Synthesis of Polyoxygenated Steroids with Transition Metal Based Oxidants: Methyltrioxorhenium—Hydrogen Peroxide System, Ruthenium Tetraoxide, Osmium Tetraoxide and Potassium Permanganate

ChemInform ◽  
2005 ◽  
Vol 36 (31) ◽  
Author(s):  
D. Musumeci ◽  
D. Sica ◽  
F. Zollo
Keyword(s):  
Hydrogen Peroxide ◽  
Transition Metal ◽  
Potassium Permanganate ◽  
Osmium Tetraoxide ◽  
Ruthenium Tetraoxide

Catalytic oxidation of α-pinene by transition metal using t-butyl hydroperoxide and hydrogen peroxide

2003 ◽  
Vol 200 (1-2) ◽  
pp. 177-184 ◽  
Author(s):  
Badia Ait Allal ◽  
Larbi El Firdoussi ◽  
Smail Allaoud ◽  
Abdallah Karim ◽  
Yves Castanet ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Transition Metal ◽  
Catalytic Oxidation ◽  
Butyl Hydroperoxide

scholarly journals Ultramicrosensors based on transition metal hexacyanoferrates for scanning electrochemical microscopy

2013 ◽  
Vol 4 ◽  
pp. 649-654 ◽  
Author(s):  
Maria A Komkova ◽  
Angelika Holzinger ◽  
Andreas Hartmann ◽  
Alexei R Khokhlov ◽  
Christine Kranz ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Detection Limit ◽  
Transition Metal ◽  
Prussian Blue ◽  
Electrochemical Deposition ◽  
Mixed Layer ◽  
Scanning Electrochemical Microscopy ◽  
The Stability ◽  
Mixed Layers ◽  
Electrochemical Microscopy

We report here a way for improving the stability of ultramicroelectrodes (UME) based on hexacyanoferrate-modified metals for the detection of hydrogen peroxide. The most stable sensors were obtained by electrochemical deposition of six layers of hexacyanoferrates (HCF), more specifically, an alternating pattern of three layers of Prussian Blue and three layers of Ni–HCF. The microelectrodes modified with mixed layers were continuously monitored in 1 mM hydrogen peroxide and proved to be stable for more than 5 h under these conditions. The mixed layer microelectrodes exhibited a stability which is five times as high as the stability of conventional Prussian Blue-modified UMEs. The sensitivity of the mixed layer sensor was 0.32 A·M−1·cm−2, and the detection limit was 10 µM. The mixed layer-based UMEs were used as sensors in scanning electrochemical microscopy (SECM) experiments for imaging of hydrogen peroxide evolution.

Effect of Oxidant on the Leaching Rate of Indium from Water Quenching Slag

2013 ◽  
Vol 591 ◽  
pp. 122-125
Author(s):  
Li Jiao Yang ◽  
Si Chen ◽  
Yan Zhang ◽  
Nan Chun Chen ◽  
Jun Gao ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Sulfuric Acid ◽  
Potassium Permanganate ◽  
Crystal Violet ◽  
Acid Leaching ◽  
Water Quenching ◽  
Test Results ◽  
Leaching Rate ◽  
Initial Concentration ◽  
Solid Ratio

Extracting indium from water quenching slag, which contains poor indium, by two process of leaching, the effect of different oxidants and dosages on the leaching rate of indium in water quenching slag were studied. The leaching conditions: temperature 80 °C, leaching time 2 h, the liquid to solid ratio of neutral leaching 8︰1, the liquid to solid ratio of acid leaching 2︰1, initial concentration of sulfuric acid 500 g·L-1, adding different oxidants, the concentration was detected by crystal violet spectrophotometry. Test results showed that the leaching rate of indium was significantly improved by adding hydrogen peroxide and potassium permanganate. Compared with the effect of different oxidants, the effect of potassium permanganate was significantly higher than that of hydrogen peroxide on the leaching rate of indium.

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