthesis ◽  
Synthetic Strategy

An efficient and simple synthetic strategy to prepare interconnected hierarchically porous anatase TiO2 nanofibers as anode materials for LIBs is introduced.

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