Research on Aging Resistance of Three Phase Composites for Anti-collision Intelligent Control of Bridge Engineering

Aminated Carbon Nanotubes (CNTs) and Carbon Fiber (CF) materials for anticollision intelligent control of Bridge Engineering were used to enhance the properties of Bismaleimide Resin (BMI) matrix resin and then tested the moist heat aging, salt spray aging and erosion resistance in this study. The resulted show that when the aging time was 168h, after wet heat and salt spray, the flexural strength and impact strength of three-phase composites with 1.5wt% MWNTs-NH2 content can reach maximum, and the wet heat aging bending performance is 45% better than that of non-added carbon nanotubes, the impact performance is 41% higher, the salt spray aging bending performance is 43% higher and the salt spray aging impact performance is 32% higher.

Surface Treatment of Composites with Bismaleimide Resin-Based Wet Peel Ply for Enhanced Adhesive Bonding Performance

Surface treatment is typically required to improve the bonding performance of carbon-fiber-reinforced composites. Herein, a wet peel ply was prepared using bismaleimide (BMI) resins as a matrix resin. The temperature–heating rate extrapolation method and rheological method were employed to study the reaction characteristics and viscosity-temperature characteristics of the matrix in the BMI wet peel ply. The curing temperatures of the BMI wet peel ply and the BMI prepreg were the same (200 °C), making this wet peel ply suitable for co-curing with the BMI prepreg. After treatment with the wet peel ply, the bonding strength of the BMI composite joint showed a mean shear strength of 35.5 MPa, which was 1.72% higher than that of the sanded composite and 17.5% higher than that of the composite treated with the dry peel ply. In addition, the BMI composite treated with the BMI wet peel ply exhibited good bonding stability with a coefficient of variation of 3.9. After damp-heat aging for 1440 h, the retention rate of shear strength at room-temperature was 82.3%. The relatively loosely woven carrier in the BMI wet peel ply increased the surface roughness of the composite, thus improving the bonding strength.

Preparation and properties of bismaleimide resin blended with alkynyl-terminated modifiers

A kind of modified bismaleimide resin, with good processability, heat resistance, and impact strength was developed, using 4,4′-dipropargyloxydiphenyl ether (DPEDPE), N-(4-propargyloxyphenyl)maleimide (4-PPM), and 3-ethynylphenyl maleimide (3-EPM) as modifiers. The DPEDPE, 4-PPM, and 3-EPM were synthesized and characterized by Fourier transform infrared spectroscopy (FTIR) and 1H-nuclear magnetic resonance (1H NMR), and used to modify the N,N′-(4,4′-diphenylmethane)bismaleimide (BDM)/2,2′-diallyl bisphenol A (DABPA) resin system (BD) to obtain the different blend resin systems of DPEDPE-modified BD (BDD), 4-PPM-modified BD (BDP), and 3-EPM-modified BD (BDE). The curing temperature of BD resin increases with increase of the alkynyl-terminated modifier content. The processability of BD resin was improved with addition of the propargyloxy-terminated compounds. The temperature of 5% weight loss, residual yield at 800°C and glass transition temperature of the cured BD resin increase with increase of the alkynyl-terminated modifier content and can reach 443°C, 46.7% and higher than 380°C. The tensile strength of the cured BD resin decreases with increase of alkynyl-terminated modifier content. The impact strength of the cured BD resin increases with increase of the propargyloxy-terminated compound content and can increase by 65%. The tensile strength, elastic modulus, and impact strength of the cured BD resin blended with DPEDPE can be 73.7 MPa, 4.1 GPa, and 19.6 kJ m−2, respectively. Moreover, the cured BD resin blended with DPEDPE has good water absorption resistance.

Enhancing the mechanical properties of bismaleimide resin with montmorillonite modified by two intercalators (amino-terminated polyoxypropylene and octadecyl trimethyl ammonium chloride)

Purpose Bismaleimide (BMI) is a kind of thermosetting resin and its application is usually limited by low toughness. In this paper, two kinds of reinforcement intercalator amino-terminated polyoxypropylene (POP) and octadecyl trimethyl ammonium chloride (OTAC) were designed and synthesized to toughen BMI resin and the toughening effect was compared and analyzed. The purpose of this paper is to toughen BMI resin and analyze the toughening effect of two reinforcements intercalator amino-terminated polyoxypropylene (POP) and octadecyl trimethyl ammonium chloride (OTAC). Design/methodology/approach Sodium-based montmorillonite (Na-MMT) was modified by POP and OTAC, and the ion-exchange reaction obtained organic montmorillonite (POP-MMT and OTAC-MMT). The polymer matrix (MBAE) was synthesized, in which 4,4’-diamino diphenyl methane BMI was used as the monomer and 3,3’-diallyl bisphenol A and bisphenol A diallyl ether were used as active diluents. And then, POP-MMT/MBAE and OTAC-MMT/MBAE composites were prepared using MBAE as matrix and POP-MMT or OTAC-MMT as reinforcement. The Fourier-transform infrared, X-ray diffraction and scanning electron microscope (SEM) of the filler and microstructure and mechanical properties of the composite were characterized to the better reinforcement. Findings POP-MMT and OTAC-MMT enhanced BMI-cured products’ toughness by generating microcracks in the polymer to absorb more fracture energy. Meanwhile, POP-MMT and OTAC-MMT were the main stress components and the enhancement of the interface interaction was beneficial to transfer the external force from the matrix to the reinforcement and improved the mechanical properties of the composite. Furthermore, with the intercalation rate increasing, the compatibility of the two phases was increased and the performance of MBAE was also elevated. Research limitations/implications BMI is generally used as aerospace structural materials, functional materials, impregnating paint and other fields. However, high crosslinking density leads to moulding material’s brittleness and limits a wider range of applications. Therefore, it has become an urgent priority to explore and improve the mechanical properties of BMI resin. Originality/value POP and OTAC have successfully intercalated Na-MMT layers to get POP-MMT and OTAC-MMT, and the interplanar crystal spacing and the intercalation rate were calculated, respectively. The results were corresponding with the SEM images of POP-MMT and OTAC-MMT. After that, the morphology of composites illustrated the compatibility was related to the intercalation rate. According to the mechanism of modified MMT toughening epoxy resin, when they were dispersed uniformly in the matrix, the composite’s mechanical properties had been significantly improved. Additionally, OTAC-MMT with a higher intercalation rate had better compatibility and interfacial force with the matrix, so that the mechanical properties of OTAC-MMT/MBAE were the best.

High toughness and excellent electrical performance bismaleimide resin modified by hyperbranched unsaturated polyester of flexible aliphatic side chains

Because of its flawed toughness, the scope of application of bismaleimide resin (BMI) in the field of aeronautics, industry and electricity is greatly restricted. Herein, a novel Hyperbranched unsaturated polymers (HBP) with the flexible chains grafted was incorporated to reinforce BMI resin’s toughness, where the new interpenetrating networks (IPN) structure was formed. The rich unsaturated double bond of HBP polyester could react with the BMI resin for chemical crosslinking and be used for the toughening agent. 13C-NMR and FT-IR were used to characterize HBP’s hyperbranched structure. Consequently, after adding 20 wt.% HBP, the impact strength of BMI modified by HBP increased by 211.1%. In comparison with neat BMI, the flexural strength of BMI modified by HBP was enhanced by 209.3%. It is worth noticing that HBP available in BMI resin significantly improved its electrical performance.