scholarly journals Capacitive Organic Dye Removal by Block Copolymer Based Porous Carbon Fibers

2020 ◽  
Vol 7 (16) ◽  
pp. 2000507
Author(s):  
Joel Marcos Serrano ◽  
Assad U. Khan ◽  
Tianyu Liu ◽  
Zhen Xu ◽  
Alan R. Esker ◽  
...  
Author(s):  
Wenqi Zhao ◽  
Zhen Xu ◽  
John Elliott ◽  
Cindy S. Barrera ◽  
Zacary L. Croft ◽  
...  

2020 ◽  
Vol 5 (1) ◽  
pp. 153-165 ◽  
Author(s):  
Zhengping Zhou ◽  
Tianyu Liu ◽  
Assad U. Khan ◽  
Guoliang Liu

Pyrolysis temperature is an important processing parameter that determines the physical and electrochemical properties of block copolymer-based porous carbon fibers.


2019 ◽  
Vol 5 (2) ◽  
pp. eaau6852 ◽  
Author(s):  
Zhengping Zhou ◽  
Tianyu Liu ◽  
Assad U. Khan ◽  
Guoliang Liu

Carbon fibers have high surface areas and rich functionalities for interacting with ions, molecules, and particles. However, the control over their porosity remains challenging. Conventional syntheses rely on blending polyacrylonitrile with sacrificial additives, which macrophase-separate and result in poorly controlled pores after pyrolysis. Here, we use block copolymer microphase separation, a fundamentally disparate approach to synthesizing porous carbon fibers (PCFs) with well-controlled mesopores (~10 nm) and micropores (~0.5 nm). Without infiltrating any carbon precursors or dopants, poly(acrylonitrile-block-methyl methacrylate) is directly converted to nitrogen and oxygen dual-doped PCFs. Owing to the interconnected network and the highly optimal bimodal pores, PCFs exhibit substantially reduced ion transport resistance and an ultrahigh capacitance of 66 μF cm−2 (6.6 times that of activated carbon). The approach of using block copolymer precursors revolutionizes the synthesis of PCFs. The advanced electrochemical properties signify that PCFs represent a new platform material for electrochemical energy storage.


2020 ◽  
Vol 6 (16) ◽  
pp. eaaz0906 ◽  
Author(s):  
Tianyu Liu ◽  
Joel Serrano ◽  
John Elliott ◽  
Xiaozhou Yang ◽  
William Cathcart ◽  
...  

Capacitive deionization (CDI) is energetically favorable for desalinating low-salinity water. The bottlenecks of current carbon-based CDI materials are their limited desalination capacities and time-consuming cycles, caused by insufficient ion-accessible surfaces and retarded electron/ion transport. Here, we demonstrate porous carbon fibers (PCFs) derived from microphase-separated poly(methyl methacrylate)-block-polyacrylonitrile (PMMA-b-PAN) as an effective CDI material. PCF has abundant and uniform mesopores that are interconnected with micropores. This hierarchical porous structure renders PCF a large ion-accessible surface area and a high desalination capacity. In addition, the continuous carbon fibers and interconnected porous network enable fast electron/ion transport, and hence a high desalination rate. PCF shows desalination capacity of 30 mgNaCl g−1PCF and maximal time-average desalination rate of 38.0 mgNaCl g−1PCF min−1, which are about 3 and 40 times, respectively, those of typical porous carbons. Our work underlines the promise of block copolymer–based PCF for mutually high-capacity and high-rate CDI.


2021 ◽  
Author(s):  
Xiao-Sa Zhang ◽  
Hong-Tian Zhao ◽  
Yu Liu ◽  
Wenze Li ◽  
Ai-Ai Yang ◽  
...  

Metal–organic frameworks (MOFs) have recently emerged as a type of uniformly and periodically atom-distributed precursor and efficient self-sacrificial template to fabricate hierarchical porous-carbon-related nanostructured functional materials. In this work, we...


2009 ◽  
Vol 24 (2) ◽  
pp. 320-324 ◽  
Author(s):  
Wei XIE ◽  
Hai-Feng CHENG ◽  
Zeng-Yong CHU ◽  
Zhao-Hui CHEN ◽  
Yong-Jiang ZHOU

Author(s):  
Rui-Xia Yang ◽  
Qiao-Hong Peng ◽  
Bing Yu ◽  
You-Qing Shen ◽  
Hai-Lin Cong

2021 ◽  
pp. 100150
Author(s):  
Kasidit Janbooranapinij ◽  
Arinchai Yimponpipatpol ◽  
Narueporn Ngamthanacom ◽  
Gasidit Panomsuwan

2020 ◽  
Vol 260 ◽  
pp. 116266 ◽  
Author(s):  
Patrycja Bober ◽  
Islam M. Minisy ◽  
Udit Acharya ◽  
Jiří Pfleger ◽  
Vladimir Babayan ◽  
...  

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