Effect of Oxidant on the Leaching Rate of Indium from Water Quenching Slag

2013 ◽  
Vol 591 ◽  
pp. 122-125
Author(s):  
Li Jiao Yang ◽  
Si Chen ◽  
Yan Zhang ◽  
Nan Chun Chen ◽  
Jun Gao ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Sulfuric Acid ◽  
Potassium Permanganate ◽  
Crystal Violet ◽  
Acid Leaching ◽  
Water Quenching ◽  
Test Results ◽  
Leaching Rate ◽  
Initial Concentration ◽  
Solid Ratio

Extracting indium from water quenching slag, which contains poor indium, by two process of leaching, the effect of different oxidants and dosages on the leaching rate of indium in water quenching slag were studied. The leaching conditions: temperature 80 °C, leaching time 2 h, the liquid to solid ratio of neutral leaching 8︰1, the liquid to solid ratio of acid leaching 2︰1, initial concentration of sulfuric acid 500 g·L-1, adding different oxidants, the concentration was detected by crystal violet spectrophotometry. Test results showed that the leaching rate of indium was significantly improved by adding hydrogen peroxide and potassium permanganate. Compared with the effect of different oxidants, the effect of potassium permanganate was significantly higher than that of hydrogen peroxide on the leaching rate of indium.

Study on Leaching Zinc Calcine with High Iron

2013 ◽  
Vol 826 ◽  
pp. 118-121
Author(s):  
Jin Lin Yang ◽  
Hong Mei Zhang ◽  
Xiu Juan Su ◽  
Shao Jian Ma
Keyword(s):  
Sulfuric Acid ◽  
Acid Concentration ◽  
Great Influence ◽  
Sulfuric Acid Concentration ◽  
Acid Leaching ◽  
Leaching Rate ◽  
Iron Extraction ◽  
High Iron ◽  
Solid Ratio ◽  
Leaching Efficiency

In recent years, recovering zinc from zinc calcine with high iron has been a matter of discussion. In this paper, sulfuric acid leaching was carried out to assess the effect of several parameters on zinc and iron extraction in zinc calcine with high iron in which the grade of zinc and iron is 53.90% and 19.38%, respectively. Parameters, such as stirring speed, sulfuric acid concentration, liquid to solid ratio and leaching time, were investigated. The results show that leaching time has done nothing to the leaching rate, but has great influence on leaching efficiency. Liquid to solid ratio and sulfuric acid concentration have significant influence on leaching results, and stirring rate has not obvious influence on leaching results. Under the condition of 120g/L sulfuric acid, 6:1 liquid to solid ratio, 55°C leaching temperature and 120min leaching time, the recovery of zinc and iron is 82.24% and 9.64%, respectively. It is obvious that ZnO in zinc calcine is easy to dissolve in acidity solution, which shown in two aspects: high leaching rate and high leaching speed. ZnO can be dissolved entirely in sufficient sulfuric acid in 10min.

Study on Direct Acid Leaching Vanadium without Grinding and Roasting from Clay Vanadium Ore in Hunan

2013 ◽  
Vol 316-317 ◽  
pp. 882-886
Author(s):  
Wei He ◽  
Guo Hua Ye ◽  
Xiong Tong
Keyword(s):  
Sulfuric Acid ◽  
New Technology ◽  
Acid Leaching ◽  
Leaching Rate ◽  
Solid Ratio ◽  
Acid Type ◽  
Temperature Liquid ◽  
The Cost ◽  
Grinding System ◽  
Acid Dosage

Abstract：A new technology of direct acid leaching vanadium without grinding and roasting was put forward, and the effects of leaching factors including dosage of sulfuric acid, type and dosage of assistant leaching agent, leaching time and temperature, liquid-solid ratio on the vanadium leaching rate were systematically investigated. The results show that vanadium leaching rate could be up to 92.58% under the optimal conditions of sulfuric acid dosage of 30%, MnO2 as assistant leaching agent and its dosage of 1.5%, leaching time of 6h, leaching temperature of 90°C, liquid-solid ratio of 1:1, and the leaching performance is perfect. Due to leaving out the high costing grinding system and the complex roasting system, the new technology has advantages in shortening the process, decreasing the cost, avoiding pollution generated by roasting comparing with the traditional technologies, and it can meet the requirement of modern metallurgy very well.

Sulfuric Acid Leaching on Low Grade Oxide Ore

2013 ◽  
Vol 826 ◽  
pp. 122-125 ◽  
Author(s):  
Jin Lin Yang ◽  
Hong Mei Zhang ◽  
Gui Fang Wang ◽  
Shao Jian Ma ◽  
Min Zhang
Keyword(s):  
Sulfuric Acid ◽  
Sulfuric Acid Concentration ◽  
Acid Leaching ◽  
Strong Acid ◽  
Metal Extraction ◽  
Low Grade ◽  
Leaching Rate ◽  
Sulfuric Acid Leaching ◽  
Solid Ratio ◽  
Iron Leaching

In this paper, sulfuric acid leaching was carried out to assess the effect of several parameters on metal extraction in a low grade complex gossan ore in which the grade of zinc and iron is 13% and 40.2%, respectively. Parameters, such as sulfuric acid concentration, liquid to solid ratio and leaching temperature, were studied. The results show that the zinc leaching rate is almost 80%, while the iron leaching rate is about 45% used strong acid with 200g/L. It can be seen from the results that sulfuric acid leaching could not effectively recover zinc from gossan ores studied in this paper because of iron dissolving greatly.

Leaching kinetics of copper and valuable metal extraction from copper-cadmium residues of zinc hydrometallurgy by oxidation acid leaching

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jihao Guo ◽  
Hongao Xu ◽  
Bo Li ◽  
Yonggang Wei ◽  
Hua Wang
Keyword(s):  
Hydrogen Peroxide ◽  
Acid Concentration ◽  
Acid Leaching ◽  
Metal Extraction ◽  
Agitation Rate ◽  
Leaching Kinetics ◽  
Solid Ratio ◽  
Zinc Hydrometallurgy ◽  
Kinetics Of ◽  
Leaching Efficiency

Abstract Multiple purification of zinc sulfate solution is an important process for zinc hydrometallurgy, and large quantities of copper-cadmium residues are generated as byproducts in this process. Copper-cadmium residues contain a large number of valuable metals that must be recovered. A comprehensive extraction process has been proposed using sulfuric acid as the leaching reagent and hydrogen peroxide as the oxidizing reagent. The effects of acid concentration, leaching temperature, leaching time, liquid-to-solid ratio, hydrogen peroxide dosage and stirring speed on the leaching efficiency were investigated. The optimum conditions were determined as an acid concentration of 150 g/L, liquid-to-solid ratio of 4:1, hydrogen peroxide amount of 20 mL, time of 60 min, temperature of 30 °C, particle size of −d75 μm, and agitation rate of 300 r/min. It was concluded that the leaching efficiency of copper and cadmium reached 97%, but because of the existence of zinc sulfide in the residues, a lower leaching efficiency of zinc was obtained. Furthermore, the leaching kinetics of copper was also studied based on the shrinking core model. The activation energy for copper leaching was 5.06 kJ/mol, and the leaching process was controlled by the diffusion through the product layer.

Experimental Study on Sulfuric Acid Leaching Behavior of Chromite with Different Temperature

2011 ◽  
Vol 361-363 ◽  
pp. 628-631 ◽  
Author(s):  
Cheng Jun Liu ◽  
Jie Qi ◽  
Mao Fa Jiang
Keyword(s):  
Sulfuric Acid ◽  
Acid Leaching ◽  
Raw Material ◽  
Leaching Rate ◽  
Sulfuric Acid Leaching ◽  
Leaching Process ◽  
Pollution Problem ◽  
Environmental Pollution Problem ◽  
Leaching Solution ◽  
Leaching Residue

Utilizing Pakistan chromite as raw material, the rapid leaching of chromium and iron could be realized by the sulfuric acid leaching process on the condition of atmospheric pressure and the addition of oxidant A. And the leaching rate of chromium and iron would be 98.5% and 71.9%, respectively. The sulfuric acid leaching processes with different temperature were systematically studied by chemical analysis and phase analysis. The results showed that, with the increase of reaction temperature, the leaching rate of chromium would increase gradually, but the leaching rate of iron increased at first and then decreases and reached its maximum at 140°C. When the temperature > 160°C, the phases of the leaching residue were magnesium iron silicate and a few of silica, no chromohercynite, chrompicotite and magnesioferrite existed in the chromite. The leaching solution of sulfuric acid leaching process could be used for preparing the basic chrome sulfate, and there is no Cr6+ in the leaching residue and solution. The results would provide theoretical guidance for solving environmental pollution problem of Cr6+ in traditional chromate production process.

Study on Recovering Zinc from Gossan

2012 ◽  
Vol 454 ◽  
pp. 329-332 ◽  
Author(s):  
Jin Lin Yang ◽  
Shao Jian Ma ◽  
Wei Mo ◽  
Jin Peng Feng ◽  
Xiu Juan Su ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Sulfuric Acid Concentration ◽  
Acid Leaching ◽  
Leaching Rate ◽  
Sulfuric Acid Leaching ◽  
Alkaline Leaching ◽  
Physical Separation ◽  
Xrd Pattern ◽  
Diffraction Peaks ◽  
Roasting Temperature

In this paper, the conventional physical separation method such as flotation, gravity separation, magnetic separation, alkaline leaching and sulfuric acid leaching were studied. The effects of grinding fineness, amount of agent, magnetic intensity, roasting temperature, roasting time, the leaching agent and leaching time on the leaching of zinc were investigated, respectively. The results show that the leaching rate of zinc is below 50% in the conventional alkaline leaching, and the leaching rate of zinc is below 85% and the leaching rate of iron is above 35% in sulfuric acid leaching. Compared with XRD pattern of the raw ore, the different diffraction peaks of smithsonite is off in alkaline leaching products. In sulfuric acid leaching, the different diffraction peaks of smithsonite are off in the leaching products when sulfuric acid concentration is less than 60 g/L. After 60 g/L, the different diffraction peaks of smithsonite and siderite are off in the leaching products.

Recovery of Copper and Cobalt from Spent Aerospace Material with Pollution-Free Oxidant

2012 ◽  
Vol 476-478 ◽  
pp. 357-360 ◽  
Author(s):  
Yue Bin Xiao ◽  
Xue Jiao Zhou ◽  
Lei Cao ◽  
Ya Gao ◽  
Da Liu ◽  
...  
Keyword(s):  
Acid Leaching ◽  
Agitation Speed ◽  
Temperature Reaction ◽  
Initial Concentration ◽  
Solid Ratio ◽  
Aerospace Material ◽  
Valuable Element ◽  
C 30 ◽  
Optimized Conditions ◽  
Free Oxidation

The acid leaching of spent aerospace material with pollution-free oxidation is discussed. Effect of parameters including initial concentration of hydrochloric acid solution, leaching temperature, reaction time, agitation speed, liquid to solid ratio and concentration of oxidant on valuable element extractions are determined, the optimized conditions are 6 M, 60 °C, 30 min, 250 r/min, 6:1 and 0.0378 mol•L-1•min-1, respectively. The comprehensive results of experiments show that the extracting efficiency of Co and Cu are over 83% and 98% respectively when optimized conditions were adopted.

Factors on Leaching Zinc and Copper from Zinc Leach Residue

2014 ◽  
Vol 633 ◽  
pp. 169-172
Author(s):  
Li Jiao Yang ◽  
Nan Chun Chen ◽  
Xia Ping Zhong ◽  
Jun Gao ◽  
Yao Xiu Lang ◽  
...  
Keyword(s):  
Sulfuric Acid ◽  
Zinc Sulfide ◽  
Zinc Sulfate ◽  
Acid Leaching ◽  
Ion Concentration ◽  
Leach Residue ◽  
Sulfuric Acid Leaching ◽  
Edta Titration ◽  
Solid Ratio ◽  
Copper And Zinc

It is found that cuprous sulfite, zinc sulfate and zinc sulfide were the main phases of copper and zinc in zinc leach residue, through analyzing its composition and phase characteristics by XRF and XRD. The method that cooperate sulfuric acid leaching with oxidant was chosen. 60 g/L H2SO4 at 60 °C for 2 h with 4% KMnO4 and liquid/solid ratio of 5..1, 84.29 % of Cu and 92.02 % of Zn are extracted. The ion concentration of copper and zinc are tested by UV-VIS spectrophotometer and EDTA titration respectively. The results show that the amount of acid is sufficient for leaching at the condition of 60 g/L H2SO4 and liquid/solid ratio of 5..1. At the same time, copper change from low valence into high valence after adding KMnO4 which strengthen the leaching, and the chemical reaction can reach balance at 60 °C for 2 h. This method has good extraction effect on copper and zinc.

Oxygen Pressure Acid Leaching of Vanadium Slag

2011 ◽  
Vol 79 ◽  
pp. 242-247 ◽  
Author(s):  
Wang Zhong Mu ◽  
Ting An Zhang ◽  
Zhi He Dou ◽  
Guo Zhi Lü ◽  
Lan Hu ◽  
...  
Keyword(s):  
Oxygen Pressure ◽  
Acid Leaching ◽  
Leaching Rate ◽  
Vanadium Slag ◽  
Solid Ratio ◽  
Leaching Process ◽  
Oxygen Pressure Acid Leaching ◽  
Effects Of Temperature ◽  
Pressure Acid Leaching ◽  
Single Factor Experiment

Oxygen pressure acid leaching process was used to extract vanadium from vanadium slag (Panzhihua steelmaking plant of China). The single factor experiment was finished and the effects of temperature, leaching time, liquid to solid ratio, stirring speed, initial concentration of sulfuric acid, and were investigated on the leaching rate of vanadium, titanium and iron. The leachate and residue were characterized by ICP, XRF, XRD, SEM and EDX. The experiment results indicate when temperature is 140 °C, leaching time is 120 min, liquid to solid ratio is 20:1(ml:g), stirring speed is 500 rpm, initial acid concentration is 200 g/L, oxygen partial pressure is 0.5 MPa, and particle size is -0.075~+0.055 mm, leaching rate of vanadium is 97.89% and the content of vanadium in the residue is 0.586%. Leaching rate of titanium and iron is 12.78% and 94.45% respectively. Vanadium could be extracted effectively through the oxygen pressure acid leaching process.

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