Synthesis and properties of magnetite nanoparticles with peroxide‐containing polymer shell and nanocomposites based on them

2021 ◽  
pp. 50928
Author(s):  
Vitalii Serdiuk ◽  
Oleh Shevchuk ◽  
Natalya Bukartyk ◽  
Tetiana Kovalenko ◽  
Anatolii Borysiuk ◽  
...  
2019 ◽  
Vol 35 (2) ◽  
pp. 516-522 ◽  
Author(s):  
Jittaya Sadchaiyaphum ◽  
Pongsathon Phapugrangkul ◽  
Preeyporn Chaiyasat ◽  
Amorn Chaiyasat

High encapsulation efficiency of magnetite nanoparticles (MNPs; Fe3O4) in microcapsules using PDVB as a hydrophobic polymer shell was successfully achieved by microsuspension conventional radical polymerization (ms CRP). MNPs were initially synthesized by co-precipitation of Fe2+/Fe3+ in a binary phase. During the nucleation of MNPs in alkaline aqueous solution existing oleic acid (OA), MNPs were coated with OA (MNPs-OA) before moving to the toluene phase with the addition of salt. At OA concentration of 0.3 wt%, most of the nucleated MNPs were hydrophobic and well dispersed in the toluene phase. Using DVB as a monomer for ms CRP, high encapsulation efficiency (92 %EE) of MNPs-OA was obtained, with low free polymer particle formation. By contrast, large amounts of free polymer particles were observed at low %EE (32%) of MNPs. The main driving force for high %EE was obtained by coating the surface of the MNPs by OA which increased hydrophobicity.


2018 ◽  
Vol 2018 (43) ◽  
pp. 5980-5987 ◽  
Author(s):  
Prakash B. Rathod ◽  
K. S. Ajish Kumar ◽  
Anjali A. Athawale ◽  
Ashok K. Pandey ◽  
Subrata Chattopadhyay

Author(s):  
Dm. A. Pomogailo ◽  
M. G. Spirin ◽  
V. M. Skobeeva ◽  
G. I. Dzhardimalieva ◽  
S. I. Pomogailo ◽  
...  

2008 ◽  
Vol 44 (2) ◽  
pp. 113-120 ◽  
Author(s):  
M. Timko ◽  
A. Dżarová ◽  
V. Závišová ◽  
M. Koneracká ◽  
A. Šprincová ◽  
...  

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