Mechanical properties, flame retardancy, hot-air ageing, and hot-oil ageing resistance of ethylene-vinyl acetate rubber/hydrogenated nitrile-butadiene rubber/magnesium hydroxide composites

2009 ◽  
Vol 114 (5) ◽  
pp. 3310-3318 ◽  
Author(s):  
Shuguo Chen ◽  
Yong Zhang ◽  
Ruyin Wang ◽  
Haiyang Yu ◽  
Martin Hoch ◽  
...  
2013 ◽  
Vol 750-752 ◽  
pp. 816-819 ◽  
Author(s):  
Teng Teng Wang ◽  
Guo Lun Zhong ◽  
Li Ling Zhou

The mechanical properties, compatibility, flame retardancy property, hot-air ageing resistance of hydrogenated nitrile-butadiene rubber (HNBR) / chloroprene rubber (CR) blends were investigated. With increasing CR, stress at 100% elongation, shore A hardness, limited oxygen index of HNBR/CR blends increased, while the tensile strength, hot-air aging resistance of the blends decreased. Differential scanning calorimeter (DSC) revealed that it’s incompatible with both HNBR and CR before vulcanization, however they became compatible completely after vulcanization as indicated by Dynamic Mechanical Analysis (DMA).


Polymers ◽  
2018 ◽  
Vol 10 (9) ◽  
pp. 1028 ◽  
Author(s):  
Zhi-Qi Liu ◽  
Zhi Li ◽  
Yun-Xian Yang ◽  
Yan-Ling Zhang ◽  
Xin Wen ◽  
...  

This study was aimed at investigating the effects of carbon nanomaterials with different geometries on improving the flame retardancy of magnesium hydroxide–filled ethylene-vinyl acetate (EM). The thermal stability and flame retardancy were studied by thermogravimetric analysis (TGA), limiting oxygen index (LOI), UL-94 test, and cone calorimeter test (CCT). The in situ temperature monitoring system and interrupted combustion offered direct evidence to link flame retardancy and composite structure. Results demonstrated that carbon nanomaterials enhanced the thermal stability and fire safety of EM. The geometry of carbon nanomaterials played a key role in synergistic flame retardancy of EM, with the flame-retardant order of carbon nanotube > nanoscale carbon black > graphene. Based on an online temperature monitoring system and interrupted combustion test, one-dimensional carbon nanotube was more inclined to form the network structure synergistically with magnesium hydroxide in ethylene-vinyl acetate, which facilitated the generation of more continuous char structure during combustion. In parallel, the mechanical property was characterized by a tensile test and dynamic mechanical analysis (DMA). The incorporation of carbon nanomaterials presented a limited effect on the mechanical properties of the EM system.


Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2107
Author(s):  
Dongwei Yao ◽  
Guangzhong Yin ◽  
Qingqing Bi ◽  
Xu Yin ◽  
Na Wang ◽  
...  

In this study, we selected basalt fiber (BF) as a functional filler to improve the mechanical properties of ethylene vinyl acetate (EVA)-based flame retardant materials. Firstly, BF was modified by grafting γ-aminopropyl triethoxysilane (KH550). Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscope (SEM), and energy dispersive X-ray spectroscopy (EDS) were used to comprehensively prove the successful modification of the BF surface. Subsequently, the modified BF was introduced into the EVA/magnesium hydroxide (MH) composites by melt blending. The limiting oxygen index (LOI), UL-94, cone calorimeter test, tensile test, and non-notched impact test were utilized to characterize both the flame retardant properties and mechanical properties of the EVA/MH composites. It was found that the mechanical properties were significantly enhanced without reducing the flame retardant properties of the EVA/MH composites. Notably, the surface treatment with silane is a simple and low-cost method for BF surface modification and the pathway designed in this study can be both practical and effective for polymer performance enhancement.


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