Structural evolution of uniaxial tensile-deformed injection molded poly(ɛ-caprolactone)/hydroxyapatite composites

2015 ◽  
Vol 38 (9) ◽  
pp. 1771-1782 ◽  
Author(s):  
Haibin Zhao ◽  
Guoqun Zhao ◽  
Lih-Sheng Turng ◽  
Xiangfang Peng
2020 ◽  
Vol 26 (3) ◽  
pp. 122-125
Author(s):  
Ivan Gajdoš ◽  
Ján Slota ◽  
Ľuboš Kaščák ◽  
Oleksandr Grytsenko ◽  
Tomasz Jachowicz

As the use of the thermoplastic materials becomes conventional in numerous parts and various applications, incidence of various types of failure becomes inevitable. Failure of injection molded parts can be a cause of economic and legal problems, as well as causing health damage or death. Public perception of plastics is adversely affected by their failures, such as the bad reputation that early plastics earned with toys that broke too easily. As the injection molding process is very complex, finding the cause of failure is very complicated. In industrial mass scale production, determining the cause of failure is key point in customer-supplier relationship. In the presented study, a type of injection molded product from HDPE affected by occurrence of cracks was investigated by mechanical, thermal testing and spectral analysis. Mechanical properties were evaluated by the uniaxial tensile test and the SHORE hardness test. Thermal properties of the samples were evaluated by DSC/TGA analysis and for the spectral analysis a Raman spectroscopy device was used. Obtained results provided information about fluctuating quality of used material, coupled with non/stable molding conditions and small molding window. All those aspects caused molded in stress, which was released in the form of crack during the installation.


Author(s):  
L.D. Schmidt ◽  
K. R. Krause ◽  
J. M. Schwartz ◽  
X. Chu

The evolution of microstructures of 10- to 100-Å diameter particles of Rh and Pt on SiO2 and Al2O3 following treatment in reducing, oxidizing, and reacting conditions have been characterized by TEM. We are able to transfer particles repeatedly between microscope and a reactor furnace so that the structural evolution of single particles can be examined following treatments in gases at atmospheric pressure. We are especially interested in the role of Ce additives on noble metals such as Pt and Rh. These systems are crucial in the automotive catalytic converter, and rare earths can significantly modify catalytic properties in many reactions. In particular, we are concerned with the oxidation state of Ce and its role in formation of mixed oxides with metals or with the support. For this we employ EELS in TEM, a technique uniquely suited to detect chemical shifts with ∼30Å resolution.


1996 ◽  
Vol 451 ◽  
Author(s):  
T. P. Moffat

ABSTRACTA variety of Cu/(Ni, Co) multilayers have been grown on Cu single crystals by pulse plating from an alloy electroplating bath. Copper is deposited under mass transport control while the iron group metal is deposited under interfacial charge transfer control. The structural evolution of these films is influenced by the morphological instability of the mass transport limited copper deposition reaction and the development of growth twins during iron-group metal deposition. Specular films have been obtained for growth on Cu(100) while rough, defective films were typically obtained for growth on Cu(111) and Cu(110).


2000 ◽  
Vol 629 ◽  
Author(s):  
Jean-Loup Masson ◽  
Peter F. Green

ABSTRACTResearchers have shown that thin, nonwetting, liquid homopolymer films dewet substrates, forming patterns that reflect fluctuations in the local film thickness. These patterns have been shown to be either discrete cylindrical holes or bicontinuous “spinodal-like” patterns. In this paper we show the existence of a new morphology. During the early stage of dewetting, discrete highly asymmetric holes appear spontaneously throughout the film. The nucleation rate of these holes is faster than their growth rate. The morphology of the late stage of evolution, after 18 days, is characterized by a bicontinuous pattern, distinct form conventional spinodal dewetting patterns. This morphology has been observed for a range of film thicknesses between 7.5 and 21nm. The structural evolution of this intermediate morphology is discussed.


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