ChemInform Abstract: Water Soluble Phosphanes. Part 9. Nucleophilic Phosphanylation of Fluoroaromatic Compounds with Carboxyl, Carboxymethyl, and Aminomethyl Functionalities - An Efficient Synthetic Route to Amphiphilic Arylphosphanes.

ChemInform ◽  
2010 ◽  
Vol 29 (14) ◽  
pp. no-no
Author(s):  
M. HINGST ◽  
M. TEPPER ◽  
O. STELZER
Keyword(s):  
Water Soluble ◽  
Synthetic Route

Synthesis of a protein modifying agent. A water-soluble stable free radical

1980 ◽  
Vol 58 (7) ◽  
pp. 714-715 ◽  
Author(s):  
Sangram Sisodia ◽  
R. Dean Martz ◽  
N. Bosworth ◽  
Gary Lammert ◽  
J. D. Reinheimer
Keyword(s):  
Free Radical ◽  
Water Soluble ◽  
Sulfonate Group ◽  
Benzene Sulfonate ◽  
Synthetic Route ◽  
Stable Free Radical ◽  
Sodium Sulfonate ◽  
Modifying Agent ◽  
Synthetic Routes

Two synthetic routes to prepare a water-soluble stable free radical were investigated. The first product, sodium-2,4-dinitro-5-(4′-amino-2′,2′,6′,6′-tetramethylpiperidine-1-oxyl)benzene sulfonate, was water soluble but the sulfonate group was not readily replaceable with nucleophiles. The second synthetic route yielded N(4′-(2′,2′,6′,6′-tetramethylpiperidine-1-oxyl))-3,5-dinitro-4-sodium sulfonate benzamide, which was water soluble and its sulfonate group was readily replaced by nucleophiles.

scholarly journals Synthesis of titanium-based ceramics by a new synthetic route of water-soluble titanium complexes

2011 ◽  
Vol 119 (1390) ◽  
pp. 494-497 ◽  
Author(s):  
Kazuhiro YAMAMOTO ◽  
Satoshi MATSUSHIMA ◽  
Koji TOMITA ◽  
Yasuyuki MIURA ◽  
Masato KAKIHANA
Keyword(s):  
Water Soluble ◽  
Synthetic Route ◽  
Titanium Complexes

scholarly journals Pee-dots: biocompatible fluorescent carbon dots derived from the upcycling of urine

2016 ◽  
Vol 18 (1) ◽  
pp. 243-250 ◽  
Author(s):  
Jeremy B. Essner ◽  
Charles H. Laber ◽  
Sudhir Ravula ◽  
Luis Polo-Parada ◽  
Gary A. Baker
Keyword(s):  
Carbon Dots ◽  
Water Soluble ◽  
Synthetic Route ◽  
One Step ◽  
Fluorescent Carbon Dots ◽  
Fluorescent Carbon

We have demonstrated an easy, economic, one-step synthetic route to water-soluble fluorescent carbon dots derived from the thermal upcycling of urine.

Synthesis and LCST-type phase behavior of water-soluble polypeptide with Y-shaped and charged side-chains

2016 ◽  
Vol 7 (10) ◽  
pp. 1922-1930 ◽  
Author(s):  
Yanzhi Xu ◽  
Mengxiang Zhu ◽  
Minjie Li ◽  
Ying Ling ◽  
Haoyu Tang
Keyword(s):  
Phase Behavior ◽  
Water Soluble ◽  
Side Chains ◽  
Synthetic Route ◽  
Type Phase ◽  
Phase Behaviors ◽  
First Time

Water-soluble thermoresponsive polypeptides with LCST-type phase behaviors bearing Y-shaped and charged side-chains have been reported for the first time by a multi-step synthetic route.

Water-soluble lysine-containing polypeptides. VI. A study of annealed complexes between calf thymus DNA and the following copolymers: poly-(L-lysyl-X), where X = Gly, L-Ala, L-Val, L-Leu, and L-Phe

1978 ◽  
Vol 56 (20) ◽  
pp. 2657-2664 ◽  
Author(s):  
Sandra L. Kielland ◽  
Lewis A. Slotin ◽  
Ross E. Williams
Keyword(s):  
Electron Micrographs ◽  
Water Soluble ◽  
Optical Measurements ◽  
Calf Thymus Dna ◽  
Synthetic Route ◽  
Circular Dichroism Spectra ◽  
Chain Branching ◽  
Calf Thymus ◽  
Polypeptide Synthesis ◽  
Circular Dichroïsm

Turbidity measurements, circular dichroism spectra, electron micrographs, and thermal–optical measurements have been made on complexes between sonicated DNA and several polypeptides with the following structure: poly-(L-lysine-L-X) where X = Gly, Ala, Val, Leu, Phe. The results are influenced by any method of polypeptide synthesis which results in chain branching of the polypeptide. When polypeptides prepared by the same synthetic route are incorporated into the complexes the results also depend on the polypeptide used. Five possible explanations are offered as sources of the latter observations.

Synthesis of PEG-supported organotrifluoroborates and their applications in palladium-catalyzed homo-coupling reactions

2015 ◽  
Vol 44 (10) ◽  
pp. 4759-4764
Author(s):  
Li Yong ◽  
Min-Liang Yao ◽  
David W. Blevins ◽  
George W. Kabalka
Keyword(s):  
Room Temperature ◽  
Water Soluble ◽  
Coupling Reactions ◽  
Synthetic Route ◽  
Palladium Catalyzed

A general synthetic route to water-soluble PEG-supported organotrifluoroborates has been developed. In the presence of air and catalytic amounts of Pd(OAc)2, the PEG-supported organotrifluoroborates undergo homo-coupling reactions smoothly at room temperature.

scholarly journals A Malonyl-Based Scaffold for Conjugatable Multivalent Carbohydrate-BODIPY Presentations

Molecules ◽  
2019 ◽  
Vol 24 (11) ◽  
pp. 2050 ◽  
Author(s):  
Clara Uriel ◽  
Rebeca Sola-Llano ◽  
Jorge Bañuelos ◽  
Ana Gomez ◽  
J. Lopez
Keyword(s):  
Amino Acid ◽  
Water Soluble ◽  
Hydroxyl Groups ◽  
Synthetic Route ◽  
Fluorescent Markers ◽  
Boron Dipyrromethene

A concise synthetic route from methylmalonate to a tetravalent aliphatic scaffold has been developed. The ensuing tetra-tethered derivative is equipped with two hydroxyl groups, as well as orthogonal alkene and alkyne functionalities. The usefulness of the scaffold has been demonstrated with the preparation of two representative multivalent derivatives: (i) a tetravalent compound containing two D-mannose units, one fluorescent boron-dipyrromethene (BODIPY) dye and a suitably functionalized amino acid and (ii) by way of dimerization and saponification, a water-soluble tetramannan derivative containing two fluorescent BODIPY units. Additionally, photophysical measurements conducted on these derivatives support the viability of the herein designed single and double BODIPY-labeled carbohydrate-based clusters as fluorescent markers.

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