Simple synthesis of the novel Cu‐MOF catalysts for the selective alcohol oxidation and the oxidative cross‐coupling of amines and alcohols

2020 ◽  
Vol 34 (12) ◽  
Author(s):  
Pouya Ghamari Kargar ◽  
Sima Aryanejad ◽  
Ghodsieh Bagherzade
2021 ◽  
Author(s):  
Seyyedeh Ameneh Alavi G. ◽  
Mohammad Ali Nasseri ◽  
Milad Kazemnejadi ◽  
Ali Allahresani ◽  
Mahdi HussainZadeh

The novel heterogeneous bimetallic nanoparticles of Cu–Co were synthesized and successfully applied as a recyclable magnetically catalyst in Heck, Suzuki, and C–N cross-coupling via a quick, easy, efficacious and environmentally protocol.


Proceedings ◽  
2018 ◽  
Vol 2 (13) ◽  
pp. 713
Author(s):  
Siya Lozanova ◽  
Ivan Kolev ◽  
Avgust Ivanov ◽  
Chavdar Roumenin

A novel in-plane sensitive Hall arrangement consisting of two identical n-Si three-contact (3C) elements and realized in a common technological process, is presented. In the solution, the minimization of the offset and its temperature drift is achieved by cross-coupling of the outer device contacts. This terminals’ connection provides equalizing currents between the two substrates which strongly compensate the inevitable difference in the electrical conditions in the two parts of the arrangement. As a result, the residual offset of both integrated Hall elements at the output Vout(0) and its temperature drift are strongly minimized. The residual offset is about 160 times smaller than the single-configuration one. The obtained output voltage-to-residual offset ratio at sensitivity of SRI ≈ 98 V/AT is very promising, reaching 6 × 103 at temperature T = 40 °C and induction 1 T. As a result, increased metrological accuracy for numerous applications is achieved. For a first time through the novel arrangement a suppression of sensitivity in the presence of external magnetic field could be achieved in order to obtain permanent offset information. This is one of the key results in the Hall device investigation.


2015 ◽  
Vol 44 (37) ◽  
pp. 16592-16601 ◽  
Author(s):  
Yinle Li ◽  
Zhuqing Zhang ◽  
Jianfeng Shen ◽  
Mingxin Ye

The novel multifunctional Fe3O4@C–Pd@CeO2 nanospheres show excellent catalytic performance in the Suzuki–Miyaura cross-coupling reaction and the reduction of 4-nitrophenol.


Synlett ◽  
2018 ◽  
Vol 30 (07) ◽  
pp. 787-791 ◽  
Author(s):  
David Cain ◽  
Calum McLaughlin ◽  
John Molloy ◽  
Cameron Carpenter-Warren ◽  
Niall Anderson ◽  
...  

Cascade reactions are an important strategy in reaction ­design, allowing streamlining of chemical synthesis. Here we report a cascade Suzuki–Miyaura/Diels–Alder reaction, employing vinyl Bpin as a bifunctional reagent in two distinct roles: as an organoboron nucleo­phile for cross-coupling and as a Diels–Alder dienophile. Merging these two reactions enables a rapid and operationally simple synthesis of functionalized carbocycles in good yield. The effect of the organoboron subtype on Diels–Alder regioselectivity was investigated and postsynthetic modifications were carried out on a model substrate. The potential for a complementary Heck/Diels–Alder process was also assessed.


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