ChemInform Abstract: Solvent Free Beckmann Rearrangement of Ketoximes by Anhydrous Ferric Chloride.

ChemInform ◽  
2010 ◽  
Vol 32 (47) ◽  
pp. no-no
Author(s):  
M. M. Khodaei ◽  
F. A. Meybodi ◽  
N. Rezai ◽  
P. Salehi
Keyword(s):  
Ferric Chloride ◽  
Beckmann Rearrangement ◽  
Solvent Free ◽  
Anhydrous Ferric Chloride

SOLVENT FREE BECKMANN REARRANGEMENT OF KETOXIMES BY ANHYDROUS FERRIC CHLORIDE

2001 ◽  
Vol 31 (13) ◽  
pp. 2047-2050 ◽  
Author(s):  
M. M. Khodaei ◽  
F. A. Meybodi ◽  
N. Rezai ◽  
P. Salehi
Keyword(s):  
Ferric Chloride ◽  
Beckmann Rearrangement ◽  
Solvent Free ◽  
Anhydrous Ferric Chloride

Iron-Zircon Pigments Prepared by Non-Hydrolytic Sol-Gel Method at Low Temperature

2011 ◽  
Vol 412 ◽  
pp. 223-226 ◽  
Author(s):  
Wei Hui Jiang ◽  
Yan Hui Yang ◽  
Qing Xia Zhu ◽  
Jian Min Liu
Keyword(s):  
Crystal Structure ◽  
Low Temperature ◽  
Ferric Chloride ◽  
Lithium Fluoride ◽  
Sol Gel ◽  
Zircon Crystal ◽  
Molar Ratio ◽  
Gel Method ◽  
Sol Gel Method ◽  
Anhydrous Ferric Chloride

ron-zircon pigment has been synthesized by non-hydrolytic sol-gel method using zirconium chloride and tetraethoxysilane as precursors, anhydrous ferric chloride as colorant, lithium fluoride as mineralizer and anhydrous ethanol as solvent. Iron-zircon pigment has been characterized by means of DTA-TG, XRD, Colorimeter and TEM. The results show that only a small fraction of iron is incorporated in the zircon crystal structure while the remaining iron cations are trapped within the zircon matrix. The iron-zircon with the red value (a*) of 20.64 can be synthesized at 700°C with the optimum Fe/Zr molar ratio of 0.2.

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