Hydrogen Separation Using Dense Composite Membranes

Author(s):  
David H. Anderson ◽  
Carl R. Evenson ◽  
Todd H. Harkins ◽  
Douglas S. Jack ◽  
Richard Mackay ◽  
...  
1999 ◽  
Vol 350 (1-2) ◽  
pp. 106-112 ◽  
Author(s):  
Anwu Li ◽  
Weiqiang Liang ◽  
Ronald Hughes

2011 ◽  
Vol 179-180 ◽  
pp. 1309-1313 ◽  
Author(s):  
Xiao Liang Zhang ◽  
Xu Feng Xie ◽  
Yan Huang

Pd-based composite membranes are the attractive membrane materials for hydrogen separation due to their high hydrogen permeability and infinite permselectivity. Thin pure Ni and Pd-Ni alloy membranes with high hydrogen permeation were prepared by the electroless plating method. It is difficult to prepare the dense pure Ni membranes with 1-2 μm thickness for hydrogen separation. However, Pd-Ni alloy membranes with several micrometers thickness showed good permeation performance. Hydrogen permeance of the Pd95Ni5 alloy membrane with fcc phase up to 3.1×10-6 mol/m2 s Pa and the ideal permselectivity over 600 were obtained at 773 K.


2003 ◽  
Vol 93 (1) ◽  
pp. 11-22 ◽  
Author(s):  
Fernando Roa ◽  
J.Douglas Way ◽  
Robert L. McCormick ◽  
Stephen N. Paglieri

2013 ◽  
Vol 437 ◽  
pp. 257-264 ◽  
Author(s):  
A.E. Lewis ◽  
D.C. Kershner ◽  
S.N. Paglieri ◽  
M.J. Slepicka ◽  
J.D. Way

2014 ◽  
Vol 135 ◽  
pp. 190-198 ◽  
Author(s):  
Sumudu N. Wijenayake ◽  
Nimanka P. Panapitiya ◽  
Cindy N. Nguyen ◽  
Yu Huang ◽  
Kenneth J. Balkus ◽  
...  

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Jae-Yun Han ◽  
Chang-Hyun Kim ◽  
Sang-Ho Kim ◽  
Dong-Won Kim

For the commercial applications of hydrogen separation membranes, both high hydrogen selectivity and permeability (i.e., perm-selectivity) are required. However, it has been difficult to fabricate thin, dense Pd alloy composite membranes on porous metal support that have a pore-free surface and an open structure at the interface between the Pd alloy films and the metal support in order to obtain the required properties simultaneously. In this study, we fabricated Pd alloy hydrogen separation membranes with dense/porous hybrid structure for high hydrogen perm-selectivity. The hydrogen selectivity of this membrane increased owing to the dense and pore-free microstructure of the membrane surface. The hydrogen permeation flux also was remarkably improved by the formation of an open microstructure with numerous open voids at the interface and by an effective reduction in the membrane thickness as a result of the porous structure formed within the Pd alloy films.


1994 ◽  
Vol 94 (1) ◽  
pp. 299-311 ◽  
Author(s):  
A.L. Athayde ◽  
R.W. Baker ◽  
P. Nguyen

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