Synthesis and UV curing kinetics of rapidly UV-curable hyperbranched polycarbosiloxanes

In ouder to prepare the waterborne UV-curable polyurethane acrylate coatings, the anionic polyurethane acrylate emulsifier and bisphenol-S eopxy acrylate were synthesized. The curing process, kinetics and properties of waterborone UV-curable epoxy acrylate/polyurethanes acrylate coating were investigated by FTIR, DSC and DMA. The results show that the static initial curing temperature Ti is 52.36 oC, peak temperature Tp is 71.58 oC, the finished temperature Tf is 89.15 oC. The curing reaction can be described by two-parameter autocatalytic Šesták-Berggren (S-B) model.This coating has a better UV-curing property. The dynamic mechanical analysis showed that the glass transition temperature Tg of coating film is 52.70 oC.

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Study on the Curing Kinetics of UV-Curable Inkjet Ink

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.174.397 ◽

2010 ◽

Vol 174 ◽

pp. 397-400 ◽

Cited By ~ 1

Author(s):

Ping Xiu Ni ◽

Xian Fu Wei ◽

Pei Qing Huang ◽

Wei Wei

Keyword(s):

Elastic Modulus ◽

Induction Period ◽

Functional Groups ◽

Uv Curing ◽

Curing Kinetics ◽

Curing Time ◽

Uv Curable ◽

Functional Monomers ◽

The Relationship ◽

Kinetics Of

In order to make different UV curing inkjet ink system and test the relationship between the dynamic elastic modulus and UV curing time, the same monomer and pre-polymer were mixed in different proportions, and different functional monomers and pre-polymer were mixed. The results show that the larger the proportion of the pre-polymer and the greater the number of monomer functional groups, the shorter the induction period of the UV curing of UV inkjet ink system and the faster the UV curing rate. Then, the UV curing kinetics of UV inkjet inks was analyzed preliminarily.

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Synthesis and Curing Kinetics of UV-Curable Waterborne Bisphenol-S Epoxy-Acrylate/Polyurethane-Acrylate/Methylacryloylpropyl-POSS Nanocomposites

Journal of Macromolecular Science Part B ◽

10.1080/00222348.2014.970953 ◽

2014 ◽

Vol 53 (12) ◽

pp. 1800-1813 ◽

Cited By ~ 6

Author(s):

Jungang Gao ◽

Feng Li Zhu ◽

Jianbo Yang ◽

Xiaoqiian Liu

Keyword(s):

Curing Kinetics ◽

Epoxy Acrylate ◽

Bisphenol S ◽

Uv Curable ◽

Polyurethane Acrylate ◽

Kinetics Of

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Ultraviolet Curing Kinetics of Epoxy Resin in UV-Curing Reaction Photopolymerization with Real-Time Fourier Transform Infrared Spectroscopy

Lecture Notes in Electrical Engineering - Applied Sciences in Graphic Communication and Packaging ◽

10.1007/978-981-10-7629-9_94 ◽

2018 ◽

pp. 761-767

Author(s):

Lu Zhang ◽

Xianfu Wei ◽

Beiqing Huang ◽

Lili Wang ◽

Xiaotong Xiong

Keyword(s):

Fourier Transform ◽

Infrared Spectroscopy ◽

Epoxy Resin ◽

Real Time ◽

Fourier Transform Infrared Spectroscopy ◽

Uv Curing ◽

Fourier Transform Infrared ◽

Curing Kinetics ◽

Ultraviolet Curing ◽

Kinetics Of

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Real-Time FTIR andin SituRheological Studies on the UV Curing Kinetics of Thiol-ene Polymers

Macromolecules ◽

10.1021/ma9708656 ◽

1997 ◽

Vol 30 (23) ◽

pp. 7322-7328 ◽

Cited By ~ 136

Author(s):

Bor-Sen Chiou ◽

Saad A. Khan

Keyword(s):

Real Time ◽

Uv Curing ◽

Curing Kinetics ◽

Kinetics Of

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Synthesis, characterization and UV curing kinetics of hyperbranched polysiloxysilanes from A2 and CB2 type monomers

Polymer ◽

10.1016/j.polymer.2009.05.049 ◽

2009 ◽

Vol 50 (15) ◽

pp. 3587-3594 ◽

Cited By ~ 25

Author(s):

Sheng-Jie Wang ◽

Xiao-Dong Fan ◽

Jie Kong ◽

Jian-Ren Lu

Keyword(s):

Uv Curing ◽

Curing Kinetics ◽

Kinetics Of

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Photo Polymerization of Thiol-Hyperbranched Polysilazanes

Advanced Materials Research ◽

10.4028/www.scientific.net/amr.683.266 ◽

2013 ◽

Vol 683 ◽

pp. 266-270 ◽

Cited By ~ 1

Author(s):

Jia Le Song ◽

Peng Wei Hao ◽

Chao Qiang Ye ◽

Li Xin Chen ◽

Wei Guang Li

Keyword(s):

Activation Energy ◽

Uv Curing ◽

Polymerization Rate ◽

Initiator Concentration ◽

Uv Curable ◽

Photo Polymerization ◽

Autocatalytic Model ◽

Theoretical Predictions ◽

Double Bond Conversion ◽

Kinetics Of

The kinetics of UV curable thiol-hyperbranched polysilazanes (HBP) was studied by differential photo-scanning calorimeter (DPC) technology. The effects of photo initiator concentration [I], light intensity I0and temperature on the UV curing rate and the final unsaturated double bond conversion of thiol-HBP were investigated. The results indicate that the dependence of polymerization rate Rp on [I] and I0, respectively, was found to fit with theoretical predictions very well at [I] no more than 0.50wt% and I0lower than 19.40mW/cm2. The kinetic parameters were calculated by autocatalytic model, and correspondingly, the total apparent reaction exponent and apparent activation energy are 8.76 and 13.97kJ/mol, respectively.

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