Mechanical performance and flame retardancy of polypropylene composites containing zeolite and multiwalled carbon nanotubes

2015 ◽  
Vol 133 (3) ◽  
pp. n/a-n/a ◽  
Author(s):  
Qing Zhao ◽  
Yanhong Hu ◽  
Xingyi Wang

2020 ◽  
Vol 27 (8) ◽  
Author(s):  
Ke Guo ◽  
Tao Wang ◽  
Xuechun Wang ◽  
Renfeng Song ◽  
Zhiqiang Zhang ◽  
...  




2019 ◽  
Vol 137 (19) ◽  
pp. 48667
Author(s):  
Rui Wang ◽  
Yanyu Zheng ◽  
Lihao Chen ◽  
Shaoyun Chen ◽  
Dongxian Zhuo ◽  
...  




2015 ◽  
Vol 37 (9) ◽  
pp. 2756-2769 ◽  
Author(s):  
Ivanka Petrova ◽  
Evgeni Ivanov ◽  
Rumiana Kotsilkova ◽  
Christos Chatzimanolis-Moustakas ◽  
Apostolos Kyritsis ◽  
...  


2017 ◽  
Vol 30 (9) ◽  
pp. 1036-1047
Author(s):  
Baoxia Xue ◽  
Yun Peng ◽  
Yinghao Song ◽  
Jie Bai ◽  
Mei Niu ◽  
...  

Novel flame-retardant phosphorylated chitosan-multiwalled carbon nanotubes (PCS-MWCNTs) were obtained by the loading of PCS on the surface of MWCNTs by a chemical deposition cross-linking method. A series of polyethylene terephthalate (PET) composites were prepared by melt compounding with MWCNTs or PCS-MWCNTs to investigate the flame-retardant properties. Field-emission scanning electron microscopy, transmission electron microscopy, and Fourier transform infrared (FTIR) spectrometry were employed to characterize the morphology, chemical structure, and functionalization effect of MWCNTs. The coating degree and thermal stability of PCS-MWCNTs were investigated by thermogravimetric analysis (TGA). Thermal decomposition products after TGA and flame-retardant properties of PET composites were characterized by FTIR and CONE measurements, respectively. The results indicated that PCS is loaded on the MWCNT surface. Modified PCS-MWCNTs exhibited better dispersion and efficient flame retardancy. TGA data indicated that PCS-MWCNTs can enhance the onset temperature of PET and increase the amount of the char residues. The char residue with 1 wt% PCS-MWCNTs/PET increased from 12.62% (pure PET) to 15.46%. The analysis of the decomposition products and morphology of the char residue indicated that PCS-MWCNTs not only retain the effect of alternating couplet carbon (C) and physical barrier by MWCNTs, but also form P–C compounds, improving the flame retardancy of PET. CONE tests demonstrated that the PCS-MWCNTs lead to the efficient decrease in the flammability parameters, such as the heat release rate (HRR), total release heat rate (THR), total smoke production (TSP), mean mass loss rate (MMLR), and the total combustion time. The peak HRR value decreased from 513.22 kW m−2 to 341 kW m−2. The THR, TSP, and MMLR values decreased by 20.38 MJ m−2, 1.1 m2, and 1.32 g s−1, respectively. The total combustion time decreased by 98 s, from 388 s to 290 s, indicating that PCS-MWCNTs extinguish fire.



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