Improving thermo‐oxidative stability and mediums resistance of nitrile rubber via surface superhydrophobic modification

2021 ◽  
pp. 52016
Author(s):  
Xiaolong Lu ◽  
Jianshu Wang ◽  
Shuwei Cai ◽  
Ben Niu ◽  
Qin He ◽  
...  
Keyword(s):  
Oxidative Stability ◽  
Nitrile Rubber

scholarly journals Improving Thermo-Oxidative Stability of Nitrile Rubber Composites by Functional Graphene Oxide

Materials ◽  
2018 ◽  
Vol 11 (6) ◽  
pp. 921 ◽  
Author(s):  
Rui Zhong ◽  
Zhao Zhang ◽  
Hongguo Zhao ◽  
Xianru He ◽  
Xin Wang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Oxidative Stability ◽  
Nitrile Rubber ◽  
Rubber Composites ◽  
Functional Graphene Oxide

Experimental Assessment of the Practical Oxidative Stability of Lithium Thiophosphate Solid Electrolytes

2019 ◽  
Author(s):  
Georg Dewald ◽  
Saneyuki Ohno ◽  
Marvin Kraft ◽  
Raimund Koerver ◽  
Paul Till ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Solid State ◽  
Oxidative Stability ◽  
Photoelectron Spectroscopy ◽  
Solid Electrolytes ◽  
Stability Limit ◽  
Lithium Ion ◽  
High Energy ◽  
Redox Activity ◽  
Solid State Batteries

<p>All-solid-state batteries are often expected to replace conventional lithium-ion batteries in the future. However, the practical electrochemical and cycling stability of the best-conducting solid electrolytes, i.e. lithium thiophosphates, are still critical issues that prevent long-term stable high-energy cells. In this study, we use <i>stepwise</i><i>cyclic voltammetry </i>to obtain information on the practical oxidative stability limit of Li<sub>10</sub>GeP<sub>2</sub>S<sub>12</sub>, a Li<sub>2</sub>S‑P<sub>2</sub>S<sub>5</sub>glass, as well as the argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolytes. We employ indium metal and carbon black as the counter and working electrode, respectively, the latter to increase the interfacial contact area to the electrolyte as compared to the commonly used planar steel electrodes. Using a stepwise increase in the reversal potentials, the onset potential at 25 °C of oxidative decomposition at the electrode-electrolyte interface is identified. X‑ray photoelectron spectroscopy is used to investigate the oxidation of sulfur(-II) in the thiophosphate polyanions to sulfur(0) as the dominant redox process in all electrolytes tested. Our results suggest that after the formation of these decomposition products, significant redox behavior is observed. This explains previously reported redox activity of thiophosphate solid electrolytes, which contributes to the overall cell performance in solid-state batteries. The <i>stepwise cyclic voltammetry</i>approach presented here shows that the practical oxidative stability at 25 °C of thiophosphate solid electrolytes against carbon is kinetically higher than predicted by thermodynamic calculations. The method serves as an efficient guideline for the determination of practical, kinetic stability limits of solid electrolytes. </p>

Experimental Assessment of the Practical Oxidative Stability of Lithium Thiophosphate Solid Electrolytes

2019 ◽  
Author(s):  
Georg Dewald ◽  
Saneyuki Ohno ◽  
Marvin Kraft ◽  
Raimund Koerver ◽  
Paul Till ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Solid State ◽  
Oxidative Stability ◽  
Photoelectron Spectroscopy ◽  
Solid Electrolytes ◽  
Stability Limit ◽  
Lithium Ion ◽  
High Energy ◽  
Redox Activity ◽  
Solid State Batteries

<p>All-solid-state batteries are often expected to replace conventional lithium-ion batteries in the future. However, the practical electrochemical and cycling stability of the best-conducting solid electrolytes, i.e. lithium thiophosphates, are still critical issues that prevent long-term stable high-energy cells. In this study, we use <i>stepwise</i><i>cyclic voltammetry </i>to obtain information on the practical oxidative stability limit of Li<sub>10</sub>GeP<sub>2</sub>S<sub>12</sub>, a Li<sub>2</sub>S‑P<sub>2</sub>S<sub>5</sub>glass, as well as the argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolytes. We employ indium metal and carbon black as the counter and working electrode, respectively, the latter to increase the interfacial contact area to the electrolyte as compared to the commonly used planar steel electrodes. Using a stepwise increase in the reversal potentials, the onset potential at 25 °C of oxidative decomposition at the electrode-electrolyte interface is identified. X‑ray photoelectron spectroscopy is used to investigate the oxidation of sulfur(-II) in the thiophosphate polyanions to sulfur(0) as the dominant redox process in all electrolytes tested. Our results suggest that after the formation of these decomposition products, significant redox behavior is observed. This explains previously reported redox activity of thiophosphate solid electrolytes, which contributes to the overall cell performance in solid-state batteries. The <i>stepwise cyclic voltammetry</i>approach presented here shows that the practical oxidative stability at 25 °C of thiophosphate solid electrolytes against carbon is kinetically higher than predicted by thermodynamic calculations. The method serves as an efficient guideline for the determination of practical, kinetic stability limits of solid electrolytes. </p>

SOYBEAN AND SUNFLOWER BIODIESELS: EVALUATION OF OXIDATIVE STABILITY BY RANCIMAT AND DSC

2018 ◽  
Author(s):  
Igor de Mesquita Figueredo ◽  
Maria Alexsandra de Sousa Rios
Keyword(s):  
Oxidative Stability

Effect of Epoxy Resin Concentration on Some Mechanical Properties of Carbon Fabric/ Nitrile Rubber Reinforced Composites

2019 ◽  
Vol 9 (1) ◽  
pp. 1-15
Author(s):  
Sawsan Fakhry Halim ◽  
Said Sayed Gad El Kholy ◽  
HalaFikry Naguib ◽  
Riham Samir Hegazy ◽  
Nermen Mohamed Baheg
Keyword(s):  
Mechanical Properties ◽  
Epoxy Resin ◽  
Nitrile Rubber ◽  
Reinforced Composites ◽  
Carbon Fabric

Bonding strength improvement of adhesives based on butadiene-nitrile rubber and chlorinated rubber blends with metal chelates

2019 ◽  
pp. 2-8
Author(s):  
A.K. Alekhin ◽  
◽  
L.R. Lyusova ◽  
U.A. Naumova ◽  
S.V. Kotova ◽  
...  
Keyword(s):  
Bonding Strength ◽  
Metal Chelates ◽  
Nitrile Rubber ◽  
Rubber Blends ◽  
Butadiene Nitrile Rubber ◽  
Strength Improvement
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