Chemical Reactions Engineered to Address Thermal Energy Situations (CREATES)

Author(s):  
Jennifer Wilhelm ◽  
Ronald Wilhelm ◽  
Merryn Cole
1984 ◽  
Vol 21 (3) ◽  
pp. 475-488 ◽  
Author(s):  
Carl D. Palmer ◽  
John A. Cherry

The geochemical mass transfer model WATEGM-SE is used to illustrate by example potential chemical reactions that can occur at a hypothetical low-temperature thermal energy aquifer storage facility. Important processes that control the chemistry include heating and cooling of the water, equilibration of the pumped water with the atmospheric partial pressure of CO2 and O2, and the mixing of the injection water with the native groundwater during the injection, storage, and recovery cycles. For the given example, 0.3 mmol/L of calcite would be precipitated under closed system pumping and heating from 10 to 50 °C while a total of 1.9 mmol/L would be precipitated under the open condition. If this calcite were to form scale within the facility's piping then considerable lengths can be affected depending on the pumping rate. Alternatively, if the precipitate is kept in suspension it will be transported to the injection well and will be filtered out by the aquifer itself. This filtration can result in significant decreases in porosity and hence permeability in the immediate vicinity of the injection well. Mixing of the injection water with the native groundwater changes the water chemistry and can result in mineral supersaturation or undersaturation depending on the composition of these waters and the proportions in which they are mixed. The effect of mixing on the given example is undersaturation with respect to calcite and supersaturation with respect to amorphous Fe(OH)3. The pe values in the simulations of mixtures of an oxidizing injection water and a reducing native groundwater yielded some results with significantly higher pe values than the oxidizing injection water. The use of equilibrium geochemical mass transfer models tempered by an understanding of their limitations may prove to be an effective tool for evaluation of potential chemical reactions associated with low-temperature aquifer thermal energy storage facilities. Key words: thermal energy storage, geochemical equilibria, groundwater, simulation, scale formation, mixing.


Author(s):  
Daniel Lager ◽  
Lia Kouchachvili ◽  
Xavier Daguenet

This Subtask aims to have reliable thermal analysis methods/protocols and procedures for the characterization of aterial and reaction properties for sorption and chemical reactions of thermal energy storage  (TES) applications. One goal is an inventory of already standardized measurement procedures for TCM as well  as of needed characterization procedures.


Author(s):  
Timothy W. Tong ◽  
Mohsen M. Abou-Ellail ◽  
Yuan Li ◽  
Karam R. Beshay

The present paper is concerned with the numerical computation of flow, heat transfer and chemical reactions in porous burners. The porous solid matrix acts as a host for redistributing the thermal energy transferred to it from the hot reacting gases. Inside the porous matrix, heat is transferred down stream by conduction and radiation. This thermal energy is then transferred to the incoming cold fuel/air mixture to initiate the chemical reaction processes and thus stabilize the flame. One of the important features of porous burners is its presumed low levels of NO concentration. In the present work, the computed NOx is compared with experimental data and open premixed flames. In order to accurately compute the nitric oxide levels in porous burners, both prompt and thermal NOx mechanisms are included. In the present work, the porous burner species mass fraction source terms are computed from an ‘extended’ reaction mechanism, controlled by chemical kinetics of elementary reactions. The porous burner has mingled zones of porous/nonporous reacting flow, i.e., the porosity is not uniform over the entire domain. Finite-volume equations are obtained by formal integration over control volumes surrounding each grid node. Up-wind differencing is used to insure that the influence coefficients are always positive. Finite-difference equations are solved, iteratively, for velocity components, pressure correction, gas enthalpy, species mass fractions and solid matrix temperature. A non-uniform (80×80) computational grid is used. The grid used to solve the solid energy equation is extended inside the solid annular wall of the porous burner, to improve its modeling. A discrete-ordinate model with S4 quadrature is used for the computation of thermal radiation emitted from the solid matrix. The porous burner uses a premixed CH4-air mixture, while its radiating characteristics are required to be studied numerically under equivalence ratios 0.6 and 0.5. Twenty-five species are included, involving 75 elementary chemical reactions. The computed solid wall temperature profiles are compared with experimental data for similar porous burners. The obtained agreement is fairly good. Some reacting species, such as H2O, CO2, H2, NO and N2O increase steadily inside the reaction zone. However, unstable products, such as HO2, H2O2 and CH3, increase in the preheating zone to be depleted afterward.


Author(s):  
Qi Xiao ◽  
Sarina Sarina ◽  
Eric Waclawik ◽  
Huaiyong Zhu

Direct photoexcitation of metal nanoparticles (NPs) can induce selective chemical reactions that are difficult to achieve with thermal energy. Here we report that visible-light photoexcitation on palladium (Pd) NPs shows...


1999 ◽  
Vol XXXI (1-4) ◽  
pp. 63-76
Author(s):  
R. T. Gaifutdinov ◽  
М. F. Ismagilov ◽  
D. R. Khasanova

Body temperature reflects the state of homeostasis, the intensity of bioenergetic processes and the thermal state of the human body as a whole. In the physical sense, body temperature is a measure of the amount of thermal energy in the body, determines the rate of chemical reactions, affecting all biological functions of the body.


Volume 1 ◽  
2004 ◽  
Author(s):  
Stanislaw Sieniutycz

We describe quantitatively effects of nonlinear transfer phenomena that drive energy generators (thermal engines) and heat pumps. It is shown that these transports can be treated either in a standard way or as peculiar rate processes (chemical reactions governed by appropriate affinities). An approach to nonlinear transports links heat fluxes with differences of temperature in certain power Ta. A more recent approach distinguishes in each elementary transfer step two competitive (unidirectional) fluxes and the resulting flux as their difference. We show how the kinetics of this sort can be implemented into the contemporary theory of thermal energy generators.


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