ChemInform Abstract: Syntheses and Properties of 11,11,12,12-Tetracyano-2,6-anthraquinodimethane (TANT) and Its 9,10-Dichloro Derivative as Novel Extensive Electron Acceptors.

Conducting polymers comprises a new class of materials achieving electrical conductivities which rival those of the best metals. The parent compounds (conjugated polymers) are quasi-one-dimensional semiconductors. These polymers can be doped by electron acceptors or electron donors. The prototype of these materials is polyacetylene (PA). There are various other conjugated polymers such as polyparaphenylene, polyphenylenevinylene, polypoyrrole or polythiophene. The doped systems, i.e. the conducting polymers, have intersting potential technological applications such as replacement of conventional metals in electronic shielding and antistatic equipment, rechargable batteries, and flexible light emitting diodes.Although these systems have been investigated almost 20 years, the electronic structure of the doped metallic systems is not clear and even the reason for the gap in undoped semiconducting systems is under discussion.

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The influence of potassium dichromate on dissimilatory reduction of sulfate and nitrate ions by bacteria Desulfovibrio sp.

Ecology and Noospherology ◽

10.15421/031708 ◽

2017 ◽

Vol 28 (1-2) ◽

pp. 84-95

Author(s):

O. M. Moroz ◽

S. O. Hnatush ◽

Ch. I. Bohoslavets ◽

T. M. Hrytsun’ ◽

B. M. Borsukevych

Keyword(s):

Electron Acceptor ◽

Potassium Dichromate ◽

Anaerobic Respiration ◽

Sulfate Reducing Bacteria ◽

Negative Influence ◽

Electron Acceptors ◽

Metal Compounds ◽

Nitrate Ions ◽

Sulfate Reducing ◽

Reducing Bacteria

Sulfate reducing bacteria, capable to reductive transformation of different nature pollutants, used in biotechnologies of purification of sewage, contaminated by carbon, sulfur, nitrogen and metal compounds. H2S formed by them sediment metals to form of insoluble sulfides. Number of metals can be used by these microorganisms as electron acceptors during anaerobic respiration. Because under the influence of metal compounds observed slowing of bacteria metabolism, selection isolated from technologically modified ecotops resistant to pollutions strains is important task to create a new biotechnologies of purification. That’s why the purpose of this work was to study the influence of potassium dichromate, present in medium, on reduction of sulfate and nitrate ions by sulfate reducing bacteria Desulfovibrio desulfuricans IMV K-6, Desulfovibrio sp. Yav-6 and Desulfovibrio sp. Yav-8, isolated from Yavorivske Lake, to estimate the efficiency of possible usage of these bacteria in technologies of complex purification of environment from dangerous pollutants. Bacteria were cultivated in modified Kravtsov-Sorokin medium without SO42- and FeCl2×4H2O for 10 days. To study the influence of K2Cr2O7 on usage by bacteria SO42- or NO3- cells were seeded to media with Na2SO4×10H2O or NaNO3 and K2Cr2O7 at concentrations of 1.74 mM for total content of electron acceptors in medium 3.47 mM (concentration of SO42- in medium of standard composition). Cells were also seeded to media with 3.47 mM Na2SO4×10H2O, NaNO3 or K2Cr2O7 to investigate their growth in media with SO42-, NO3- or Cr2O72- as sole electron acceptor (control). Biomass was determined by turbidymetric method, content of sulfate, nitrate, dichromate, chromium (III) ions, hydrogen sulfide or ammonia ions in cultural liquid – by spectrophotometric method. It was found that K2Cr2O7 inhibits growth (2.2 and 1.3 times) and level of reduction by bacteria sulfate or nitrate ions (4.2 and 3.0 times, respectively) at simultaneous addition into cultivation medium of 1.74 mM SO42- or NO3- and 1.74 mM Cr2O72-, compared with growth and level of reduction of sulfate or nitrate ions in medium only with SO42- or NO3- as sole electron acceptor. Revealed that during cultivation of bacteria in presence of equimolar amount of SO42- or NO3- and Cr2O72-, last used by bacteria faster, content of Cr3+ during whole period of bacteria cultivation exceeded content H2S or NH4+. K2Cr2O7 in medium has most negative influence on dissimilatory reduction by bacteria SO42- than NO3-, since level of nitrate ions reduction by cells in medium with NO3- and Cr2O72- was a half times higher than level of sulfate ions reduction by it in medium with SO42- and Cr2O72-. The ability of bacteria Desulfovibrio sp. to priority reduction of Cr2O72- and after their exhaustion − NO3- and SO42- in the processes of anaerobic respiration can be used in technologies of complex purification of environment from toxic compounds.

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Photoconductivity in Vacuum Deposited Films of Silicon-Based Polymers

MRS Proceedings ◽

10.1557/proc-444-191 ◽

1996 ◽

Vol 444 ◽

Author(s):

H. Okumoto ◽

M. Shimomura ◽

N. Minami ◽

Y. Tanabe

Keyword(s):

Charge Transfer ◽

Chemical Modification ◽

Electronic Transport ◽

Hole Transport ◽

Electron Acceptors ◽

Oxygen Atmosphere ◽

Dangling Bonds ◽

Silicon Based ◽

Deposited Films

AbstractSilicon-based polymers with σconjugated electrons have specific properties; photoreactivity for microlithography and photoconductivity for hole transport materials. To explore the possibility of combining these two properties to develop photoresists with electronic transport capability, photoconductivity of polysilanes is investigated in connection with their photoinduced chemical modification. Increase in photocurrent is observed accompanying photoreaction of poly(dimethylsilane) vacuum deposited films. This increase is found to be greatly enhanced in oxygen atmosphere. Such changes of photocurrent can be explained by charge transfer to electron acceptors from Si dangling bonds postulated to be formed during photoreaction.

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Phosphoryl- and Phosphonium-Bridged Viologens as Stable Two- and Three-Electron Acceptors for Organic Electrodes

10.26434/chemrxiv.12711770.v1 ◽

2020 ◽

Author(s):

Colin R. Bridges ◽

Andryj M. Borys ◽

Vanessa Béland ◽

Joshua R. Gaffen ◽

Thomas Baumgartner

Keyword(s):

Molecular Weight ◽

Organic Molecules ◽

Electrode Materials ◽

High Energy ◽

Electron Acceptors ◽

Low Molecular Weight ◽

Reduction Potentials ◽

Organic Electrode ◽

High Reduction ◽

High Specific Energy

Low molecular weight organic molecules that can accept multiple electrons at high<br>reduction potentials are sought after as electrode materials for high-energy sustainable batteries. To date their synthesis has been difficult, and organic scaffolds for electron donors significantly outnumber electron acceptors. Herein, we report two highly electron deficient phosphaviologen derivatives from a phosphorus-bridged 4,4-bipyridine and characterize their electrochemical properties. Phosphaviologen sulfide (PVS) and P-methyl phosphaviologen (PVM) accept two and three electrons at high reduction potentials, respectively. PVM can reversibly accept 3 electrons between 3-3.6 V vs. Li/Li+ with an equivalent molecular weight of 102 g/(mol e-) (262 mAh/g), making it a promising scaffold for sustainable organic electrode materials having high specific energy densities.

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Do We Need to Re-write the Electro-Optical Rule Book for Non-Fullerene Electron Acceptors?

10.29363/nanoge.onlinehopv.2020.018 ◽

2020 ◽

Author(s):

Paul Meredith ◽

Ardalan Armin ◽

Oskar Sandberg ◽

Stefan Zeiske ◽

Wei Li ◽

...

Keyword(s):

Electron Acceptors

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Природные материалы для сорбционной очистки хром- и кадмийсодержащих инфильтратов полигонов ТБО

Vodosnabzhenie i sanitarnaia tehnika ◽

10.35776/mnp.2019.12.02 ◽

2019 ◽

pp. 13-19

Author(s):

A. Safonov ◽

N. Andriushchenko ◽

N. Popova ◽

K. Boldyrev

Keyword(s):

Sorption Capacity ◽

Electron Acceptors ◽

Bacterial Cells ◽

Maximum Sorption Capacity ◽

Sorption Material ◽

Maximum Sorption ◽

Properties Of Materials ◽

Solid Waste Landfills ◽

Sorption Characteristics

Проведен анализ сорбционных характеристик природных материалов (вермикулит, керамзит, перлит, цеолит Трейд ) при очистке кадмий- и хромсодержащих сточных вод с высокой нагрузкой по ХПК. Установлено, что цеолит обладает максимальными сорбционными характеристиками для Cd и Cr и наименьшим биологическим обрастанием. При использовании вермикулита и керамзита или смесей на их основе можно ожидать увеличения сорбционной емкости для Cd и Сr при микробном обрастании, неизбежно происходящем в условиях контакта с водами, загрязненными органическими соединениями и биогенами. При этом биообрастание может повысить иммобилизационную способность материалов для редоксзависимых металлов за счет ферментативных ресурсов бактериальных клеток, использующих их в качестве акцепторов электронов. Эффект микробного обрастания разнонаправленно изменял параметры материалов: для Cr в большинстве случаев уменьшение и для Cd значительное увеличение. При этом дополнительным эффектом иммобилизации Cr является его биологическое восстановление биопленками. Варьируя состав сорбционного материала, можно подбирать смеси, оптимально подходящие для очистки вод инфильтратов с полигонов твердых бытовых отходов с высокой нагрузкой по ХПК и биогенным элементам как при использовании in situ, так и в системах на поверхности.The analysis of the sorption characteristics of natural materials (vermiculite, expanded clay, perlite, Trade zeolite) during the purification of cadmium and chromium-containing leachate with a high COD load was carried out. It was determined that zeolite had the maximum sorption capacity for Cd and Cr and the lowest biological fouling. When using vermiculite and expanded clay or mixtures on their basis, one can expect an increase in the sorption capacity for Cd and Cr during microbial fouling that inevitably occurs during contacting with water polluted with organic compounds and nutrients. In this case biofouling can increase the immobilization properties of materials for redox-dependent metals due to the enzymatic resources of bacterial cells that use them as electron acceptors. The effect of microbial fouling changed the parameters of materials in different directions: for Cr, in most cases, downward, and for Cd, significantly upward. Moreover, chromium biological recovery by biofilms is an additional effect of immobilization. Varying the composition of the sorption material provides for selecting mixtures that are optimally suitable for the purification of leachates from solid waste landfills with high COD and nutrients load, both when used in situ and in surface systems.

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Highly efficient fused ring electron acceptors based on a new undecacyclic core

Materials Chemistry Frontiers ◽

10.1039/d0qm00984a ◽

2021 ◽

Author(s):

Chun-Ru Wang ◽

Fuwen Zhao ◽

Dan He ◽

Jingming Xin ◽

Huotian Zhang ◽

...

Keyword(s):

Extinction Coefficient ◽

Energy Levels ◽

Electron Acceptors ◽

Highly Efficient ◽

Fused Ring ◽

Nanoscale Morphology

Two FREAs, IUIC-O and IUIC-T, based on an undecacyclic core were developed. IUIC-T having higher extinction coefficient, affords aligned energy levels with PBDB-T, finer nanoscale morphology and more orderly molecular...

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