Annealing induced electrical conductivity jump of multi-walled carbon nanotube/polypropylene composites and influence of molecular weight of polypropylene

2010 ◽  
Vol 48 (21) ◽  
pp. 2238-2247 ◽  
Author(s):  
Yongzheng Pan ◽  
Henry Kuo Feng Cheng ◽  
Lin Li ◽  
Siew Hwa Chan ◽  
Jianhong Zhao ◽  
...  
2010 ◽  
Vol 447-448 ◽  
pp. 619-623
Author(s):  
Yong Zheng Pan ◽  
Lin Li ◽  
Siew Hwa Chan ◽  
Jian Hong Zhao

Composites of polypropylene (PP) and multi-walled carbon nanotubes (MWCNTs) were prepared by a micro melt mixing process. The molecular weight of PP was varied from 190,000 to 340,000 to examine its effects on the electrical conductivity. It has been discovered that a significant enhancement of electrical conductivity could be achieved by a thermal post annealing process above the melting temperature of PP. Factors such as annealing time, temperature, viscosity of PP, and content of MWCNTs all affected the enhancement of electrical conductivity. Re-aggregation of MWCNTs and the subsequent formation of MWCNT networks during annealing are considered to be the main reasons for the quick enhancement of electrical conductivity. The observed effect of molecular weight of PP on the enhancement of electrical conductivity suggested that the enhancement process could be controlled by diffusion of MWCNTs.


2015 ◽  
Vol 727-728 ◽  
pp. 137-140
Author(s):  
A Ying Zhang

This paper presents a systematic study of the nano-sized structure and temperature dependent electrical properties. A method of synthesizing the self-assembled multi-walled carbon nanotube (MWCNT) nanopaper on hydrophilic polycarbonate membrane was explored. The process is based on the very well-defined dispersion of nanotube and controlled pressure vacuum deposition procedure. The experiment results show that the ratio changes of MWCNT in the nanopaper could lead to the changes in the electrical conductivity efficiency of the nanopaper. Furthermore, the electrical resistivity of MWCNT nanopaper decreased as temperature increase.


Carbon ◽  
2011 ◽  
Vol 49 (6) ◽  
pp. 2127-2133 ◽  
Author(s):  
Jun Seop Kim ◽  
Shin Je Cho ◽  
Kwang Seok Jeong ◽  
Young Chul Choi ◽  
Mun Seok Jeong

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