Unusual Two-Dimensional Nickel(II) Complexes Based on [Ni(dien)]2+ and [M(CN)4]2− Building Blocks (M = Ni, Pd and Pt)− Synthesis, Structural Diversity and Magnetic Properties

2004 ◽  
Vol 2004 (9) ◽  
pp. 1886-1893 ◽  
Author(s):  
Iñaki Muga ◽  
Juan M. Gutiérrez-Zorrilla ◽  
Pablo Vitoria ◽  
Pascual Román ◽  
Luis Lezama ◽  
...  
2021 ◽  
Author(s):  
Kemryn Allen-Perry ◽  
Weston Straka ◽  
Danielle Keith ◽  
Shubo Han ◽  
C. Lewis Reynolds ◽  
...  

Two-dimensional materials based on transition metal carbides have been intensively studied due to their unique properties including metallic conductivity, hydrophilicity, and structural diversity and have shown great potential in several applications. While MXenes based on magnetic transition elements show interesting magnetic properties, not much is known about the magnetic properties of titanium-based MXenes. Here, we measured magnetic properties of Ti<sub>3</sub>C<sub>2</sub>T<sub>x </sub>MXenes synthesized by different chemical etching conditions. Our measurements indicate that there is a paramagnetic–antiferromagnetic (PM-AFM) phase transition, and the transition temperature depends on the synthesis procedure of MXenes. Our observation indicates that the magnetic properties of these MXenes can be tuned by the extent of chemical etching which can be beneficial for the design of MXene-based spintronic devices.


2020 ◽  
Vol 49 (13) ◽  
pp. 4012-4021 ◽  
Author(s):  
Ajit Kumar Kharwar ◽  
Sanjit Konar

A co-operative ligand approach leads to beautiful two-dimensional and three-dimensional architectures with interesting magnetic properties.


Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 694
Author(s):  
Kemryn Allen-Perry ◽  
Weston Straka ◽  
Danielle Keith ◽  
Shubo Han ◽  
Lewis Reynolds ◽  
...  

Two-dimensional materials based on transition metal carbides have been intensively studied due to their unique properties including metallic conductivity, hydrophilicity and structural diversity and have shown a great potential in several applications, for example, energy storage, sensing and optoelectronics. While MXenes based on magnetic transition elements show interesting magnetic properties, not much is known about the magnetic properties of titanium-based MXenes. Here, we measured the magnetic properties of Ti3C2Tx MXenes synthesized by different chemical etching conditions such as etching temperature and time. Our magnetic measurements were performed in a superconducting quantum interference device (SQUID) vibrating sample. These data suggest that there is a paramagnetic-antiferromagnetic (PM-AFM) phase transition and the transition temperature depends on the synthesis procedure of MXenes. Our observation indicates that the magnetic properties of these MXenes can be tuned by the extent of chemical etching, which can be beneficial for the design of MXenes-based spintronic devices.


2021 ◽  
Author(s):  
Kemryn Allen-Perry ◽  
Weston Straka ◽  
Danielle Keith ◽  
Shubo Han ◽  
C. Lewis Reynolds ◽  
...  

Two-dimensional materials based on transition metal carbides have been intensively studied due to their unique properties including metallic conductivity, hydrophilicity, and structural diversity and have shown great potential in several applications. While MXenes based on magnetic transition elements show interesting magnetic properties, not much is known about the magnetic properties of titanium-based MXenes. Here, we measured magnetic properties of Ti<sub>3</sub>C<sub>2</sub>T<sub>x </sub>MXenes synthesized by different chemical etching conditions. Our measurements indicate that there is a paramagnetic–antiferromagnetic (PM-AFM) phase transition, and the transition temperature depends on the synthesis procedure of MXenes. Our observation indicates that the magnetic properties of these MXenes can be tuned by the extent of chemical etching which can be beneficial for the design of MXene-based spintronic devices.


RSC Advances ◽  
2021 ◽  
Vol 11 (15) ◽  
pp. 8654-8663
Author(s):  
Fatima Zahra Ramadan ◽  
Flaviano José dos Santos ◽  
Lalla Btissam Drissi ◽  
Samir Lounis

Based on density functional theory combined with low-energy models, we explore the magnetic properties of a hybrid atomic-thick two-dimensional (2D) material made of germanene doped with fluorine atoms in a half-fluorinated configuration (Ge2F).


2021 ◽  
Vol 23 (10) ◽  
pp. 6171-6181
Author(s):  
Yaoqi Gao ◽  
Baozeng Zhou ◽  
Xiaocha Wang

It is found that the biaxial strain, electric field and interlayer distance can effectively modulate the electronic structure and magnetic properties of two-dimensional van der Waals heterostructures.


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