ChemInform Abstract: HIGH-YIELD SYNTHESIS OF SILICON NITRIDE/SILICON CARBIDE CERAMIC MATERIALS BY PYROLYSIS OF A NOVEL POLYORGANOSILAZANE

1984 ◽  
Vol 15 (42) ◽  
Author(s):  
D. SEYFERTH ◽  
G. H. WISEMAN
1994 ◽  
Vol 347 ◽  
Author(s):  
Tzyy-Heng Alex Shan ◽  
Robert Cozzens

ABSTRACTSilicon carbide ceramic materials have been successfully formed from commercially available polycarbosilane using microwave radiation as the sole source of heat. Conventional thermal processing of the same polymeric precursor was also studied for comparison with microwave processing. Microwave heating enhances crystallinity at much lower curing temperature and within shorter times. Possible explanations for microwave enhanced processing are proposed.


2010 ◽  
Vol 42 (3) ◽  
pp. 297-303
Author(s):  
G. V. Stepanov ◽  
V. I. Zubov ◽  
A. L. Maistrenko ◽  
V. G. Kulich ◽  
S. I. Shestakov ◽  
...  

2002 ◽  
Vol 74 (11) ◽  
pp. 2137-2144 ◽  
Author(s):  
P. Šajgalík

This paper deals with the role of chemistry in the design of high-tech ceramic materials. Grain boundary composition of polycrystalline ceramics dictates the hardness fracture toughness and creep resistance of liquid-phase sintered silicon nitride and silicon carbide materials.


1992 ◽  
Vol 271 ◽  
Author(s):  
Joanne M. Schwark ◽  
Mark J. Sullivan

ABSTRACTA tailorable viscosity, liquid polysilazane has been developed which thermosets to a solid ceramic precursor for both silicon nitride (Si3N4) and silicon carbide (SiC). Conversion of the thermoset, crosslinked polysilazane to a ceramic material has been examined. Preferential formation of silicon carbide or silicon nitride is controlled by the pyrolysis conditions employed.


2016 ◽  
Vol 878 ◽  
pp. 108-113
Author(s):  
Noor Leha Abdul Rahman ◽  
Koay Mei Hyie ◽  
Anizah Kalam ◽  
Teng Wan Dung ◽  
Husna Elias

Porous biomorphic silicon carbide is a promising ceramic materials for used in wide variety of applications especially in filtration and separation. Wood derived silicon carbide retains the heterogeneous structure of initial wood. Silicon carbide ceramic was derived from Dark Red Meranti wood precursor in this study. The derivation process was prepared by reaction between liquid silicon and carbon preform. The carbon preform was obtained via pyrolysis process at 850 °C in Argon gas flow atmosphere. This process was followed by Si infiltration at 1500 °C for different holding hours. The density was determined using Archimedes method. SEM was performed to observe their microstructures while the compositions and phase analysis were analysed by EDX and XRD respectively. Thermogravimetric analysis showed that a major weight loss of about 60% of carbon perform due to the decomposition of cellulose and lignin.XRD results revealed the presence of SiC and excess of silicon. It was found that conversion efficiency of carbon into SiC has been improved when the holding time was increased.


Author(s):  
Mark van Roode ◽  
William D. Brentnall ◽  
Paul F. Norton ◽  
Gregory P. Pytanowski

A program has been initiated under the sponsorship of the Department of Energy (DOE), Office of Industrial Technology, to improve the performance of stationary gas turbines in cogeneration through the selective replacement of metallic hot section parts with uncooled ceramic components. It is envisioned that the successful demonstration of ceramic gas turbine technology, and the systematic incorporation of ceramics in existing and future gas turbines will enable more efficient engine operation, resulting in significant fuel savings, increased output power, and reduced emissions. The program which started in September, 1992, takes an engine of the Solar Centaur family of industrial gas turbines, and modifies the design of the hot section to accept ceramic first stage blades and first stage nozzles, and a ceramic combustor liner. The ceramic materials selected for the blade are silicon nitride, for the nozzle silicon nitride and silicon carbide, and for the combustor liner silicon carbide as well as two continuous fiber reinforced ceramic composites, one with a silicon carbide matrix and another with an oxide matrix. This paper outlines the approach, conceptual component design, and materials selection for the program.


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