Performance and economic investigation of a combined phosphoric acid fuel cell/organic Rankine cycle/electrolyzer system for sulfuric acid production; Energy‐based organic fluid selection

2020 ◽  
Vol 44 (4) ◽  
pp. 2704-2725 ◽  
Author(s):  
Saber Sadeghi ◽  
Ighball Baniasad Askari
2014 ◽  
Vol 16 (4) ◽  
Author(s):  
B. Duysebaev ◽  
A. Abramov ◽  
S. Berstenev ◽  
N. Ryspanov ◽  
A.Y. Sokolov ◽  
...  

<p>The possibility and effectiveness of using sulfur dioxide and hydrogen sulfide as the fuel in low-temperature fuel cells at the sulfuric acid production site has been investigated. A fuel cell has been designed and constructed using palladium as a catalyst, which enables conversion of the energy of oxidation of sulfur dioxide and hydrogen sulfide to the electric energy. The experimental data showed that the use of hydrogen sulfide and sulfur dioxide as a fuel allows achieving the power of 1.0 and 0.5 mW, respectively. The <br />comparative studies with the use of hydrogen in the same fuel cell resulted in the power of about 2.0 mW, i.e. the use of hydrogen sulfide delivers a performance comparable with that of the hydrogen. The processes of oxidizing of the sulfur containing gases are used in our company in production of sulfuric acid. Oxidation <br />of these gases conducted using the conventional technological processes. The use of these processes to produce energy as a byproduct could be an attractive way to reduce the energy consumption of the whole process. Considering the relatively high power obtained in this work for the sulfur containing gases fed fuel <br />cells, the substitution of conventional oxidation of sulfur containing gases in this technological chain by the fuel cell oxidation, and by-producing the electric energy, could be very profitable for the energy efficiency enhancement of the main production process. In the future work, the design and development of fuel cell catalysts and membranes to enhance the performances of sulfur containing fuel cells will be significant</p>


2021 ◽  
Vol 13 (3) ◽  
pp. 1218
Author(s):  
Sharjeel Ashraf Ansari ◽  
Mustafa Khalid ◽  
Khurram Kamal ◽  
Tahir Abdul Hussain Ratlamwala ◽  
Ghulam Hussain ◽  
...  

The proton exchange membrane fuel cell (PEMFC) is the fastest growing fuel cell technology on the market. Due to their sustainable nature, PEMFCs are widely adopted as a renewable energy resource. Fabricating a PEMFC is a costly process; hence, mathematical modeling and simulations are necessary in order to fully optimize its performance. Alongside this, the feasibility of a waste heat recovery system based on the organic Rankine cycle is also studied and power generation for different operating conditions is presented. The fuel cell produces a power output of 1198 W at a current of 24A. It has 50% efficiency and hence produces an equal amount of waste heat. That waste heat is used to drive an organic Rankine cycle (ORC), which in turn produces an additional 428 W of power at 35% efficiency. The total extracted power hence stands at 1626 W. MATLAB/Simulink R2016a is used for modeling both the fuel cell and the organic Rankine cycle.


Author(s):  
Somasundaram Essakiappan ◽  
Harish S. Krishnamoorthy ◽  
Jorge Ramos-Ruiz ◽  
Prasad Enjeti ◽  
Mohamed Arifujjaman ◽  
...  

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