Dual Function Metallo–Organic Assemblies for Electrochromic–Hybrid Supercapacitors

2020 ◽  
Vol 7 (16) ◽  
pp. 2000718
Author(s):  
Ofir Eisenberg ◽  
Yadid M. Algavi ◽  
Haim Weissman ◽  
Julia Narevicius ◽  
Boris Rybtchinski ◽  
...  
2017 ◽  
Vol 25 (2) ◽  
pp. 927-960
Author(s):  
Jarod Jacobs

In this article, I discuss three statistical tools that have proven pivotal in linguistic research, particularly those studies that seek to evaluate large datasets. These tools are the Gaussian Curve, significance tests, and hierarchical clustering. I present a brief description of these tools and their general uses. Then, I apply them to an analysis of the variations between the “biblical” DSS and our other witnesses, focusing upon variations involving particles. Finally, I engage the recent debate surrounding the diachronic study of Biblical Hebrew. This article serves a dual function. First, it presents statistical tools that are useful for many linguistic studies. Second, it develops an analysis of the he-locale, as it is used in the “biblical” Dead Sea Scrolls, Masoretic Text, and Samaritan Pentateuch. Through that analysis, this article highlights the value of inferential statistical tools as we attempt to better understand the Hebrew of our ancient witnesses.


2019 ◽  
Author(s):  
Enrico Bergamaschi ◽  
Frédéric Beltran ◽  
Christopher Teskey

<p></p><p></p><p>Switchable catalysis offers opportunities to control the rate or selectivity of a reaction <i>via</i> a stimulus such as pH or light. However, few examples of switchable catalytic systems that can facilitate multiple processes exist. Here we report a rare example of such dual-functional, switchable catalysis. Featuring an easily prepared, bench-stable cobalt(I) hydride complex in conjunction with pinacolborane, we can completely alter the reaction outcome between two widely employed transformations – olefin migration and hydroboration – with visible light as the sole trigger. This dichotomy arises from ligand photodissociation which leads to metamorphosis of the active catalytic site, resulting in divergent mechanistic pathways.</p><p></p><p></p>


2019 ◽  
Author(s):  
Yamin Zhang ◽  
Lina Chen ◽  
Chongyang Hao ◽  
Xiaowen Zheng ◽  
Yixuan Guo ◽  
...  

For the applications of aqueous Li-ion hybrid capacitors and Na-ion hybrid capacitors, potassium ions are pre-inserted into MnO<sub>2</sub> tunnel structure, the as-prepared K<sub>1.04</sub>Mn<sub>8</sub>O<sub>16</sub> materials consist of <a>nanoparticles</a> and nanorods were prepared by facile high-temperature solid-state reaction. <a></a>The as-prepared materials were well studied andthey show outstanding electrochemical behavior. We assembled hybrid supercapacitors with commercial activated carbon (YEC-8A) as anode and K<sub>1.04</sub>Mn<sub>8</sub>O<sub>16 </sub>as cathode. It has high energy densities and power densities. Li-ion capacitors reach a high energy density of 127.61 Wh kg<sup>-1 </sup>at the power density of 99.86 W kg<sup>-1</sup> and Na-ion capacitor obtains 170.96 Wh kg<sup>-1 </sup>at 133.79 W kg<sup>-1</sup>. In addition, the <a>hybrid supercapacitor</a>s demonstrate excellent cycling performance which maintain 97 % capacitance retention for Li-ion capacitor and 85 % for Na-ion capacitor after 10,000 cycles.


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