Promoting Effect of SO2 on Activated Carbon-Supported Vanadia Catalyst for NO Reduction by NH3 at Low Temperatures

1999 ◽  
Vol 187 (1) ◽  
pp. 245-248 ◽  
Author(s):  
Zhenping Zhu ◽  
Zhenyu Liu ◽  
Hongxian Niu ◽  
Shoujun Liu
2000 ◽  
Vol 26 (1) ◽  
pp. 25-35 ◽  
Author(s):  
Zhenping Zhu ◽  
Zhenyu Liu ◽  
Shoujun Liu ◽  
Hongxian Niu ◽  
Tiandon Hu ◽  
...  

2012 ◽  
Vol 51 (36) ◽  
pp. 11667-11673 ◽  
Author(s):  
Yanli Wang ◽  
ChuanZhang Ge ◽  
Liang Zhan ◽  
Cui Li ◽  
Wenming Qiao ◽  
...  

2019 ◽  
Vol 211 ◽  
pp. 421-429 ◽  
Author(s):  
Junyeong Kim ◽  
Jeong Yeon Do ◽  
Keepyung Nahm ◽  
No-Kuk Park ◽  
Junhwa Chi ◽  
...  

2021 ◽  
Author(s):  
Yuki Omori ◽  
Ayaka Shigemoto ◽  
Kohei Sugihara ◽  
Takuma Higo ◽  
Toru Uenishi ◽  
...  

Pd catalyst (Pd/Ce<sub>0.7</sub>Zr<sub>0.3</sub>O<sub>2</sub>) in an electric field exhibits extremely high three-way catalytic activity (TWC: NO-C<sub>3</sub>H<sub>6</sub>-CO-O<sub>2</sub>-H<sub>2</sub>O). By applying an electric field to the semiconductor catalyst, low-temperature operation of TWC can be achieved even at 473 K by virtue of the activated surface-lattice oxygen.


2019 ◽  
Vol 79 (6) ◽  
pp. 1195-1205 ◽  
Author(s):  
Xuxu Wang ◽  
Xuebin Hu ◽  
Chun Zhao ◽  
Zhihua Sun ◽  
Huaili Zheng ◽  
...  

Abstract In this study, powder activated carbon (PAC) utilized to activate peroxydisulfate (PDS) was investigated for decolorization of Acid Orange 7 (AO7). The results indicated a remarkable synergistic effect in the PAC/PDS system. The effect of PAC, PDS dosages and initial pH on AO7 decolorization were studied and the processes followed first-order kinetics. Response surface method with central composite design (CCD) model was utilized to optimize these three factors and analyze the combined interaction. The optimum condition for the decolorization rate of AO7 was analyzed as the following: PAC (0.19 g/L), PDS (1.64 g/L), and initial pH (4.14). Cl− and SO42− showed a promoting effect on AO7 decolorization while HCO3− had a slightly inhibiting effect. Quenching experiments confirmed that both sulfate and hydroxyl radicals were the oxidizing species, and the oxidation reaction occurred on the surface of PAC. The results of UV-vis spectrum with 100% decolorization rate and the 50% total organic carbon reduction indicated highly efficient decolorization and mineralization of AO7 in the PAC/PDS system. Finally, the recovery performance of PAC was studied and the result indicated PAC had poor reuse in reactivity.


2019 ◽  
Vol 9 (14) ◽  
pp. 3637-3646
Author(s):  
Xiaofang Tan ◽  
Gang Cheng ◽  
Xinjie Song ◽  
Xun Chen ◽  
Wenxin Dai ◽  
...  

Pd/N–TiO2 was readily synthesized as an efficient catalyst for NO reduction by CO at lower temperature under visible light irradiation.


2019 ◽  
Vol 44 (26) ◽  
pp. 13523-13537 ◽  
Author(s):  
Kaijie Liu ◽  
Qingbo Yu ◽  
Baolan Wang ◽  
Huaqing Xie ◽  
Wenjun Duan ◽  
...  

1991 ◽  
Vol 6 (5) ◽  
pp. 1040-1047 ◽  
Author(s):  
K. Kuriyama ◽  
M.S. Dresselhaus

The conductivity and photoconductivity are measured on a high-surface-area disordered carbon material, i.e., activated carbon fibers, to investigate their electronic properties. This material is a highly disordered carbon derived from a phenolic precursor, having a huge specific surface area of 1000–2000 m2/g. Our preliminary thermopower measurements show that the dominant carriers are holes at room temperature. The x-ray diffraction pattern reveals that the microstructure is amorphous-like with Lc ≃ 10 Å. The intrinsic electrical conductivity, on the order of 20 S/cm at room temperature, increases by a factor of several with increasing temperature in the range 30–290 K. In contrast, the photoconductivity in vacuum decreases with increasing temperature. The magnitude of the photoconductive signal was reduced by a factor of ten when the sample was exposed to air. The recombination kinetics changes from a monomolecular process at room temperature to a bimolecular process at low temperatures, indicative of an increase in the photocarrier density at low temperatures. The high density of localized states, which limits the motion of carriers and results in a slow recombination process, is responsible for the observed photoconductivity.


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