Synthesis and molecular interaction of tung oil‐based anionic waterborne polyurethane dispersion

2020 ◽  
Vol 137 (45) ◽  
pp. 49383
Author(s):  
Lei Jiang ◽  
Zhiyong Ren ◽  
Wentao Liu ◽  
Hao Liu ◽  
Chengshen Zhu
Polymers ◽  
2019 ◽  
Vol 12 (1) ◽  
pp. 15
Author(s):  
Antonella Patti ◽  
Domenico Acierno

Polyurethane is a polymer adaptable to different scientific and industrial requirements; nevertheless it is also extremely susceptible to UV radiation, which compromises the physical and mechanical functionality. In this framework, our study investigated the effect of waterborne polyurethane dispersion (WPUD) applied to a polyester (PET)-based fabric, through the impregnation method, on the puncturing and water resistance of the pristine material, before and after UV weathering. Results confirmed an increment of both features in the prepared fabrics, attributed to the PUR textile treatment; but a partially loss of the gained properties in the samples due to the UV weathering. In order to improve the efficiency of the impregnating dispersions, in protecting the durability of the treated materials, the addition of different UV light stabilizers, or/and of crosslinking agent into WPUD was also tested. From the experimental data, it can be concluded that formulations based on WPUD, containing both the crosslinker and UV organic absorber, have displayed an increment of their perforation and water resistance for the treated samples with respect to the starting textile, and contemporary have preserved the features against the UV light. Finally, microscopic and spectroscopic analyses have been performed as further characterization techniques of the samples surface.


2014 ◽  
Vol 513-517 ◽  
pp. 251-254 ◽  
Author(s):  
Zheng Xiang Wang ◽  
Ji Tong Yuan ◽  
Qi Long Liu ◽  
Xi Mei Xiao ◽  
Yun Hua Li ◽  
...  

A novel waterborne polyurethane (WPU) modified by tung oil was prepared with 2,4-tolylene diisocyanate, polyethylene glycol, dimethylol propinic acid, 1,4-butanedilo as main materials via acetone process. The structure of WPU molecule was characterized by FT-IR. Adhesive behavior for non-polar and/or low surface energy soft packing films was studied. Water resistance of films were evaluated by water contact angle and water uptake and thermal properties determined by thermal analysis instruments. The results show that the modified WPU films have good water and heat resistance. Both of modified WPUs or not have good adherence on BOPP films.


2014 ◽  
Vol 955-959 ◽  
pp. 88-91 ◽  
Author(s):  
Zhe Yang ◽  
Yan Bin Zhu ◽  
Fang Peng ◽  
Chang Qing Fu

The undecylenate based diol (UAD) has been synthesized from undecylenate by esterification and thiol-ene click reaction sequently, and then it was used as a diol to prepare bio-based waterborne polyurethane (WPU) reacting with isophorone diisocyanate (IPDI) and castor oil-based carboxyl hydrophilic chain extender. The structure of undecylenate based diol was verified by hydrogen proton nuclear magnetic resonance (1H NMR). Fourier transform infrared spectroscopy (FT-IR) was used to characterize the structure of WPU film. Furthermore, particle size and viscosity were used to character apparent properties of the bio-based waterborne polyurethane dispersion. The result shows that: bio-based waterborne polyurethane dispersion is transparent and very stable under room temperature. This work provides a simple and efficient method for the preparation of fatty acids based polyols and bio-based waterborne polyurethanes.


2015 ◽  
Vol 03 (01) ◽  
pp. 88-94 ◽  
Author(s):  
Xiaomin Yang ◽  
Baixia Ren ◽  
Zhiyong Ren ◽  
Lei Jiang ◽  
Wentao Liu ◽  
...  

2016 ◽  
Vol 848 ◽  
pp. 160-166
Author(s):  
Bai Xia Ren ◽  
Hua Fen Wang ◽  
Zhi Yong Ren ◽  
Wen Tao Liu ◽  
Lei Jiang ◽  
...  

A series of MDI-50 based non-ionic waterborne polyurethane dispersions (MDI-NPUD) were prepared by the mixing of 2,4’-diphenylmethane diisocianate (2,4’-MDI) and 4,4’-MDI (MDI-50) which reacted with hydroxylated tung oil (HTO) and polyethylene glycol-800 (PEG-800), Fourier Transform Infrared Spectroscopy (FTIR) and Proton-Nuclear Magnetic Resonance (1H-NMR) were used to characterize and analyze their molecular structures. The results indicated that MDI-50 and HTO were introduced as hard segment while PEG acted as soft segment. The surface tension, Hydrophile-Lipophile Balance (HLB) and stability were investigated. All MDI-NPUDs had much lower surface tension than the dicyclohexyl methane diisocyanate (HMDI) based NPUD (HMDI-NPUD). By changing the feed ratio of MDI-NPUD, the properties of MDI-NPUD could be controlled


2016 ◽  
Vol 45 (6) ◽  
pp. 270-276 ◽  
Author(s):  
Y. Zang ◽  
W. Gong ◽  
H. Xie ◽  
Z. Du ◽  
B. Liu ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (130) ◽  
pp. 107413-107420 ◽  
Author(s):  
Qiwen Yong ◽  
Fuwei Nian ◽  
Bing Liao ◽  
Liping Huang ◽  
Lu Wang ◽  
...  

Self-extinction and solvent-free waterborne polyurethane resin without the addition of extra matting agents.


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