Mechanism of oxidation of alanine by chloroaurate(III) complexes in acid medium: Kinetics of the rate processes

2009 ◽  
Vol 41 (7) ◽  
pp. 473-482 ◽  
Author(s):  
Pratik K. Sen ◽  
Nasimul Gani ◽  
Jayanta K. Midya ◽  
Biswajit Pal
Keyword(s):  
Acid Medium ◽  
Rate Processes ◽  
Mechanism Of Oxidation ◽  
Kinetics Of

Kinetics and Mechanism of Oxidation of Aliphatic Primary Alcohols with 1-Chlorobenzimidazole in Aqueous Acetic Acid Medium

2016 ◽  
Vol 230 (8) ◽  
Author(s):  
Muthusamy Rukmangathan ◽  
Vetrivel Santhoshkumar ◽  
Balasubramanian Ramkumar
Keyword(s):  
Acetic Acid ◽  
Acid Medium ◽  
Kinetics And Mechanism ◽  
Aqueous Acetic Acid ◽  
Primary Alcohols ◽  
Acetic Acid Medium ◽  
Kinetics Of Oxidation ◽  
First Order ◽  
Mechanism Of Oxidation ◽  
Kinetics Of

AbstractThe kinetics of oxidation of a few aliphatic primary alcohols with 1-chlorobenzimidazole (CBI) was studied in aqueous acetic acid medium. The reactions were found to be first order each with respect to the concentrations of CBI and alcohol. The added HClO

Kinetics of vanadium (V) catalyzed oxidation of gallic acid by potassium bromate in acid medium

10.1002/kin.5 ◽  
1996 ◽  
Vol 28 (9) ◽  
pp. 673-679 ◽  
Author(s):  
Dasharath L. Kamble ◽  
Sharanappa T. Nandibewoor
Keyword(s):  
Gallic Acid ◽  
Acid Medium ◽  
Potassium Bromate ◽  
Kinetics Of ◽  
Catalyzed Oxidation

Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium

2015 ◽  
Vol 4 (3) ◽  
pp. 302-309 ◽  
Author(s):  
Deepmala Pareek ◽  
Riya Sailani ◽  
Vinita Gupta ◽  
Chandra Khandelwal ◽  
Prem Sharma
Keyword(s):  
Acid Medium ◽  
Kinetics And Mechanism ◽  
Mechanism Of Oxidation

Kinetics and mechanism of oxidation of DL-α-alanine by permanganate ion in acid perchlorate media

1991 ◽  
Vol 69 (12) ◽  
pp. 2018-2023 ◽  
Author(s):  
Refat M. Hassan
Keyword(s):  
Amino Acids ◽  
Ionic Strength ◽  
Acid Solution ◽  
Second Order ◽  
Perchloric Acid Solution ◽  
Oxidation Reduction ◽  
Initial Stage ◽  
Aqueous Perchloric Acid ◽  
Mechanism Of Oxidation ◽  
Kinetics Of

The kinetics of permanganate oxidation of DL-α-alanine in aqueous perchloric acid solution at a constant ionic strength of 2.0 mol dm−3 has been investigated spectrophotometrically. The reaction was found to show second-order kinetics overall with respect to each of the reactants in the slow initial stage; the second-order kinetics are not, however, maintained throughout the relatively fast final stage of reaction. The added salts lead to the prediction that Mn(III) and (or) Mn(IV) play a very important role in the reaction kinetics. A tentative mechanism consistent with the kinetics is discussed. Key words: kinetics, oxidation, reduction, amino acids, permanganate.

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