Nanomagnetically modified thioglycolic acid (γ‐Fe 2 O 3 @SiO 2 ‐SCH 2 CO 2 H): Efficient and reusable green catalyst for the one‐pot domino synthesis of spiro[benzo[ a ]benzo[6,7]chromeno[2,3‐ c ]phenazine] and benzo[ a ]benzo[6,7]chromeno[2,3‐ c ]phenazines

2017 ◽  
Vol 31 (11) ◽  
Author(s):  
Sajjad Abbasi Pour ◽  
Afshin Yazdani‐Elah‐Abadi ◽  
Mojgan Afradi
Keyword(s):  
Thioglycolic Acid ◽  
One Pot ◽  
Green Catalyst ◽  
The One

scholarly journals Gum arabic-OPO3H2 as a new natural-based green catalyst for the one-pot pseudo-four-component synthesis of naphtho[1,2-e][1,3]oxazines

RSC Advances ◽  
2020 ◽  
Vol 10 (66) ◽  
pp. 40508-40513
Author(s):  
Sahar Saadat Hosseinikhah ◽  
Bi Bi Fatemeh Mirjalili ◽  
Naeimeh Salehi ◽  
Abdolahamid Bamoniri
Keyword(s):  
Gum Arabic ◽  
Phosphorus Pentoxide ◽  
One Pot ◽  
Green Catalyst ◽  
The One

Gum arabic-OPO3H2 (GA-OPO3H2) as a unique natural-based green catalyst was synthesized by the reaction of phosphorus pentoxide with gum arabic.

scholarly journals Microwave Assisted Three Component Reaction Conditions to Obtain New Thiazolidinones with Different Heterocyclic Skeletons

Proceedings ◽  
2019 ◽  
Vol 41 (1) ◽  
pp. 38
Author(s):  
Fernando J. Lorenzo ◽  
Romina A. Ocampo ◽  
Sandra D. Mandolesi
Keyword(s):  
Microwave Irradiation ◽  
Thioglycolic Acid ◽  
Aldehyde Group ◽  
Green Solvent ◽  
Reaction Products ◽  
Reaction Conditions ◽  
One Pot ◽  
Microwave Assisted ◽  
Three Component Reaction ◽  
The One

We present here a new proposal for the “one pot” generation of new 4-thiazolidinones (9a–e) through a multicomponent reaction under microwave irradiation conditions, using aromatic and heteroaromatic amines (8a–e), absolute ethanol as a “green” solvent and modifying the aldehyde group in the glycosidic residue, synthesized from D-mannitol. The study is focused in the variation of the irradiation times and the concentration of thioglycolic acid in order to study the possibility of controlling the structure and/or stereochemistry of the products formed in the reaction. Thiazolidinones 9a–d were obtained with a 69–82% The generation of the corresponding reaction products were monitored by TLC and CG-MS, taking reaction aliquots. The conditions reaction proved to be chemoselective depending on the excess of acid and irradiation times.

Fulvic Acid: An Efficient and Green Catalyst for the One-pot Four-component Domino Synthesis of Benzo[a]phenazine Annulated Heterocycles in Aqueous Medium

2020 ◽  
Vol 52 (1) ◽  
pp. 48-55 ◽  
Author(s):  
Afshin Yazdani-Elah-Abadi ◽  
Maliheh Razeghi ◽  
Nasim Shams ◽  
Mehrnoush Kangani ◽  
Razieh Mohebat
Keyword(s):  
Fulvic Acid ◽  
Aqueous Medium ◽  
One Pot ◽  
Green Catalyst ◽  
The One

scholarly journals Convenient Approach for the One-Pot, Three-Component Synthesis of 1-(Benzothiazolylamino)Methyl-2- Naphthol Using Citric Acid as a Green Catalyst

2016 ◽  
Vol 24 (2) ◽  
pp. 112-121 ◽  
Author(s):  
Mojtaba Lashkari ◽  
Malek Taher Maghsoodlou ◽  
Mahsa Karima ◽  
Belgais Adrom ◽  
Maryam Fatahpour
Keyword(s):  
Citric Acid ◽  
Isolation Procedure ◽  
Multicomponent Synthesis ◽  
One Pot ◽  
Green Catalyst ◽  
Mild Conditions ◽  
Convenient Approach ◽  
The One ◽  
Naphthol Derivatives

Abstract A straightforward, one-pot multicomponent synthesis of 1-(benzothiazolylamino)methyl-2-naphthol derivatives was achieved by condensation of 2-naphthol, aldehydes, and 2- aminobenzothiazole catalyzed by a small amount of citric acid, which acts as a benign enviermentally catalyst. Mild conditions with excellent yields and a simple isolation procedure are noteworthy advantages of this method.

Glutamic Acid as an Efficient and Green Catalyst for the One-Pot Synthesis of 1,2,4,5-Tetrasubstituted Imidazoles under Thermal, Solvent-Free Conditions

2017 ◽  
Vol 41 (11) ◽  
pp. 673-675 ◽  
Author(s):  
Fahimeh Khazaee Feizabad ◽  
Khatereh Khandan-Barani ◽  
Alireza Hassanabadi
Keyword(s):  
Glutamic Acid ◽  
Reaction Times ◽  
Catalytic Amount ◽  
Solvent Free ◽  
One Pot ◽  
Green Catalyst ◽  
Aryl Aldehydes ◽  
Solvent Free Conditions ◽  
The One ◽  
Tetrasubstituted Imidazoles

A high-yielding synthesis of 1,2,4,5-tetrasubstituted imidazoles is described, involving the reaction of 1,2-dicarbonyl compounds, aryl aldehydes, amines and ammonium acetate in the presence of a catalytic amount of glutamic acid under thermal, solvent-free conditions. The salient features of this protocol are aerobic conditions, a non-hazardous green catalyst, short reaction times and mild reaction conditions.

An Efficient One Pot, Multicomponent Synthesis of 1, 3-Thiazolidin-4-Ones Using L-Proline as Catalyst in Water

2021 ◽  
Vol 18 ◽  
Author(s):  
Yatin U. Gadkari ◽  
Rajesh D. Shanbhag ◽  
Vikas N. Telvekar
Keyword(s):  
Energy Efficient ◽  
Room Temperature ◽  
Thioglycolic Acid ◽  
Current Approach ◽  
Environmentally Benign ◽  
Multicomponent Synthesis ◽  
One Pot ◽  
The One ◽  
Aqueous Conditions ◽  
Aromatic Heterocyclic

: An efficient methodology for the synthesis of 1,3-thiazolidin-4-ones using L-Proline as catalyst under aqueous conditions has been developed. The one-pot, multicomponent reaction of aromatic/heterocyclic aldehyde, aromatic amine and thioglycolic acid at room temperature give 1,3-thiazolidin-4-ones in moderate to good yields. Further, the current approach is notably greener than traditional methods with E-factor of 3.1 and the eco scale score of 96. The developed protocol offers several features, such as being simple, environmentally benign, energy-efficient, economical, mild conditions, shorter reaction time.

Silica Nanoparticles from Rice Husk Ash: A Green Catalyst for the One-Pot Three-Component Synthesis of Benzo[B]Furan Derivatives

2014 ◽  
Vol 875-877 ◽  
pp. 202-207 ◽  
Author(s):  
Ali Ramazani ◽  
Morteza Rouhani ◽  
Sang Woo Joo
Keyword(s):  
Silica Nanoparticles ◽  
Rice Husk ◽  
Room Temperature ◽  
Rice Husk Ash ◽  
One Pot ◽  
Furan Derivatives ◽  
Green Catalyst ◽  
Iminium Ion ◽  
The One ◽  
High Yields

Reaction of an isocyanide with an iminium ion intermediate, formed by reaction between an electronpoor 2-hydroxybenzaldehyde derivative and a secondary amine in the presence of silica nanoparticles proceeds smoothly at room temperature to afford benzo [b] furan derivatives in high yields.

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