ChemInform Abstract: The Iron(III)-Chloride System. A Study of the Stability Constants and of the Distribution of the Tetrachloro Species Between Organic Solvents and Aqueous Chloride Solutions (on the basis of spectrophotometric measurements.

1986 ◽  
Vol 17 (15) ◽  
Author(s):  
J. BJERRUM ◽  
I. LUKES
Keyword(s):  
Organic Solvents ◽  
Stability Constants ◽  
Chloride System ◽  
Chloride Solutions ◽  
System A ◽  
Aqueous Chloride ◽  
The Stability

Some phase relationships between basic bismuth chlorides in aqueous solutions at 25 °C

1987 ◽  
Vol 65 (12) ◽  
pp. 2824-2829 ◽  
Author(s):  
Peter Taylor ◽  
Vincent J. Lopata
Keyword(s):  
Aqueous Solutions ◽  
Equilibrium Constants ◽  
Natural Occurrence ◽  
Chloride Solutions ◽  
Gibbs Energies ◽  
Activity Ratios ◽  
Aqueous Chloride ◽  
The Stability ◽  
Experimental Values ◽  
Phase Relationships

Observations are reported on the interconversion of solid α-Bi2O3, Bi12O17Cl2, BiOCl, and a daubréeite-like phase tentatively identified as Bi2O2(OH)Cl, in aqueous chloride solutions at 25 °C. Equilibrium constants, K, for these interconversions are expressed as anion activity ratios, {Cl−}/{OH−}. Experimental values of K for equilibrium between Bi2O3 and each of the chlorides are 100.56 ± 0.20 for Bi12O17Cl2, 101.5 ± 0.4 for Bi2O2(OH)Cl, and 103.13 ± 0.04 for BiOCl; the fatter two represent metastable equilibria. These equilibrium constants yielded the following estimates of Gibbs energies of formation: Bi12O17Cl2, −3141 ± 6 kJ mol−1;"Bi2O2(OH)Cl", −696 ± 4 kJ mol−1; BiOCl, −321.5 ± 1.3 kJ mol−1. Phase relationships among these solids are discussed, with reference to natural occurrence, other bismuth oxychlorides, and the stability of other basic salts of bismuth.

Excess free energies of mixing of Sr,Ba-bearing binary feldspar solid solutions (experimental data)

1995 ◽  
Vol 59 (394) ◽  
pp. 79-91 ◽  
Author(s):  
A. R. Kotelnikov ◽  
I. V. Chernysheva
Keyword(s):  
Solid Solutions ◽  
Phase State ◽  
Excess Energy ◽  
Free Energies ◽  
Chloride Solutions ◽  
Energy Of Mixing ◽  
Aqueous Chloride ◽  
The Stability ◽  
The Relationship ◽  
Excess Energy Of Mixing

AbstractThe distribution of potassium and strontium, potassium and barium between feldspars and aqueous chloride solutions was studied at 700°C, 2 kbar and 800°C, 2 kbar respectively. The distribution of Sr and Ba between coexisting feldspar and chloride solutions is not ideal; Sr and Ba are enriched in feldspar relative to solution. In order to estimate the phase state of the chloride solutions, special experiments were conducted using the synthetic fluid-inclusion method in the systems KCl-BaCl2-H2O and KCl-SrCl2-H2O at 700–800°C, 2 kbar. It was shown that (0.5M KCl+0.5M SrCl2) aqueous solution is homogeneous at 800°C, 2 kbar. The 0.25–0.5M SrCl2 solutions are homogeneous at 700°C 2, kbar. The (0.5M KCl+0.5M BaCl2) solution is homogeneous at 700°C, 2 kbar and heterogeneous at 800°C, 2 kbar. Margules parameters for describing the excess energy of mixing of the (K,Sr)- and (K,Ba)-feldspar solid solutions were calculated. The integrated values of excess energy of mixing () were estimated for the different binary feldspar solid solutions, and a correlation of with the crystallochemical parameter ρ = (RA-RB)/D(Me-O) was observed. Feldspar solid solutions can be subdivided into three groups based on the relationship between , p and the stability of the solid solution.

NPLs — The Solution Recipe for Albania

2015 ◽  
Vol 3 (1) ◽  
pp. 48
Author(s):  
Elona Shehu ◽  
Elona Meka
Keyword(s):  
Interest Rate ◽  
Negative Relationship ◽  
Banking System ◽  
Gdp Growth ◽  
System A ◽  
Analysis Technique ◽  
Recent Financial Crisis ◽  
The Stability ◽  
Asset Quality ◽  
Macroeconomic Determinants

The quality of the loan portfolio in Albanian banking system is facing many obstacles during the last decade. In this paper we look at possible determinants of assets quality. During the recent financial crisis commercial banks were confronted with deteriorating asset quality that threatened not only the banking industry, but also the stability of the entire financial system. This study aims to examine the correlation between non-performing loans and the macroeconomic determinants in Albania during the last decade. NPLs are considered to be of a high importance as they represent the high risk exposure of banking system. A solid bank with healthy assets increases the market efficiency. Our approach is based on a panel data regression analysis technique from 2005-2015. Within this methodology this study finds robust evidence on the existing relationship between lending interest rate, real GDP growth and NPLs. We expect to find a negative relationship between lending interest rate and asset quality. Further we assume an inverse relationship between GDP growth and non-performing loans, suggesting that NPLs decrease if the economy is growing. Furthermore this study proposes a solution platform, which looks deeper into the possibility of creating a secondary active market for troubled loans, restructuring the banking system or implementing the Podgorica model. This research paper opens a new lieu of discussion in terms of academic debates and decision-making policies.

In the stability of paints and varnishes for protective and decorative wood finish

2016 ◽  
Author(s):  
Ю.И. Цой
Keyword(s):  
Organic Solvents ◽  
Evaluation Criteria ◽  
Ternary Systems ◽  
Solubility Parameters ◽  
Formaldehyde Resin ◽  
Film Forming ◽  
The Difference ◽  
Molecular Forces ◽  
The Stability ◽  
Thermodynamic Interaction

Задача получения однородного состава ЛКМ сводится к правильному выбору пленкообразователей и соответствующих растворителей и, в случае необходимости, разбавителей и добавок. На основе положений теории растворимости была проведена оценка совместимости компонентов и стабильности таких систем. Критериями оценки были приняты параметры растворимости и термодинамического взаимодействия. Исследовали совместимость алкидных лаков с аминоформальдегидными смолами в бутаноле, и результаты этих исследований представлены в треугольной фазовой диаграмме. Для оценки совместимости смол по результатам расчета параметров термодинамического взаимодействия были построены спинодали для тройных систем. Как показывает анализ результатов проведенных исследований, даже при большой разности ?? = |?12 – ?13| = 0,2 наблюдается небольшая область несовместимости. С уменьшением разности ?? область несовместимости сужается. При ?23 > ?с область несовместимости расширяется как для ? = 0,2, так и для ?? = 0,1 и ?? = 0. Таким образом, для таких систем на совместимость компонентов, в первую очередь, влияет их взаимодействие между собой – чем оно больше, тем лучше они совместимы. Проведенные исследования показали, что парциальные параметры растворимости, учитывающие природу когезионных сил, более объективно характеризуют растворимость пленкообразующих смол в органических растворителях, чем их общий параметр растворимости. Растворимость пленкообразующих алкидных и этерифицированных аминоформальдегидных смол в органических растворителях обусловлена термодинамическим взаимодействием молекулярных сил различной природы. Стабильность смеси алкидной и этерифицированной аминоформальдегидной смолы в бутаноле обусловлена в большей степени термодинамическим взаимодействием молекулярных сил; при этом степень бутанолизации меламиноформальдегидной смолы оказывает наибольшее влияние на стабильность cистемы. Проведенные исследования по стабильности лакокрасочных смесей из различных пленкообразующих смол на основе рассмотренных критериев оценки могут быть использованы для совершенствования технологии защитно-декоративной отделки древесины. The problem of obtaining a homogeneous composition of the coatings is reduced to the proper selection of film-forming agents, and diluent and, if appropriate, diluents and additives. On the basis of the theory of solubility, we have carried out the assessment of the compatibility of the components and stability of such systems. The evaluation criteria were adopted the parameters of the solubility and thermodynamic interaction. Researched the compatibility with alkyd varnishes aminoformaldehyde resin in butanol, and the results of these studies are presented in the triangular phase diagram. To evaluate the compatibility of the resins according to the results of calculation of thermodynamic parameters of interaction were built spinodal for ternary systems. As the analysis of the results of the studies, even when the difference ??|?12 – ?13| = 0,2 there is a small area of incompatibility. With the decrease of the difference ? ? region incompatibility narrows. When ?23> ?с region incompatibility extends to ?? = 0,2, and for ?? = 0.1 and ?? = 0. Thus, for such systems, compatibility of components, primarily, affects their interaction with each other – the further away it is, the better they are compatible. Studies have shown that the partial solubility parameters, which take into account the nature of cohesive forces, more objectively characterize the solubility of film-forming resins in organic solvents than their total solubility parameter. The solubility and film-forming aminoformaldehyde esterified alkyd resins in organic solvents due to thermodynamic interaction of molecular forces of different nature. Тhe stability of the mixture and aminoformaldehyde esterified alkyd resin in butanol is generated largely by thermodynamic forces of molecular interaction; the degree of butanolate melamine-formaldehyde resin has the greatest effect on the stability of the system. Conducted research on the stability of the paint mixtures of various film-forming resins on the basis of the evaluation criteria can be used to improve the technology of protective and decorative wood finish.

Extraction of strontium and barium salts by the nitrobenzene solution of dicarbolide in the presence of glymes

1985 ◽  
Vol 50 (3) ◽  
pp. 581-599 ◽  
Author(s):  
Petr Vaňura ◽  
Emanuel Makrlík
Keyword(s):  
Stability Constants ◽  
Organic Phase ◽  
Equilibrium Constants ◽  
Minor Role ◽  
Nitrobenzene Solution ◽  
Ligand Structure ◽  
Stability Constants Of Complexes ◽  
Separation Factors ◽  
The Stability ◽  
A Minor

Extraction of microamounts of Sr2+ and Ba2+ (henceforth M2+) from the aqueous solutions of perchloric acid (0.0125-1.02 mol/l) by means of the nitrobenzene solutions of dicarbolide (0.004-0.05 mol/l of H+{Co(C2B9H11)2}-) was studied in the presence of monoglyme (only Ba2+), diglyme, triglyme, and tetraglyme (CH3O-(CH2-CH2O)nCH3, where n = 1, 2, 3, 4). The distribution of glyme betweeen the aqueous and organic phases, the extraction of the protonized glyme molecule HL+ together with the extraction of M2+ ion and of the glyme complex with the M2+ ion, i.e., ML2+ (where L is the molecule of glyme), were found to be the dominating reactions in the systems under study. In the systems with tri- and tetraglymes the extraction of H+ and M2+ ions solvated with two glyme molecules, i.e., the formation of HL2+ and ML22+ species, can probably play a minor role. The values of the respective equilibrium constants, of the stability constants of complexes formed in the organic phase, and the theoretical separation factors αBa/Sr were determined. The effect of the ligand structure on the values of extraction and stability constants in the organic phase is discussed.

Towards a new design with generic modeling and adaptive control of a transformable quadrotor

2021 ◽  
pp. 1-31
Author(s):  
S.H. Derrouaoui ◽  
Y. Bouzid ◽  
M. Guiatni
Keyword(s):  
Adaptive Control ◽  
Control Strategy ◽  
Experimental Tests ◽  
Generic Model ◽  
System Control ◽  
System A ◽  
Viable Solution ◽  
Generic Modeling ◽  
Adaptive Control Strategy ◽  
The Stability

Abstract Recently, transformable Unmanned Aerial Vehicles (UAVs) have become a subject of great interest in the field of flying systems, due to their maneuverability, agility and morphological capacities. They can be used for specific missions and in more congested spaces. Moreover, this novel class of UAVs is considered as a viable solution for providing flying robots with specific and versatile functionalities. In this paper, we propose (i) a new design of a transformable quadrotor with (ii) generic modeling and (iii) adaptive control strategy. The proposed UAV is able to change its flight configuration by rotating its four arms independently around a central body, thanks to its adaptive geometry. To simplify and lighten the prototype, a simple mechanism with a light mechanical structure is proposed. Since the Center of Gravity (CoG) of the UAV moves according to the desired morphology of the system, a variation of the inertia and the allocation matrix occurs instantly. These dynamics parameters play an important role in the system control and its stability, representing a key difference compared with the classic quadrotor. Thus, a new generic model is developed, taking into account all these variations together with aerodynamic effects. To validate this model and ensure the stability of the designed UAV, an adaptive backstepping control strategy based on the change in the flight configuration is applied. MATLAB simulations are provided to evaluate and illustrate the performance and efficiency of the proposed controller. Finally, some experimental tests are presented.

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