New linear integral kinetic parameters assessment method based on an accurate approximate formula of temperature integral

2021 ◽  
Author(s):  
Hamdane Akbi ◽  
Ahmed Mekki ◽  
Souleyman Rafai
Keyword(s):  
Kinetic Parameters ◽  
Approximate Formula ◽  
Assessment Method ◽  
Temperature Integral ◽  
Linear Integral

scholarly journals Pyrolysis Kinetic Parameters of Omari Oil Shale Using Thermogravimetric Analysis

Energies ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 4060
Author(s):  
Ziad Abu El-Rub ◽  
Joanna Kujawa ◽  
Samer Al-Gharabli
Keyword(s):  
Activation Energy ◽  
Thermogravimetric Analysis ◽  
Kinetic Parameters ◽  
Oil Shale ◽  
Arrhenius Plot ◽  
Frequency Factor ◽  
Coefficient Of Determination ◽  
Assay Method ◽  
Temperature Integral ◽  
Integral Approximation

Oil shale is one of the alternative energies and fuel solutions in Jordan because of the scarcity of conventional sources, such as petroleum, coal, and gas. Oil from oil shale reservoirs can be produced commercially by pyrolysis technology. To optimize the process, mechanisms and rates of reactions need to be investigated. Omari oil shale formation in Jordan was selected as a case study, for which no kinetic models are available in the literature. Oil shale was analyzed using the Fischer assay method, proximate analysis (moisture, volatile, and ash), gross calorific value, elemental analysis (CHNS), and X-ray fluorescence (XRF) measurements. Non-isothermal thermogravimetric analysis was applied to study the kinetic parameters (activation energy and frequency factor) at four selected heating rates (5, 10, 15, and 20 °C/min). When oil shale was heated from room temperature to 1100 °C, the weight loss profile exhibited three different zones: drying (devolatilization), pyrolysis, and mineral decomposition. For each zone, the kinetic parameters were calculated using three selected methods: integral, temperature integral approximation, and direct Arrhenius plot. Furthermore, the activation energy in the pyrolysis zone was 112–116 kJ/mol, while the frequency factor was 2.0 × 107 − 1.5 × 109 min−1. Moreover, the heating rate has a directly proportional relationship with the rate constant at each zone. The three different methods gave comparable results for the kinetic parameters with a higher coefficient of determination (R2) for the integral and temperature integral approximation compared with the direct Arrhenius plot. The determined kinetic parameters for Omari formation can be employed in developing pyrolysis reactor models.

New approximate formula for the generalized temperature integral

AIChE Journal ◽  
2009 ◽  
Vol 55 (7) ◽  
pp. 1766-1770 ◽  
Author(s):  
Haixiang Chen ◽  
Naian Liu
Keyword(s):  
Approximate Formula ◽  
Temperature Integral

New approximate formula for Arrhenius temperature integral

2003 ◽  
Vol 408 (1-2) ◽  
pp. 39-43 ◽  
Author(s):  
Wanjun Tang ◽  
Yuwen Liu ◽  
Hen Zhang ◽  
Cunxin Wang
Keyword(s):  
Approximate Formula ◽  
Temperature Integral ◽  
Arrhenius Temperature

New approximate formula for the generalized temperature integral

2009 ◽  
Vol 98 (2) ◽  
pp. 437-440 ◽  
Author(s):  
Tang Wanjun ◽  
Chen Donghua
Keyword(s):  
Approximate Formula ◽  
Temperature Integral

Delir-Diagnostik

2007 ◽  
Vol 20 (2-3) ◽  
pp. 135-139
Author(s):  
B. Dittrich ◽  
G. Gatterer ◽  
T. Frühwald ◽  
U. Sommeregger
Keyword(s):  
Confusion Assessment Method ◽  
Assessment Method ◽  
Psychische Störung ◽  
Confusion Assessment

Zusammenfassung: Das Delir (“akuter Verwirrtheitszustand”) bezeichnet eine psychische Störung, die plötzlich auftritt, durch eine rasche Fluktuation von Bewusstseinslage und Aufmerksamkeitsleistung gekennzeichnet ist und eine organische Ursache hat. Dieses Störungsbild nimmt bei Patienten im höheren Lebensalter deutlich an Häufigkeit zu und verursacht durch verlängerte Krankenhausaufenthalte und ungünstige Krankheitsverläufe erhebliche Kosten im Gesundheitssystem. Daher erscheint eine möglichst frühe Erkennung deliranter Zustandsbilder gerade im Rahmen der Geriatrie von großer Bedeutung. Zu diesem Zweck wurde eine deutsche Version der international weit verbreiteten Confusion Assessment Method entwickelt, die für die Bedürfnisse einer Abteilung für Akutgeriatrie modifiziert wurde. Dargestellt werden die Entwicklung und erste Erfahrungen mit diesem Instrument.

The Need Inventory of Sensation Seeking (NISS)

2012 ◽  
Vol 28 (1) ◽  
pp. 11-18 ◽  
Author(s):  
Marcus Roth ◽  
Philipp Hammelstein
Keyword(s):  
Sensation Seeking ◽  
Reliability And Validity ◽  
Assessment Method ◽  
Factorial Structure ◽  
Conventional Methods ◽  
New Research ◽  
Sensation Seeking Scale ◽  
Temperamental Trait ◽  
Nonclinical Study

Based on the conception of sensation seeking as a need rather than a temperamental trait ( Hammelstein, 2004 ), we present a new assessment method, the Need Inventory of Sensation Seeking (NISS), which is considered to assess a motivational disposition. Three studies are presented: The first examined the factorial structure and the reliability of the German versions of the NISS; the second study compared the German and the English versions of the NISS; and finally, the validity of the NISS was examined in a nonclinical study and compared to the validity of conventional methods of assessing sensation seeking (Sensation Seeking Scale – Form V; SSS-V). Compared to the SSS-V, the NISS shows better reliability and validity in addition to providing new research possibilities including application in experimental areas.

An Empirical Analysis of the Obtrusiveness of and Participants' Compliance with the Electronically Activated Recorder (EAR)

2007 ◽  
Vol 23 (4) ◽  
pp. 248-257 ◽  
Author(s):  
Matthias R. Mehl ◽  
Shannon E. Holleran
Keyword(s):  
Empirical Analysis ◽  
Sampling Method ◽  
Daily Life ◽  
Assessment Method ◽  
Data Confidentiality ◽  
Short Term ◽  
Naturally Occurring ◽  
Two Samples ◽  
Audio Recorder ◽  
Term Monitoring

Abstract. In this article, the authors provide an empirical analysis of the obtrusiveness of and participants' compliance with a relatively new psychological ambulatory assessment method, called the electronically activated recorder or EAR. The EAR is a modified portable audio-recorder that periodically records snippets of ambient sounds from participants' daily environments. In tracking moment-to-moment ambient sounds, the EAR yields an acoustic log of a person's day as it unfolds. As a naturalistic observation sampling method, it provides an observer's account of daily life and is optimized for the assessment of audible aspects of participants' naturally-occurring social behaviors and interactions. Measures of self-reported and behaviorally-assessed EAR obtrusiveness and compliance were analyzed in two samples. After an initial 2-h period of relative obtrusiveness, participants habituated to wearing the EAR and perceived it as fairly unobtrusive both in a short-term (2 days, N = 96) and a longer-term (10-11 days, N = 11) monitoring. Compliance with the method was high both during the short-term and longer-term monitoring. Somewhat reduced compliance was identified over the weekend; this effect appears to be specific to student populations. Important privacy and data confidentiality considerations around the EAR method are discussed.

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