Dual-cured adhesive system improves adhesive properties of dentin cavities restored with a bulk-fill resin composite

Aim: To evaluate the impact of a dual-cured adhesive system on the in situ degree of conversion (DC), bond strength (BS) and failure mode (FM) of adhesive interfaces in dentin cavities restored with a bulk-fill resin composite. Methods: 4-mm-deep dentin cavities with a 3.1 C-factor were created in 68 bovine incisors (n = 17 per group). The lightcured (Scotchbond™ Universal) or the dual-cured (Adper™ Scotchbond™ Multi-purpose Plus) adhesive system was applied to the cavities, which were then restored with a bulkfill resin composite (Filtek™ Bulk Fill). In situ DC analysis was performed by means of micro Raman spectroscopy at the top and bottom interfaces. Push-out BS was measured in a universal testing machine after 24-h or 6-month water storage. FM was determined with a stereomicroscope. Data of in situ DC and BS were analyzed by two-way analysis of variance (ANOVA) and Tukey test (p<0.05), while the FM was analyzed descriptively. Results: The groups that received the dual-cured adhesive system showed statistically higher in situ DC and BS than those that received the light-cured adhesive system. Cohesive failure mode was the most frequent in all conditions. Conclusion: In situ DC and BS were influenced by the curing strategies of the adhesive systems with better performance of the dual-cured material.

Effect of Low Molecular Weight Oxidized Materials and Nitrogen Groups on Adhesive Joints of Polypropylene Treated by a Cold Atmospheric Plasma Jet

Polypropylene is a typical representative of synthetic polymers that, for many applications including adhesive joints, requires an increase in wettability and chemical surface reactivity. Plasma processing offers efficient methods for such surface modifications. A particular disadvantage of the plasma jets can be the small plasma area. Here, we present a cold atmospheric plasma radio-frequency slit jet developed with a width of 150 mm applied to polypropylene plasma treatment in Ar, Ar/O2 and Ar/N2 We identified two main parameters influencing the tensile strength of adhesive joints mediated by epoxy adhesive DP 190, nitrogen content, and the amount of low molecular weight oxidized materials (LMWOMs). Nitrogen functional groups promoted adhesion between epoxy adhesive DP 190 and the PP by taking part in the curing process. LMWOMs formed a weak boundary layer, inhibiting adhesion by inducing a cohesive failure of the joint. A trade off between these two parameters determined the optimized conditions at which the strength of the adhesive joint increased 4.5 times. Higher adhesion strength was previously observed when using a translational plasma gliding arc plasma jet with higher plasma gas temperatures, resulting in better cross linking of polymer chains caused by local PP melting.

Crack-Bridging Property Evaluation of Synthetic Polymerized Rubber Gel (SPRG) through Yield Stress Parameter Identification

Yield stress parameter derivation was conducted by stress-strain curve analysis on four types of grout injection leakage repair materials (GILRM); acrylic, epoxy, urethane and SPRG grouts. Comparative stress-strain curve analysis results showed that while the yield stress point was clearly distinguishable, the strain ratio of SPRG reached up to 664% (13 mm) before material cohesive failure. A secondary experimental result comprised of three different common component ratios of SPRG was conducted to derive and propose an averaged yield stress curve graph, and the results of the yield stress point (180% strain ratio) were set as the basis for repeated stress-strain curve analysis of SPRGs of up to 15 mm displacement conditions. Results showed that SPRG yield stress point remained constant despite repeated cohesive failure, and the modulus of toughness was calculated to be on average 53.1, 180.7, and 271.4 N/mm2, respectively, for the SPRG types. The experimental results of this study demonstrated that it is possible to determine the property limits of conventional GILRM (acrylic, epoxy and urethane grout injection materials) based on yield stress. The study concludes with a proposal on potential application of GILRM toughness by finite element analysis method whereby strain of the material can be derived by hydrostatic pressure. Comparative analysis showed that the toughness of SPRG materials tested in this study are all able to withstand hydrostatic pressure range common to underground structures (0.2 N/mm2). It is expected that the evaluation method and model proposed in this study will be beneficial in assessing other GILRM materials based on their toughness values.

Derivation of Kinematic Equations Based on Full-Scale Racking Tests for Seismic Performance Evaluation of Unitized Four-Sided Structural Sealant Glazing Curtain Wall Systems

Curtain wall glazing systems are a major part of a building due to the multiple roles they have, including occupant protection against environmental effects and the transfer of loads to the structural system. From a structural perspective, limited analytical guidelines and methods exist to aid designers in their determination of the curtain wall performance without extensive simulation or laboratory testing. This study takes experimental data from full-scale, “unitized”, four-sided structural sealant glazing (4SSG) curtain wall system mockups featuring a re-entrant corner subjected to cyclic racking displacements in accordance with the American Architectural Manufacturers Association AAMA 501.6 protocol to derive and establish equations that predict the relative displacements of the glass relative to the glazing frame, based on the amount of inter-story drift. Through derivation and testing, sealant cohesive failure and glass cracking were identified as limit states and corresponding drift levels were determined to control many of the equations. Displacements from the newly derived equations were correlated to the effective shear strain value experienced by the structural silicone in the mockup concurrently with the curtain wall’s drift capacity. This paper provides detailed derivation of the kinematic equations for possible use by glazing design professionals. Such equations can help designers to more easily predict the drifts that cause damage to such systems by manual calculations without the need for expensive mockup testing or time-intensive computer models.

Experimental characterization of Mode II fatigue delamination growth onset in composite Joints

In this article, the structural behavior of co-cured composite joint (CC), co-bonded composite joint (CB), and secondary-bonded composite joint (SB) under Mode II fatigue loading was evaluated. Fatigue performance was evaluated in sub-critical strain energy release rate (SERR) associated with Mode II fatigue induced delamination growth onset. Fatigue tests were carried out using the three-point bending End Notched Flexure test setup for different energy ratios. The experimental results are presented in terms of SERR versus number of cycles, and the SERR threshold for no growth is determined (Gth). Fractographic analyses were performed in order to identify the main failure mechanisms related to each joining technology under Mode II. The results indicated an initial cohesive failure followed by an adhesive failure promoted by crack propagation at the interface between the adhesive and the composite adherend on SB and CB samples, through the coalescence of microcracks that promote the adhesive failure process, leading to fiber pull-out from the matrix and cusps formation in the fracture surface. These results explain the low performance behavior observed on SB and CB bonded techniques. It is worth mentioning that the results and behavior observed in this work are valid only for the laminates, adhesives, surface treatment, and environmental conditions tested herein.

Morphology and Tensile Properties as a Function of Welding Current in Thermoplastic Induction Welds

Compared to other conventional joining methods, induction welding offers the superiority of avoiding mechanical degradation and satisfying the need for weight reduction in the aircraft industry. In this paper, a metal mesh was adapted as an induction component in the induction welding of polyetheretherketone (PEEK) with various currents. The effect of welding current on the microstructure and mechanical properties of the induction welding joint was further investigated. The results indicate that induction welding joints with the narrow thickness of the fusion zone and high tensile strength can be attained in the welding current range of 7.05 A to 11.05 A. However, when the current exceeds 13.91 A, the excessive heat input leads to the unsteady flow of PEEK or even thermal oxidative degradation and thermal decomposition, which increases the thickness of the fusion zone and reduces the tensile strength of the joint. In addition, the principal fracture mode presents cohesive failure, thereby promoting the tensile strength of the joint.

Comparative study of adhesive fatigue in aeronautical bonded joints: A numerical approach in the frequency domain

The use of adhesively bonded structures has increased over the years, together with the development of composite materials. This work investigates a procedure for fatigue life prediction of an aeronautical bonded joint under random loads, in particular, the cohesive failure of the adhesive layer in a skin-to-stiffener bonded joint. The use of two different adhesives is investigated, and Dirlik’s method is employed to predict the stress response in the adhesive layer, from which the fatigue life is obtained. The effect of damping is also investigated, and it is shown that increases in damping result in higher fatigue life estimations.

Static and fatigue behavior of induction-welded single lap carbon fiber reinforced polyetherketoneketone thermoplastic composite joints

This paper presents details of the mechanical properties related to the static and fatigue strength of carbon fiber reinforced polyetherketoneketone (CF/PEKK) thermoplastic induction-welded composite joints. To better understand the process parameters, the finite element modeling (FEM) of the heat distribution was analyzed based on the generator power, coil coupling distance, coil moving speed, frequency, compaction force, and coil geometry while maintaining the optimal coil speed. The temperature behavior calculated using the simulation model exhibited good agreement with experimental results. A microscopic inspection, non-destructive test (NDT) was conducted to check the morphology characteristics of the welded joints. To check the mechanical performance of the induction-welded specimens, single-lap shear strength (SLSS) tests under static and cyclical fatigue loading conditions were conducted to check the weld qualities from a practical perspective. The mechanical testing results indicated that the static and cyclical fatigue specimens were dominated by a cohesive failure mode with a light fiber tear (LFT). These results suggested that using the optimal process parameters based on multi-physics FEM simulation could potentially improve mechanical performance.

Discharge Plasma Treatment as an Efficient Tool for Improved Poly(lactide) Adhesive–Wood Interactions

Poly(lactide) (PLA) films obtained by thermoforming or solution-casting were modified by diffuse coplanar surface barrier discharge plasma (300 W and 60 s). PLA films were used as hot-melt adhesive in joints in oak wood. It was demonstrated that lap shear strength increased from 3.4 to 8.2 MPa, respectively, for the untreated and plasma-treated series. Pull-off tests performed on particleboard for the untreated and treated PLA films showed 100% cohesive failure. Pull-off strength tests on solid oak demonstrated adhesion enhancement from 3.3 MPa with the adhesion failure mode to 6.6 MPa with the cohesion failure mode for untreated and treated PLA. XPS revealed that carbonyl oxygen content increased by two-to-three-fold, which was confirmed in the Fourier-transform infrared spectroscopy experiments of the treated PLA. The water contact angle decreased from 66.4° for the pristine PLA to 49.8° after treatment. Subsequently, the surface free energy increased from 47.9 to 61.05 mJ/m2. Thus, it was clearly proven that discharge air plasma can be an efficient tool to change surface properties and to strengthen adhesive interactions between PLA and woody substrates.

The Effect of Pre-Bond Contamination by Thermal Degradation and De-Icing Fluid on the Tensile Strength of Scarf Composite Bonded Joints

The synergistic effect of pre-bond contamination by thermal degradation and de-icing fluid on the tensile behavior of scarf composite bonded joints has been investigated experimentally. The contamination types considered are related to the repair process of composite aircraft structures. Three contamination scenarios have been considered: namely, thermal degradation (TD) and a combination of thermal degradation with two different levels of de-icing fluid (TD+DI1 and TD+DI2). DI2 is more severe than DI1. Contamination has been applied to one of the adherents while the other one has been intentionally left intact. Tension tests have been conducted on single-lap shear specimens. The experimental results were compared with the reference samples (REF) showing an increase in tensile strength for the TD specimens and a decrease in tensile strength for the TD+DI1 and TD+DI2 specimens. After the tension tests, the failure surfaces were evaluated to get a better insight of the failure mechanisms of the bondline and to assess the effect of contamination. The TD specimens presented an increased cohesive failure which is consistent with the increase of the failure load, while the combined contamination caused the failure of the composite adherents which again is consistent with the decrease of tensile strength of the scarf specimens.