The utility of solid-phase microextraction in evaluating polycyclic aromatic hydrocarbon bioavailability during habitat restoration with dredged material at moderately contaminated sites

2017 ◽  
Vol 14 (2) ◽  
pp. 212-223 ◽  
Author(s):  
Amanda A Brennan ◽  
Nathan W Johnson
2004 ◽  
Vol 23 (2) ◽  
pp. 245 ◽  
Author(s):  
Carolyn M. Acheson ◽  
Qin Zhou ◽  
Yonggui Shan ◽  
Gregory D. Sayles ◽  
Margaret J. Kupferle

2003 ◽  
Vol 22 (3) ◽  
pp. 671-677 ◽  
Author(s):  
Margaret Mulvey ◽  
Michael C. Newman ◽  
Wolfgang K. Vogelbein ◽  
Michael A. Unger ◽  
David R. Ownby

2003 ◽  
Vol 22 (11) ◽  
pp. 2752 ◽  
Author(s):  
Stephen A. Diamond ◽  
Nicholas J. Milroy ◽  
Vincent R. Mattson ◽  
Larry J. Heinis ◽  
David R. Mount

2020 ◽  
Vol 2020 ◽  
pp. 1-9 ◽  
Author(s):  
Chenggang Cai ◽  
Pinggu Wu ◽  
Pingping Zhou ◽  
Dajin Yang ◽  
Zhengyan Hu

A gas chromatography-mass spectroscopy (GC-MS) method was developed to assess the infant exposure assessment from four important polycyclic aromatic hydrocarbon (PAH) markers in infant formula powder: benzo[a]anthracene, chrysene, benzo[b]fluoranthene, and benzo[a]pyrene (collectively referred to as PAH4). The developed method required the addition of an isotopically labeled internal standard, sample extraction under alkali conditions, a saponification step, and a solid-phase extraction purification step. In a controlled spike test, the average recovery rates of PAH4 were 77.3% to 111.8% and the relative standard deviations were 4.8% to 14.2% (n = 6). The quantitative limit (LOQ) and detection limit (LOD) of the method were 0.5 and 0.1 μg·kg−1, respectively. The PAH4 content was analyzed in 30 commercially available infant formula powders. The PAH4 content was found to be in the range of 0.1 to 0.87 μg·kg−1. Combined with the daily intake of infant milk powder in China, the average and maximum daily exposure of BaP for stage-1 infants in China are 0.45 ng/kg.bw.d−1 and 1.9 ng/kg.bw.d−1 and the PAH4 values are 8.6 ng/kg.bw.d−1 and 18.6 ng/kg.bw.d−1, respectively. The PAH4 content in the tested infant formula powders sold in the China were sufficiently low, and all of the tested products were safe for consumption.


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